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22820058FINECHEMICALSVol.22,No.8Aug.200531,2,1,1(1.,100083;2.,434023):,,,Gemini41:;Gemini;;:TQ423.34:A:1003-5214(2005)08-0578-05ProgressintheInvestigationofSulfonateSurfactantsZHENGYan2cheng1,2,HANDong1,YANGPu2hua1(1.ResearchInstituteofPetroleumExplorationandDevelopment,EORDepartment,Beijing100083,China;2.InstituteofChemistryandEnvironmentEngineering,YangtzeUniversity,Jingzhou434023,Hubei,China)Abstract:Thedevelopmentandprogressofthevarietiesandsyntheticprocessesofsulfonatesurfactantsincludingalkanesulfonate,fattyacid(ester)sulfonate,polyoxypropylenesulfonate,dialkyldiphenyletherdisulfonate,dimericsulfonatesandarylalkanesulfonateathomeandabroadweresummarized,andthesurfacepropertiesofsomesulfonateswereintroducedinthispaper.41referencesarecited.Keywords:sulfonatesurfactants;Geminisurfactants;sulfonation;surfaceproperties,,[1]:();();;();(),[2]3:,,,,1[37][811],,,,C14C16,22.12(AOS)[1214]:2060,2SO3,:RCHCHCH2SO3Na,60%;RCHOHCH2CH2SO3Na,30%;,10%AOS,AOS/,,(AS),,,AOS3:2004-06-25;:2004-12-05:(1965-),,,,,:010-62098375,E-mail:zhengycg@163.com,2.2[15]Buschmann1,22,Mukerjee,12(CMC)813mmol/L,2036mN/m;21,2221,52CMC2045mmol/L,3444mN/m,3()3.1[16,17]::(1)()();(2)()(),()(2735mN/m),,;,,,3.22()C12C20,(lauricacid,C12)(myristicacid,C14)(palmiticacid,C16)(stearicacid,C18)(behenicacid,C22),()[18,19]:SO3[20]SO3[21,22]ClSO3H[2123],,()2,,,SO3,1121125,,[24]Kanggs[25]:(),2,3.3[26](cocylisethionate),,Frosch,,pH,,:(1)22-90120(2)(3)2004()4.1()[27,28],(AES),:R,(PO),CMC,PO,R,CMCCMC,RHC5H11,CMC71510-4mol/L51110-4mol/L,,39mN/m3715mN/m4.2[29]3:9758,:55.1[30],,:n=212,,Williamson,,,n11,,n,,n=12,50mN/m1Table1PropertiesofdisulfonateddiphenyloxidesurfactantsnKrafft//CMC/(mol/L)CMC/(mN/m)/nm2-logc4251.010-2--1.65628254.310-360.64.61.85105940--2.62.241059602.010-354.5(60)7.52.241270701.010-349.8(70)7.62.445.2[31],NaClO//:22c(NaCl)=0.1mol/L(R=C12H25,25)Table2Solutionpropertiesofdisulfonatedsurfactantsinc(NaCl)=0.1mol/LMAMSDADSMADSC12H25SO3NaCMC/(mol/L)3.210-51.010-53.710-42.510-3CMC/(mN/m)29.640.051.0Amin/(nm2/mol)0.481.010.751,,,2,,DADSMADS,,,,,MAMSDADSMADS,MAMS66.12SO34060,,[32]RCHR2SO3HCHRR2SO3H(a)R1CHCHCSO3HH(CH2)nSO3H(b),,6.2(spacegroup),(oligomericsurfactant),Gemini[33]:SO3ClSO3HSO26.2.1SO3[34,35]:C12H25CHCH2SO3NaOOC(CH2)nCOOCHCH2SO3NaC12H25(c)H21C10OOSO3NaSO3NaOOC10H21(d)H15C7SO3NaOOOOSO3NaC7H15(e)(c),085FINECHEMICALS22:SO3,w(NaOH)=10%,21%22212,160190(d):SO3,70,9030min,85,1206h,,NaHCO3,(d)(e):C8H17COOCH3SO3/Air4530min80C7H15CSO3NaHCOOCH3HOOH140e6.2.2[3638]1,22(f)(g),(f):(g)2mol21mol(),Pd/C6.2.3ClSO3HZhuyunpeng[39]Gemini:(,41)10mol/LNaOH402d,5mol/L,20h,,;,0,R,Krafft0,7(AASA),,,,2Gemini,:Bergar,Paul[40,41]:12SO3(),()1858,::(1);(2);(3),-(ASP)(4),,8,,,,,,(),,,,,,,:[1].[M].:,30-43.[2],.[J].,2002,25(4)17-20.[3],.[M].:.[4],.[M].:,115-120.[5].[J].,2002,(1):8-10.[6].[J].,2000,16(12):1-5.[7],,,.[J].,2003,22(4):355-341.[8],.AS[J].,2000,26(6):657-660.[9]DoePH.El2Emarymahoud,WadeWH.Surfactantsforproducinglowinterfacialtensions.Linealkylbenzenesulfonates[J].JAOCS,1977,54(12):570-577.[10]BudhramRS,EisenbraunEJ.Synthesisandrigorouspurificationofsodiumalkylbenzenesulfonates[J].JAOCS,1985,63(10):1392-1394.[11]NMvanOs,RKok,TABMBolsman.Alkylarenesulphonates:theeffectofchemicalstructureonphyisco2chemicalproperties[J].TensideSurfDet,1992,29(3):175-188.[12]DavidWRoberts.Sulfonationtechnologyforanionicsurfactantmanufacture[J].OrganicProcessResearchDevelopment,1998,2(3):194-202.[13],.[J].,1994,(2):13-17.[14]WeilJK.Sulfonationofhexadecane-1andoctadecene-1[J].JAOCS,1965,42(10):873-875.[15]BuschmannN,StarpH,Munster.Titrimetricdeterminationofparaffinsulfonates[J].TensideSurfDet,1997,34(2):84-94.[16],.[J].,2001,29(6):16-21.[17].[J].,2000,(4):10-11.[18]WeilJK,BistlineRG.Sodiumsaltsofalkyl2sulfopalmitatesandstearates[J].JAmChemSoc,1953,75:4859.[19]KaoruYamada,ShigeakiMasutani.Analysisofthedark2coloredimpuritiesinsulphonatedfattyacidmethylester[J].JAOCS,1996,73(1):121-125.[20]KapurBL,SolomonJM.Summaryofthetechnologyforthemanufactureofhighalph-sulfofattyacidesters[J].JAOCS,1978,55:549-557.[21]PaubertM,CanselierToulouseJP.Sulphonatesderivedfromdimmeracidsandesters[J].TensideSurfDet,1995,32(1):36-44.[22].[J].,1997,(6):17-18.[23].[J].,2001,(11):17-18.[24].C16C18[J].,1996,(2):30-34.[25]KnaggsEA,YeagerJA.Alphasulfofattyestersinbiologicallysoftdetergentformulations[J].JAOCS,1965,42:805-808.[26]DaradicsL,DaradicsZ.Synthesisandanalysisoffattyacidacylestersulphonates[J].TensideSurfDet,2001,38(5):282-286.[27]ChleblickiJ,Wroclaw.Polyoxypropylalkylphenolsulphate[J].TensideSurfactantDetergent,1990,27(6):413-416.[28]RosenMiltonJ,ZhuYunpeng.Efeectofhardriverwateronthesurfacepropertiesofsurfactants[J].JChemEngData,1996,41:1160-1167.[29]FabryB,Dusseldorf.Innenst¾ndigeOleylethersulfonateaufBasisnativerFettalkohole[J].TensideSurfDet,1992,29(5):320.[30]RosenMiltonJ,BaumMichael.Therelationshipofstructuretopropertiesinsurfactants:.Synthesisandpropertiesof,2bis(sodiump-sulfophenoxy)alkanes[J].JAOCS,1976,(12):742-746.[31]RosenMiltonJ,Zhenhuazhu,Xiyuanhua.Relationshipofstructuretopropertiesofsurfactants.1