大学无机化学重要化学方程式1不含全部配位反应、鉴定反应、要从同类反应(未全包括)中找出规律1.XeF6+3H2O==XeO3+6HF2.NaBrO3+XeF2+H2O==NaBrO4+2HF+Xe3.2F2+2H2O==4HF+O24.2F2+2OH—(2%)==2F—+OF2+H2O5.2KHF2电解2KF+H2↑+F2↑6.2NaCl+2H2O电解2NaOH+H2↑(阴极区)+Cl2↑7.2IO3―+5HSO3—==5SO42—+I2+3H++H2O8.CaF2+H2SO4(浓)==CaSO4+2HF9.NaCl+H2SO4(浓)==NaHSO4+HCl↑10.Rb[ICl2]==(加热)RbCl+ICl11.2HIO3==(加热)I2O5+H2O↑12.I2O5+5CO==I2+5CO213.I2+10HNO3==2HIO3+10NO2↑+4H2O14.2Cl2+2Ca(OH)2==Ca(ClO)2+CaCl2+2H2O15.IO3―+5I―+6H+==3I2+3H2O16.3Cl2+6NaOH(850C)5NaCl+NaClO3+3HO17.O3+2I―+H2O==O2+I2+2OH—大学无机化学重要化学方程式218.S2O82—+2H2O==H2O2+2HSO4—19.Cl2+H2O2==2HCl+O2↑20.2KMnO4+5H2O2+3H2SO4==2MnSO4+K2SO4+5O2↑+8H2O21.Al2S3+6H2O==2Al(OH)3↓+3H2S↑22.2KHSO4==K2S2O7+H2O23.Fe2O3+3K2S2O7==Fe2(SO4)3+3K2SO424.2NaHSO3+Zn==Na2S2O4+Zn(OH)225.AlCl3·6H2O+6SOCl2==AlCl3+6SO2↑+12HCl26.2KMnO4+5H2S+3H2SO4==2MnSO4+K2SO4+5S↓+8H2O27.Na2S2O3+I2==Na2S4O6+2NaI28.Na2S2O3+2HCl==2NaCl+S↓+SO2↑+H2O29.Na2S2O3+4Cl2+5H2O==2NaHSO4+8HCl30.SX2―+2H+==H2S+(x-1)S↓31.PbS+4H2O2===PbSO4+4H2O32.Ag++S2O32-(少量)→Ag2S2O3↓+H2O→Ag2S↓+H2SO433.Na2O2+H2O==H2O2+2NaOH34.NH4Cl+NaNO2==(加热)N2↑+2H2O35.(NH4)2Cr2O7(加热)==N2↑+Cr2O3+4H2O36.2NH3+3CuO==(加热)3Cu+N2↑+3H2OCO+CuO==(加热)Cu+CO2↑37.NO2—+2I―+4H+==2NO+I2+2H2O38.2MnO4-+5NO2-+6H+===2Mn2++5NO3-+3H2O大学无机化学重要化学方程式339.Au+HNO3+4HCl==H[AuCl4]+NO↑+2H2O40.3Pt+4HNO3+18HCl==3H2[PtCl6]+4NO↑+8H2O41.2KNO3(加热)==2KNO2+O242.2Pb(NO3)2(加热)==2PbO+4NO2↑+O2↑2Cu(NO3)2(加热)===2CuO+4NO2↑+O2↑43.2AgNO3(加热)==2Ag+2NO2↑+O2↑44.4HNO3(光照)==4NO2↑+O2↑+2H2O45.3Ag+4HNO3(稀)==3AgNO3+NO↑+2H2O46.3PbS+8HNO3(稀)==3Pb(NO3)2+3S↓+2NO↑+4H2O3Ag2S+8HNO3==6AgNO3+3S↓+2NO+4H2O.47.PBr3+3H2O==3HBr+H3PO3(P+Br2+H2O→)48.PCl3+3H2O==H3PO3+3HClPCl5+4H2O==H3PO4+5HCl49.NCl3+3H2O==NH3+3HOCl50.As2S3+6NaOH==Na3AsO3+Na3AsS3+3H2O51.CaF2+3H2SO4(浓)+B2O3==3CaSO4+3H2O+2BF352.SiO2+4HF==SiF4↑+2H2O53.H3BO3+3CH3OHH2SO4B(OCH3)3+3H2O54.B2O3+3Cl2+3C===2BCl3+3CO55.3SiF4+2Na2CO3+2H2O==2Na2SiF6↓+2CO3+H4SiO456.B4H5(OH)42-+5H2O==2H3BO3+2B(OH)4-57.Si+2NaOH+H2O==Na2SiO3+2H2↑大学无机化学重要化学方程式458.CaSiO3+6HF==CaF2+SiF4+3H2O59.CO+PdCl2+H2O====CO2+Pd↓+2HCl60.SnS(As2S3、Sb2S3)+Na2S2==Na2SnS361.SnS2(As2S5、Sb2S3、Sb2S5)+Na2S==Na2SnS362.2Na2O2+2CO2====2Na2CO3+O263.CaH2+2H2O==Ca(OH)2+2H2↑64.Sn+4HNO3(浓)==SnO2·2H2O↓+4NO2↑65.PbO2+2H2SO4===2PbSO4+O2↑+2H2O66.PbO2+4HCl→PbCl2+Cl2↑+2H2O67.Bi(OH)3+Cl2+3NaOH==NaBiO3+2NaCl+3H2O68.2Cu+O2+H2O+CO2==Cu(OH)2·CuCO369.2Cu2++4I―==2CuI↓+I270.Cu2O+H2SO4→Cu+CuSO471.2[Cu(OH)4]2—+R-CHO==Cu2O↓+R-COOH+4OH—+2H2O72.HgCl2+2NH3===Hg(NH2)Cl↓+NH4Cl73.Hg2Cl2+2NH3→Hg↓+Hg(NH2)Cl↓+NH4Cl74.Hg22++2OH-(S2—、I—)==Hg↓+HgO↓+H2O75.Hg(NO3)2+4KI==2KNO3+K2[HgI4]76.Hg2Cl2+H2S==Hg↓+HgS↓+2HCl77.HgCl2+SnCl2(适量)====SnCl4+Hg2Cl2↓(白色)Hg2Cl2↓(白色)+SnCl2==2Hg↓+SnCl478.2Mn2++5S2O82―+8H2OΔ16H++10SO42―+2MnO4―大学无机化学重要化学方程式579.Mn2++5BiO3-+14H+===2MnO4-+5Bi3++7H2O80.5PbO2+2Mn2++6H+==5Pb2++2MnO4-+2H2O81.2MnO4-+5C2O42-+16H+==2Mn2++10CO2↑+8H2O82.3MnO2+KClO3+6KOH===3K2MnO4+KCl+3H2O83.MnO2+2H2SO4===2MnSO4+O2↑+2H2O84.Cl2+2K2MnO4==2KMnO4+2KCl85.2KMnO4+16HCl→2KCl+2MnCl2+5Cl2↑+8H2O86.MnO4-+SO32-(酸性、中性、碱性)→87.MnO2+4HCl→MnCl2+Cl2↑+2H2O88.2CrO2-+3H2O2+2OH-==2CrO42-+4H2O89.3Na2O2+2CrO2-+2H2O===2CrO4-+6Na++4OH-90.Cr2O72-+4Ag++H2O==2Ag2CrO4↓+2H+91.Cr2O72-+3SO32-+8H+==2Cr3++3SO42-+4H2O92.V2O5+6NaOH===2Na3VO4+3H2O93.V2O5+6HCl===2VOCl2+Cl2↑+3H2O94.TiO2+6HF==H2[TiF6]+2H2O95.2Ni(OH)2+Br2+2OH-==2Ni(OH)3↓+2Br-96.2Co(OH)3+6HCl==2CoCl2+Cl2↑+6H2O97.Fe2(SO4)3+SnCl2+2HCl==2FeSO4+SnCl4+H2SO498.2Fe3++2I-===2Fe2++I299.2FeCl3+H2S==2FeCl2+S+2HCl100.Cr2O72-+6Fe2++14H+==2Cr3++6Fe3++14H2O