阿尔法烯烃的基础油-英力士

ImprovedEfficiencythroughtheuseofSpecialViscosityPolyalphaolefinsDr.LionelD.MooreAssociateResearchChemist,TechnicalSupportPAOBaseFluids,INEOSOligomersMichelSanchezPAOCustomerTechnicalServiceManager,Europe,MiddleEast&NorthAfricaINEOSOligomersEngineLosses:70%ParasiticLosses:5%e.g.waterpump,alternator,etc.DrivetrainLosses:5%IdleLosses:3%Powertowheels:17%FuelEnergy:100%exhaustheat,friction,etc.Theautoindustryismovingtoimprovefuelefficiency.Today’sautosoperateat17-21%efficiency.Thereismuchpotentialforimprovement.AutoFuelEfficiencyCanBeImprovedTurbo-chargerMulti-speedtransmissionDualclutchtrasmissionBeltCVTPlug-inHybridTailpipeemissionsCO2HardwarechangesreduceCO2EmissionsElectricViscosityGradeHTHS@150°CKV@100°C(cSt)CurrentSAEX-W302.9min.9.3mm2/s-12.5CurrentSAEX-W202.6min.5.6mm2/s-9.3NewSAEX-W202.6min.6.9mm2/s-9.3NewSAEX-W162.3min.6.1mm2/s-8.2LowViscosityGradesImproveFuelEconomySource:SAEJ300engineoilclassification,April2013ConstantStructure/QualityReducedEmissionsLowFrictionLowVolatilityExcellentHydrolyticStabilityExcellentLowTemperaturePropertiesCompatiblewithotherBaseoils&ElastomersHighThermal/OxidativeStabilityPAOHighShearStabilityAllowsLongDrainIntervalsPAOs–wellsuitedforLowViscosityOilsPolyalphaolefinsLegislationhasbeeninstitutedregulatingallaspectsofGreenhouseGasEmissionsRawMaterialProductionRecyclingVehicleOperationLegislationVehicleManufactureFuelEconomyMandatesEmissionRestrictionsWeightRegulationsSource:ICCT34.2mpgby201547mpgby2020TheGlobalMarchTowardsLowerCO2EmissionsSource:ICCT54.4mpgby2025TheGlobalMarchTowardsLowerCO2EmissionsSource:ICCT95gCO2/kmforpassengercarsby2020(69.1mpg)TheGlobalMarchTowardsLowerCO2EmissionsHDPEFuelTankGrangemouth,UKGeel,BELillo,BENOHTechCenter,BESarralbe,FRKoeln,DEBamble,NOLavera,FRRosignano,ITCarson,CA,USGainesCounty,TX,USAlvin,TX,USLaPorte,TX,USLowrollingResistancetires●MobilAlabama,USA●●●AntwerpBEGladbeckDEMarlDE●SinopecINEOSJVEthanolFromrefuseVeroBeachFlorida,USCarbonFiberSheetBoeing787usescarbonfibercompositesCompositeframe&bodypanelsLimaOhio,USALisleIllinois,USAGreenLake,TexasUSAPointComfort,TexasUSALeagueCity,TexasUSAHouston,TexasUSATampico,MexicoKöln,GermanyAntwerp,BelgiumSealSands,UKUlsanKoreaSeoulKoreaSingaporePasirGudangMalaysiaTHEWORLD’SLARGESTINTEGRATEDPRODUCEROFLOWANDHIGHVISCOSITYPOLYALPHA-OLEFINSApplicationsforPAOinclude:Multi-gradegearoils7W-90/75W-140LowviscositytransmissionoilsIndustrialoilscompressor/gear/circulatingAutomotiveoils5W-20/0W-20/0W-16HeavyDutyDieselOilsManyotherswherehighperformanceisrequiredINEOSOligomersistheworld’slargestmerchantsupplierofPAOFeluy,BelgiumNewPAOtrainaddedin200915%debottleneckplannedLaPorte,TX,USA10%debottleneckcompletedAdditionaltrains/plantsalignedwithmarketrequirementsNaturalGasEthaneEthyleneLinearAlphaOlefinsHexeneC6H12OcteneC8H14DeceneC10H20DodeceneC12H24TetradeceneC14H28HexadeceneC16H32OctadeceneC18H36INEOStoExpandAlphaolefinSupplyINEOSbasicinLAODrillingFluidsDetergentsPolyethylenecomonomersPAOfeedstocksINEOSExpandsAlphaolefinSupplyNewUSplantbuildcommencedGulfCoastlocation,350KT500KTAdvantagedEthylene(ShaleGas)IncrementalexpansionsalsoplannedatJoffreCanadaandFeluyBelgiumINEOSJoffre,CanadaINEOFeluy,BelgiumDurasynPAO162164166168170Viscosity,cSt,100°C(mm2/s)1.74.05.97.89.7Viscosity,cSt,40°C(mm2/s)5.117.731.047.063.0Viscosity,cSt,-40°C(mm2/s)260270077001700037000ViscosityIndex--123136138139FlashPointCOC(°C)162225240250260Brookfield-40°C(cP)--210069501692026900CCSViscosity-30°C(cP)--850237051108250CCSViscosity-35°C(cP)--14504190888015520NoackVolatility(%wtloss)99.013.56.53.53.0PourPt,(°C)-70-66-60-56-50DurasynPAO145146147148Viscosity,cSt,100°C(mm2/s)5.15.97.07.7Viscosity,cSt,40°C(mm2/s)25.330.238.544.0Viscosity,cSt,-40°C(mm2/s)496768641100014000ViscosityIndex143145145147FlashPointCOC(°C)240250255262ColdCrankViscosity-30°C(cP)1480195030203580ColdCrankViscosity-35°C(cP)2525332050607000NoackVolatility%wtloss4.94.23.22.0PourPt,°C-45-45-43-40ProposedViscosityGradesBelowSAE20ViscosityGradeHTHS@150°CKV@100°C(cSt)ProposedSAE152.3min.5.6mm2/s-9.3ProposedSAE102.0min.5.6mm2/s-9.3ProposedSAE51.7min.5.6mm2/s-9.3Source:MCovitch,etal.,ExtendingSAEJ300toViscosityGradesbelowSAE20BoundaryLubricationHydrodynamicLubrication1/3ofenginelosses2/3ofenginelosses●●0.00.51.01.52.02.53.03.5OW-165W-205W-3010W-3010W-40FuelEconomyTrendMovingfrom10W-40to0W-16EngineOilViscosityGradeSource:J.Jeter,Honda,SAEFuelsandLubricantsOpenForumApril21,2009+1.5%FuelEconomyImprovement0W-205W-30SequenceVI-D%FuelEconomyvs.OilViscosityGradeSource:FLockwood,FuelEconomyandEngineDurability,Ashland/Valvoline,April2012+1.5%12PAOTypeNon-DeceneDecene6mm2/sPAOusedDurasyn146Durasyn166Viscosity,mm2/s,100°C7.16.9PourPoint,°C-54-54NoackVol%wtloss8.08.8CCS-35°C(cP)4,8705,080HTHS150°C(mPa●S)2.62.6FullyformulatedoilsusingindicatedPAO6+PAO4,shearstableVII,TMPEster,andEuropeanadditivepackageSAE0W-20Range6.91562002.6PAOsEasilyMeet0W-20ViscometricRequirementsOW-20FullSyntheticGroupIIIoilsneedPAOtomeet0W-20oilrequirementsFormula(wt%)GroupIIIGroupIII+PAOBet