硅烷偶联剂在涂料中的应用及其进展(1)

1419Vol114,No1192006106FineandSpecialtyChemicals3(,430072):,,20041t/a,8000t,,20102t/a:;;;ApplicationandProgressofSilaneCouplingAgentinCoatingsLIAOJun,CHENSheng2yun,LIUYing2wei,LIUChao(WuhanUniversitySiliconeNewMaterialCo.,Ltd.,Wuhan430072,China)Abstract:Themechanismofaction,commonvarietyofsilanecouplingagentanditsapplicationincoatingswerein2troduced.TheproductionandmarketsituationofsilanecouplingagentinChinawerebriefedalso.In2004,theproductioncapacityofChinassilanecouplingagentwasabout10thousandtonsperyear,andtheoutputwas8thousandtons.Itwasforecastedthattheproductioncapacitywouldreach20thousandtonsperyearbytheendof2010.Finally,thedevelopmenttrendofChinassilanecouplingagentincoatingswasanalyzed.Keywords:silanecouplingagent;coating;aminosilane;ureidosilane,,,,,,,,,5,1,RSiX3,R,X,,,1.11.1.1(1),,,,,SiOM(M),13:2006208231:(19712),,,,,,5,30,5141922006106,:,,22.1,4:1985,,,;19861995,,;19962000,,;20012005,,2.21996,30%2004,1t/a,8000t/a,2010,2t/a2000,100,,,,41000t/a30,:2.3,20048000t,,1500t,2010,2t/a,4%(19)32006106,:Intechem215,,Intechem21,,,,,,Intechem21,1618mN/m,(1115)10-4,DuPont1157,,90#,Intechem21,1,.M.:,19982.M.:,20013NobuoIshikawa,MikioSasabe.Surfaceactivesubstancescontaininganoligo(hexafluorupropeneoxide)chainasahydrophobicandoleophobicmoietyJ.JournalofFluorineChemistry,1984(25):2412534KalathilCEapen,ChristTamborski.Fluoro2Ketones..SynthesisofarylperfluoroalkyletherketonesbytheFriedel2CraftsacylationJ.JournalofFluorineChemistry,1979,4(1):2432525,,,.J.,1982,40(10):9459516GB/T7462294,Ross2MilesS(3)33.1,,,,3.2,,,,3.3,,,,,(1),,,:H2NCONH(CH2)3Si(OEt)3,(EtO)3Si(CH2)3NHCONH(CH2)6NCO,EtOOC(CH2)2HN(CH2)3Si(OEt)3,HOOC(CH2)2CONH(CH2)3Si(OEt)3(2),,,:(3),,:Me3N+(CH2)3Si(OMe)3Cl-,Me2N(CH2)3Si(OMe)3HOAc,,91