木质陶瓷的研究现状及应用

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,,,,,,[1],,。,,、,[2]。,,,,,,。1,,1),,;2)、、,;;3),,。[3]。,,,、,,。(woodceramics)“,”“”(Ecomaterial)。5[4-6]:1),、、。,。2)。3),,。4),,。5)。。,,,,(,315103)“”,,、,、、。,,。;;;;TB383A1004-244X(2011)02-0107-06ResearchprogressandapplicationofwoodceramicsYANDongming,LIANGXiyao,GAOXiaoju,ZHAOBin,LIJinfu(NingboBranchofChinaAcademyofOrdnanceScience,Ningbo315103,China)AbstractAsatypicalecomaterial,thewoodceramics,developedaccordingtothebionicsprinciple,havetheadvantagesofreproduction,lowpollution,lowenergyconsumptionandthecharacteristicsofporous,conductive,self-lubricatingandsoon.Thecharacteristicsofwoodceramicswerebrieflydescribed.Theresearchstatusofwood-relatedcompositematerialsathomeandabroadwereimportantlysummedup.Atthesametime,theapplicationexamplesofwoodceramicswerelisted.Keywordsecomaterial;woodceramics;carborundum;researchprogress;application:2010-11-02;:2011-03-02:(2008DFR50390):,,;。:,。:0535-6890192;E-mail:gxjg2933@yahoo.cn。ORDNANCEMATERIALSCIENCEANDENGINEERINGVol.34No.2Mar.,201134220113DOI:CNKI:33-1331/TJ.20110318.1315.063:2011-03-1813:15:,,(,、)。800~2000℃,,,,,。,,[7]。,,、、,,,,[8]。,,,[9];,0.1~0.15,;,、,,;(m5)(m=10~20)[10]。,。,[11]。,[12]。2.2。。“”,,,[13-14]。,,1800℃,,1600℃,,、、[15]。、、,,,,,,4h。,,,,,,。、。、,,400~500℃,、、、。、、(MDF),1~5mm,120℃,900℃,,1600℃,。X(XRD),β-SiC,100~300MPa,10。、,、、[16]。2.3,,。、、,0.95~3.83g/cm3,,,。,(3%),。,,[17]。2.4,80℃,20%~120%。、,,、[18]。-,[19-21]。,,、,(tetraethylorthosilieate,TEOS),(0.2~1.0MPa),,、SiO2。:1082,20%,40%,。(TGA),,,450℃,550℃[22]。:,,,,;,,[23]。,,A12O3,A12O3SiO2,。,[22][24],,(weight-pereentgain,WPG)。(MMA),,[25]。2.5(WIC),、,。,/(wood-inorganiccomposites,WIC),()(),()[1]。、,、,,[26]。(silicifiedwood),、,,SiO2。,,,SiO2,,SiO2,。,、[27],44℃,5mm,,20%~120%,[28]。,(15~18℃),(103±2)℃,(AAE)(ASE),3.8mg/cm3,30%,,10[29]。1~2h,20%~30%4~6h,,[30],、、,[1]。、,,[31]。3((Populustomentosa),,,(),,[32]。、、、,,,、[33-35]。2.6/(),-。-(MMA),[36];,,,,5%1GPa110GPa,,/[37],。,Si/C/O,,[38]。3,,,。()、[39],,,,。,、、,,。,,[40]。:10934。,Si/SiC,。Byrne[41]SiSi/SiC。Si/SiC,Si/SiC[42]。Greil[43]Si,Si/SiC,20%~30%,4150~200MPa。Qiao[44]Si/SiC,100~300MPa,10。SiSiC,SiC12.6MPa38.4MPa58.68MPa117.3MPa,。SiCSiSi、SiO(SiH4H3CSiCl3)。Vogli[45]SiOSiC。Qian[46]SiSiC,50%,50MPa。。Ota[47],TiO2,TiO2。Singh[48]SiZrO2,SiC。Zollfrank[49]———(PMHS),/,,SiOC,、SiOC/C。PMHSSi—HOHSiO[50],,。[51-52]/,、3~8,。44.1、,、,,。。,。,。,,。(),。4.2、,,。800℃,,80%。、,、。4.3,、。,1000,100。,、,、。。4.4,,,,,,,。,,,、、、,[53]。4.5、。“”。,,、、。(SiC),1102。GJB5478—2006I、II,I、II350,300g,。。、,、,[54-55]。5、、、,[56]。,,。,,,,。[57-59]。6[1].[M].,.:,1997:121-123.[2],,,.[J].,2003,34(1):20-22.[3].[M].,.:,1996:2-5.[4]HataK,ShibataK,OkabeT,etal.Laserbeammachiningofporouswoodceramics[J].JoumalofPorousMaterials,1998,5(1):65-75.[5]OkabeT.Newporouscarbonmaterial,woodceramics[D].DoctoralDissertationoftheUniversityofTokyo,1995.[6]OkabeT,SaitoK,FushitaniM,etal.Porouscarbonmaterials-woodceramics[M].Tokyo,Japan:UchidaRokakuhoPubCoLtd,1996:1.[7]OkabeT,SaitoK.DevelopmentofWoodceramics[M]//Ya-mamotoR.AdvancedMaterials’93,V/A:Ecomaterials.Nether-lands:ElsevierScienceBV,1994:681-684.[8]KondoN,SudaT,OkabeT.Woodceramicsthinfilms[D]//YamamotoR.TheThirdInternationalConferenceonEcomaterials,Tsukuba,Japan:TheSocietyofNon-traditionalTechnology,1997:218-223.[9]KazuhiroK,SudaT.Woodceramicashumiditysensor[D]//YamamotoR,TheFourthInternationalConferenceonEcoma-terials,Gifu,Japan:TheSocietyofNon-traditionalTechnolo-gy,1999:297-300.[10]ItakuraS,OkabeT,SaitoK.Propertiesofphenolicresintreatedwoodmanufacturedbyultrasonicwaveresinimpreg-nationmethod[D]//YamamotoR.TheThirdInternationalConferenceonEcomaterials,Tsukuba,Japan:TheSocietyofNon-traditionalTechnology,1997:178-181.[11],,.[J].,1998,21(6):45-48.[12],,,.-[J].,2001,32(2):121-123.[13]SieberH,HoffmannC,KaindlA,etal.Biomorphiccellularceramics[J].AdvancedEngineeringMaterials,2000,2(3):105-109.[14],.[J].,1998(3):40.[15].[N].,1997-5-23(3).[16],,.[J].,1998,32(8):57-61.[17].[M].,1993:8-9.[18].[M].,2000:64.[19]LiJianzhang,FurunoT,KatohS.Preparationandpropertiesofacetylatedandpropionylatedwood-silicatecomposites[J].Holzforschung,2001,55(1):93-96.[20]MiyafujiH,SakaS,YamamotoA.SiO2-P2O5-B2O3wood-inorganiccompositespreparedbymetalalkoxideoligomersandtheirfire-resistingproperties[J].Holzforchung,1998,52(4):410-416.[21]TannoF,SakaS,YamamotoA,etal.AntimicrobialTMSAH-addedwood-inorganiccompositespreparedbythesol-gelproeess[J].Holzforchung,1998,52(4):365-370.[22],.[J].,1996,10(4):435-440.[23],,,.(Si-,Al-)[J].,2000(1):51-55.[24],,,./[J].,1998(5):16-18.[25],,.--PMMA-SiO2[J].,2001(1):21-23.[26],.[J].,2001(3):52-54.[27]HicksH.Sodiumsilicatecomposition:US,4612050[P].1986-09-16.[28]McCaffertyP.Instantpetrifiedwood[J].PopularSeience,1992(10):56-57.[29],,.[J].,1993,21(1):85-88.[30],.:,93115148.1[P].1993-06-28.:11134[31],,.:[J].,1997():11-13.[32],,.[J].,2000,22(6):39-42.[33]YamaguchiH.Lowmolecularweightsilicicacid-inorganiccompoundcomplexaswoodpreservative[J].WoodScienceandTechnology,2002,36:399-417.[34]KiritaS,TsunodaK,TakahashiM.Influenceofboricacidadditiononthebiologicalresistanceofwood-inorganicmat

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