BASF的氨基树脂和颜料系统的介绍1

12.08.20041巴斯夫特性化学品部PerformanceChemicalsPerformanceChemicalsPerformanceChemicalsPerformanceChemicalsPerformanceChemicalsPerformanceChemicalsPerformanceChemicalsPerformanceChemicalsPerformanceChemicalsPerformanceChemicalsPerformanceChemicalsPerformanceChemicalsPerformanceChemicalsPerformanceChemicalsPerformanceChemicalsPerformanceChemicalsPerformanceChemicalsforCoatings,PlasticsandSpecialtiesforPrintingIndustryforAutomotiveandOilIndustryforDetergentsandFormulatorsforTextilesforLeatherƒƒƒƒƒƒ卷材涂料配色系统与新颜料应用RuthGenuneit巴斯夫德国：全球技术经理－卷材涂料色料产品李杨巴斯夫中国：销售经理－涂料用特性化学品12.08.20043卷材涂料的最终用途－全球2002钢材建筑63.0%运输工具6.1%家用电器10.7%家具1.2%其它19.0%总量:14.917.000t钢材Source:ECCA12.08.20044卷材涂料的最终用途–全球2002铝材建筑60.0%运输工具16.0%家用电器3.6%家具0.3%其它20.1%总量:955.000t铝材Source:ECCA12.08.20045卷材涂料技术–欧洲2002水性面漆0.2%底涂20.0%背面涂层16.6%溶剂型面漆63.2%总量:157.654,8tSource:ECCA12.08.20046卷材涂料的面漆技术–欧洲2002聚酯62.3%硅改性树脂0.4%聚偏氯乙烯3.5%PVC22.4%聚氨酯9.8%其它1.6%Source:ECCA溶剂型面漆总量:99.601,7t12.08.20047卷材涂料技术–美国2001其它11%PVC12%聚偏氯乙烯10%硅改性聚酯5%水性1%聚酯61%Source:NPCA总量:174百万升12.08.20048卷材涂料－BASF产品„颜料z无机颜料z有机颜料z效果颜料„交联剂z氨基树脂12.08.20049卷材涂料－交联剂氨基树脂„Luwipal®066zHMMM三聚氰胺型z需要少量酸催化z附着力好z柔韧性好„Luwipal®072z部分甲醚化三聚氰胺型z交联密度高z柔韧性改良z光泽度高23456123456063069072073068066betterstoragestabilityhigherreactivityinacidicconditionslowerviscositybetterresistancetohydrolysisbetterexternalcrosslinkingbettersuitabilityforhigh-solidscoatingshigherreactivity(uncatalyzed)highertendencytoself-condensationhigherfilmhardnesshigher-NHcontentmolarratioalcohol:melamineMolarratiooffromaldehyde:melamine12.08.200410卷材涂料－交联剂氨基树脂„Luwipal®B017z苯代三聚氰胺型z适用于底漆z附着力优良z柔韧性优良z硬度优良z耐化学性能极佳CompositionbutylatedbenzoguanamineLuwipalresin®234512345B017betterstoragestabilityhigherreactivityinacidicconditionslowerviscositybetterresistancetohydrolysisbetterexternalcrosslinkingbettersuitabilityforhigh-solidscoatingshigherreactivity(uncatalyzed)highertendencytoself-condensationhigherfilmhardnesshigher-NHcontentmolarratioalcohol:melaminemolarratioofformaldehyde:melamine12.08.200411卷材涂料－颜料选择的选择标准„热稳定性„遮盖力„耐候性„分散性„流变性„抗絮凝12.08.200412热稳定性温度高于200oC,有可能破坏有机颜料的结构颜料颗粒部分溶解会导致耐光和耐候性能变差12.08.200413遮盖力/着色强度Paliotol®YellowL1820Paliotol®YellowL1970Paliotol®YellowL2140HD12.08.200414分散性取决于„硬度„颗粒大小„颜料表面状态„基料的粘度„基料的类型„分散设备12.08.200415流变性取决于„颜料的化学结构„颜料含量„颗粒大小„比表面积例如:Sicopal®YellowL110013m²/gPaliotol®YellowL2140HD25m²/g12.08.200416BASF颜料命名规则Heliogen®BlueL6905F商品名色相主要应用领域L=油漆D=印刷油墨K=塑料S=特性化学品BASF色环中相对应的位置F=抗絮凝D=易分散H=遮盖力优良S=耐SO290-9980-8970-7950-5940-4930-3920-2900-0910-1960-69主要应用领域特定性能12.08.200417无机颜料-Sicopal®„Sicopal®黄颜料z钒酸铋z鲜艳的偏绿相和红相的黄颜料z耐候性好z遮盖力高„Sicopal®黑，蓝，绿颜料z由无机氧化和尖晶石结构混合而成的颜料z耐热性极佳z耐候性极佳z钴蓝颜料对UV的吸收有一定的限度12.08.200418无机颜料-Sicopal®„Sicopal®Black0090P.Bk.27„Sicopal®YellowL1100P.Y.184„Sicopal®YellowL1600P.Y.184„Sicopal®BlueK6310P.B.28„Sicopal®BlueK7210P.B.36„Sicopal®GreenK9710P.G.5012.08.200419无机颜料–Sicotan®„由无机氧化和金红石结构颜料混合而成„遮盖力很高„耐热性优异(500℃)„耐候性优异12.08.200420无机颜料–Sicotan®„Sicotan®YellowL1010P.Y.53„Sicotan®YellowL1012P.Y.53,有光泽的„Sicotan®YellowL1910P.Br.24„Sicotan®YellowL1912P.Br.24,有光泽的„Sicotan®YellowL2010P.Br.24„Sicotan®YellowL2110P.Br.24„Sicotan®YellowL2107P.Br.24,有光泽的„Sicotan®BrownK2611P.Y.16412.08.200421混合颜料－Paliotan®„混合颜料是钒酸铋和高性能有机颜料的混合物„遮盖力高„饱和度高„着色力强„耐候性好12.08.200422混合颜料－Paliotan®„Paliotan®YellowL1145„Paliotan®YellowL1645„Paliotan®YellowL1945„Paliotan®YellowL204512.08.200423有机颜料–Paliotol®„Paliotol®Yellowz喹啉酮和异吲哚啉z耐热性好z分散性好z冲淡后耐候性会减弱„Paliotol®YellowL0962HDP.Y.138„Paliotol®YellowL2140HDP.Y.139