环保橡胶填充油生产技术研究进展-岳宗豪

20138Aug．2013LUBRICATINGOIL284Vol．28No．4MARKET＆TREND1002-3119201304-0001-05124022REACHPAHs、。。TE626．3AResearchProgressonProductionTechnologyofEnvironmental－FriendlyRubberExtenderOilYUEZong－haoYUYangPetroChinaLiaohePetrochemicalCompanyPanjin124022ChinaAbstractThelimitsofEUREACHlegislationrelatedaboutrubberextenderoilwasintroducedbrieflyinthepaperincludingPAHslimitruledetectionmethodsanddetectionagencyofthePAHsathomeandabroad．Thenseveralmainenvironmen-tal－friendlyrubberextenderoilsandtheirfeaturesaswellastheresearchprogressathomeandabroadwereanalyzed．Andsomesuggestionsonthedevelopmentofenvironmental－friendlyrubberextenderoilinourcountrywereputforward．Keywordspolycyclicaromatichydrocarbonenvironmentalprotectionrubberextenderoilproductionprocess0200612、、REACH。。REACH17PAHs201011。、。。REACH。1REACHPAHs1．1PAHs2005/69/ECREACH。PCADAEDistillateAromaticEx-tract。REACHBaP1mg/kg8PAHsBaP、BeP、BaA、CHR、BbFA、BjFA、Bk－FA、DBAhA10mg/kg1。IP34621998《PCA———》PCA3%。6aPAHs。2201328MARKET＆TREND1．2PAHsPAHs－GC/MSHPLCGC/MSGrimmer3Grimmer。HLPCGCPAHsGC/MSDMSOGC/MSHLPCGC。4GC－MS16PAHs16PAHs0.01～0.05mg/L55.70%～105.28%1.73%～13.23%2007SN1877．3－2007《》5。IP346Shell。IP346GC－MS。IP346PCA6。IP3462005/69/ECPCAa8PAHs。2005/69/ECPAHs。、BIU。GLPSGSTUVNORD7SGSTUV。PAHs。22．1、、、、、。、、。DAE。①TDAETreateDstillateAromaticExtractTDAEDAEPCA。②HeavyNaphthenicOilNAPNAP③MildlyExtractSolvateMESMES④ResidualAromaticExtractRAE－－⑤。1。1NAPMESTDAERAEPCA%＜3.0＜3.0＜3.0＜3.0/℃＞230℃＞220℃＞240℃280100℃/mm2·s－117～3313～1716～225215℃/g·cm－30．920～0．9500．895～0．9250．930～0．9600．96720℃1．50～1．521．495～1．5101．520～1．5401．54384．3MARKET＆TRENDNAPMESTDAERAE/℃85～10085～10065～7579/℃＜0＜0＜+3033VGC0．8600．8500．8800．901%CA11～1711～1725～3033TDAEDAE。MESCATDAETDAE。NAP。RAEIP3462005/69/EC。RAESHELL595BTotalP50、。2．2TDAE、MES、NAPDAE。1TDAETDAE、ExxonMobil、BPRepsolTDAECA25%～30%DAE。MESExxonMobil、MESCA11%～17%。TDAEDAEDAETDAEDAE。TDAEDAE。TDAE1。62/7;:394.94758+*,10/7-+*,1TDAEHisao8350～600℃PCAPCA3%CA18%11%～15%100℃10～70mm2/s。Takasaki920%～90%10%～80%0.5～2.5∶160～115℃45～80℃TDAE。ExxonMobi10PCA。BP111～1.8∶150～90℃20～60℃50%PCA3%。RepsolPCA、NMP。TDAEDAEⅠⅡDAETDAE10%。。4201328MARKET＆TRENDAPIⅡ、ⅢⅠ2020DAE50%。TDAEH＆RTDAE2000TDAEH＆RTDAE40t30t/a10t/aTDAE。2NAPMESNAPErgonNy-tex8450CA14%～15%。Nytex4700CATDAE。Naphtenics、MES、202、3。,*3;7945?28/60:1=-+.2NAP5AD8;3/=?6;3/=@62CB4907?6;307-+.14907-+.1;3=:,*3MES2．3。、。12－。3。2005NAP10。－CA113。RIPP“－－－”RHW23Ⅰ0.2mg/kg14。、、CN40%。2009。、。36－1。2005/69/EC15。20101231REACH5t。RIPPARECA19.0%35%～40%16。20121262℃55℃38%。7t/a3t2005/69/EC20%。ARE4．5MARKET＆TREND、。、、TDAE－。20123REPSOL、、REPSOLTDAECA24%REPSOL。3。REACHPAHs。。。1．J．20092426－9．2IP346．DeterminationofPolycyclicAromaticsinUn－UsedLubricatingBaseOilsandAsphalteneFreePetroleumFrac-tions－DimethylSulphoxideExtractionRefrac－TiveIndexMethodS．3GrimmerGJacobJNaujackKWetal．ProfileofPoly-cyclicAromaticHydrocarbonfromLubricatingOilsInven-torybyGC/MSPAHinEnviromentalMaterialPart1J．AnalChem19803065347－355．4．GC/MSJ．2009267－71．5SN1877．3－2007S．6DavidTCokerAlexanderGKingDirkLMumfordetal．CarcinogenicAssessmentsofPetroleumProductbyNeclearMagneticResonanceJ．AnalyticalCommunications1997345137－140．7．J．20091720－23．8HisaoATakasakiMasami．ProcessOilProcessforProdu-cingtheSameandRubberCompositionUS6605692P．2000－8－30．9TakashiKKazumitsuFYoshiyukiMetal．RubberProcessOilandProductionProcessThereofUS6248929B1P．2001－6－9．10AnaghaADavidOM．SelectiveRe－ExtractionofLubeExtractstoReduceMutagenicityIndexUS6146520P．2000－11－14．11JoisYajnanarayanaHKaushiketal．ProcessforMakingNon－CarcinogenticHighAromaticProcessOilUS2003/0168382A1P．2002－11－27．12．J．2007913－15．13．REACHJ．2010334258－261．14．J．2004418－21．15．J．20112657－11．16．J．201171－4．2013－01－17。20102。[e-mail]