对臭氧氧化处理含氰废水影响因素的研究

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©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.():,pH,,pH:,[1-4]:,CODBOD,,,,,NO,,,,,100%1[5,7,8](pH7):O3+H2O+hO2+H2O2H2O2+h2OH,O3:1.1,1.2,OH,1.3,,,,,1000:CN+O3CNO-+O3,:CNO+OH+H2OCO2+NH322.1:CN-20mg/L,pH9.5,25-302.2:RS0-9805,0.8g/L;15cm,77cm();2.3:2700mL,pH,,,(20m),2.4,NaOH,0.5NaOH,2.512.6;,(12345678)1Fig1Theflowchartoftheexperiment33.1(20),(100L/h,200L/h,300L/h,400L/h,20%,30%,40%,70%),,124520081©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(:mg/L)Table1ConcentrationsofO3indifferentconditions(L/h)10020025030040020%4.6012.5672.2161.7801.42230%4.0802.0422.0831.5981.20140%3.5482.3001.8531.5621.17570%2.9061.7561.5861.3081.0292Fig.2Mapofimpactofairhumidityandair,,Q=100L/h,,,=20%3.2300L/h,,23:2Table.2TherelationofO3withairtemperaturet()20.026.528.0(mg/L)1.5621.2201.1043Fig.3Mapofimpactofairtemperature,,1,0.06mg/L,,,20,40%,300L/h,1.562mg/L,1.5623300=468.6mg/L3.3,34:3Table3Therelationofthetimewitheffeciencymin0204060%040.1277.6995.454Fig.4Mapoftherelationofthetimewitheffeciency,,,T=45min,,45min,93%3.4PHPH45:4PHTable4therelationofPHwithefficiencyPH678910%8687.191.293.491.85PHFig.5MapoftherelationofPHwithefficiency5520083©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.=468.6mg/L4.3,,T=45min,,93%4.4PH,9.5,PH,,PH9.5,[1].[J].,1998,16(3):13-16.[2],.[J].,1995,3(6):18-24.[3].[J].,1996,9:17-35.[4].[J].,1998,82(3):1-4.[5],..,1995(5):3.[6],..,2000(2):2.[7]MA,BB...:,1987.2834,46,102-103.[8].20[J].,2000,21(1):46-49.[9].[J].,1999,19(3):16-27.[10]Ting2shengQiu.StudyonNewProcessofZeroDischargeofCyanidewastewater(A).theInter.Sym.EastAsianRes.RecyclingTech.[C].Korea:TheKoreaInstituteofResourcesRecycling,2001.[11].[J].,1991.[12].[J].,2003,5(01).[13].[J].,2005-05-01.6520081

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