化学动力学的发展与百年诺贝尔化学奖

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20120052(610066)()13[1],,1322,13:[2]1,[3],1920,,,31850,Wilhelmy1867,Guld2bergWaage1980,vantHoffArrhenius,,,vantHoff,vantHoff[4]19011889,ArrheniusArrhenius,:k=Ae-Ea/RT[5]1903,Arrhenius[6]3Ostwald,Arrhenius,,1909,Ostwald[7]95,vantHoffArrheniusOstwald3,2202050,,32.1Arrhenius,2019,GoldschmidtArrhenius1909,Trautza=e-q/RT,[2]1918,Lewis,ArrheniusGoldschmidtTrautzLewis19,20302030,EyringPolanyi,,,[1],,Eyring,,2.21913,Bodenstein1918,NernstBodensteinHCl,,2020,,;19271928,Semenov,20Hinshelwood,,SemenovHinshelwood[8]1956HinshelwoodSemenov,,06,,,[3],2040,:,2.32050,Eigen,10-8s,NorrishPorter,s2060,10-6s10-1110-12s,1948Faraday10-3s,,EigenNorrishPorter1967[9]2.4,,,Hevesy[10]1943HevesyRutherford,Rutherford,D(210Pb),,,,,,,,,[11]32050,,2080,19862002107,163.120,,[12],(CPM)MoonBull,DatzTaylor2060,Herschbach,,,,,,,Polanyi,1986,HerschbachPolanyi[13]19551986,,,,3.22070,,(Femtochemistry)20Zewail2080,,Zewail[14]1999:Zewail,,[15],3.3,,,Taube,,Taube,[16]1983Marcus,261956,MarcusMarcus,,[17]1992Marcus1956,1992,3030,,Marcus3.4HoffmannWoodward,HoffmannWoodward,,Hoffmann[18]1981KohnPopleKohn1964,,[19]1998PopleGAUSSIAN,[19]1998KohnPople,3.5CrutzenMolinaRowland,,3,,[20]19951992199519983,,3,,20,2050,70,80,90[1],,361,,,..:,20042..:,19803..:,19844VanHoutenJ.JChemEduc,2001,78(12):15705..:,19906VanHoutenJ.JChemEduc,2002,79(1):217VanHoutenJ.JChemEduc,2002,79(2):1468VanHoutenJ.JChemEduc,2002,79(4):4149VanHoutenJ.JChemEduc,2002,79(5):54810VanHoutenJ.JChemEduc,2002,79(3):30111,..:,198712,,..:,199213VanHoutenJ.JChemEduc,2002,79(8):92614VanHoutenJ.JChemEduc,2002,79(12):139615..:,200116VanHoutenJ.JChemEduc,2002,79(7):78817VanHoutenJ.JChemEduc,2002,79(9):105518VanHoutenJ.JChemEduc,2002,79(6):66719VanHoutenJ.JChemEduc,2002,79(11):129720VanHoutenJ.JChemEduc,2002,79(10):1182(58)14RiceDC.Neurotoxicology,1993,14:16715SlomiankaL,RungbyJ,WestMJ,etal.Neurotoxicology,1989,10:17716BourjeilyN,SuszkiwJB.BrainRes,1997,771:31917EdelmanGM.AnnuRevCellBiol,1986,2:8118BhattacharyaA,ShuklaR,DictrichKN,etal.Neurotoxicology,1993,14:17919FinkelsteinY,KofflerB,RabeyJm,etal.BrainRes,1985,343:31420ChenHH,MaT,HumeAS,etal.BiomedEnvironSci,1998,11(1):6121,,,.,2002,31:32622MurakamiK,FengG,ChenSG.JPharmacolExpTher,1993,264(2):75723GilbertME,MackCM,LasleySM.Neurotoxicology,1999,20(1):7124,,,.,1997,11(37):18025Cory2SlechtaDA,PoundJG.LeadNeurotoxicity.in:ChangLW,DyerRSed.HandbookofNeurotoxicology,Chap2.NewYork:MarcelDekker,1995,618926WinderC,BoninT.MutatRes,1993,285:11727,,,.,2000,18:5128,,,.,2000,18:7529FinkelsteinY,MarkowitzME,RosenJE.BrainResBrainResRev,1998,27:16830NiheiMK,GuilarteTR.BrainResMolBrainRes,1999,66:4231,,,.,2002,36:3046

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