钙钛矿太阳能电池的发展与工作原理

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、。、、———、。。。。。。、。。。、。。。、。。。。。。、。μ。μ150001。。。。。,。Abstract:Developmenthistoryofperovskitesolarcellsisbrieflyreviewed.Perovskitesolarcellsaresolid-statedye-sensitizedsolarcells.Describesthestructureofperovskite.Describingthestructureandworkingprincipleofperovskitesolarcells.Theenergyconversionef-ficiencyofperovskitesolarcellshasexceededtheamorphoussiliconsolarcells.latter.Aconclusionisdrawnthatperovskite-basedsolarcellsareexpectedbecomingthenextgenerationthin-filmsolarcells.Thebottleneckofmarketizationforperovskite-basedsolarcellsisthefabricationofexpensiveholetransportationlayer.Theresearchesaimtoresolveitaresummarized.KeywordsPerovskitesolarcells;Solid-statedye-sensitizedsolarcells;Holetransportlayer··。。。。。。。。。。。。。。。。。。。。。。。。、、。、。、。。、。。。[1]SnaithH.J.,J.Phys.Chem.Lett.,2013,4(21)3623—3630[2]GraitzelM.,JanssenR.A.,MitziD.B.,SargentE.H.,Nature,2012,488(7411),304—312.[3]TodorovT.K.,ReuterK.B.,MitziD.B.,Adv.Mater.,2010,22(20),E156—E159.[4]O’reganB.,GraitzelM.,Nature,1991,353,737—740.[5]ZhouH.,ChenQ.,LiG.,LuoS.,SongT.,DuanH.S.,HongZ.,YouJ.,LiuY.,YangY.,Science,2014,345(6196),542—546.[6]HeoJ.H.,ImS.H.,NohJ.H.,MandalT.N.,LimC.-S.,ChangJ.A.,LeeY.H.,KimH.,SarkarA.,NazeeruddinM.K.,Nat.Photonics,2013,7(6),486—491.[7]EtgarL.,GaoP.,XueZ.,PengQ.,ChandiranA.K.,LiuB.,NazeeruddinM.K.,GraitzelM.,J.Am.Chem.Soc.,2012,134(42),17396—17399.[8]LiuMZ,JohnstonMB,SnaithHJ.Efficientplanarhetero-junctionperovskitesolarcellsbyvapordeposition[J].Nature,2013,501:395[9]ChristiansJA,FungRM,KamatPV.Aninorganicholecon-ductorfororganic-leadhalideperovskitesolarcellsimprovedholeconductivitywithcopperiodide[J].JAmChemSoc,2014,136:758.[10]UngerEL,HokeET,BailieCD,etal.Hysteresisandtran-sientbehaviorincurrent-voltagemeasurementsofhybrid-per-ovskiteabsorbersolarcells[J].EnergyEnvironSci,2014,7:3690.··

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