全固态锂电池技术的研究现状与展望

2420137EnergyStorageScienceandTechnologyVol.2No.4Jul.20131121213152012100192/doi10.3969/j.issn.2095-4239.2013.04.001TM911A2095-4239201304-331-11All-solid-statelithium-ionbatteriesState-of-the-artdevelopmentandperspectiveXUXiaoxiong1QIUZhijun1GUANYibiao2HUANGZhen1JINYi21NingboInstituteofMaterialsTechnologyandEngineeringChineseAcademyofSciencesNingbo315201ZhejiangChina2ChinaElectricPowerResearchInstituteStateGridBeijing100192ChinaAbstractConventionallithium-ionsecondarybatterieshavebeenwidelyusedinportableelectronicdevicesandarenowdevelopedforlarge-scaleapplicationsinhybrid-typeelectricvehiclesandstationary-typedistributedpowersources.However,thereareinherentsafetyissuesassociatedwiththermalmanagementandcombustibleorganicelectrolytesinsuchbatterysystems.Thedemandsforbatterieswithhighenergyandpowerdensitiesmaketheseissuesincreasinglyimportant.All-solid-statelithiumbatteriesbasedonsolid-statepolymerandinorganicelectrolytesareleak-proofandhavebeenshowntoexhibitexcellentsafetyperformance,makingthemasuitablecandidateforthelarge-scaleapplications.Thispaperpresentsabriefreviewofthestate-of-the-artdevelopmentofall-solid-statelithiumbatteriesincludingworkingprinciples,designandconstruction,andelectrochemicalpropertiesandperformance.Majorissuesassociatedwithsolid-statebatterytechnologiesarethenevaluated.Finally,remarksaremadeonthefurtherdevelopmentofall-solid-statelithiumcells.Keywordsenergystorageall-solid-statelithium-ioncellsolidelectrolyteinterfacemodification1                                                               [e-mail] DOENEDO332201322000[1-3][4][5]/MW100kW[6-7]/1[8]2010A123SystemsH-APU44MWAESEVONIK 1Fig.1Schematicdiagramoflithium-ionbatteriesinenergystorageengineering1MW[9]20113/333412050[10-12]2 2Fig.2Schematicillustrationofanall-solid-statelithiumcell[13]11[14-15][10]331Table1Characteristiccomparisonofvaciouskindsoflithium-basedsecondarycellsPEOPC+LiPF3C33420132      aLiMn2O4/liquidelectrolytebLiCoO2/liquidelectrolyte  call-solid-statelithiumwithLiCoO2anode3Fig.3Aschematicdiagramonasafetytestofdifferentlithiumionbatteries[10-12]12V24V2RFC2020KOLIBRI44 4Fig.4Developpmenttrendoflargescalelithium-basedcellsinthenexttwodecades33545VDRFSRFMSCVDESDPLD 5[16-17]Fig.5ThinfilmbatteriespreparedbypulsedlaserdepositionsPLD[16-17]1982Hitachi10μm[18]Ever-readyBellcoreORNLLiPONOakRidgeNationalLabORNLLiPONLi3PO4LiPON10μA/cm240000[19-21]InfinitePowerSolutionsIPSCymbet2010IPS60.17mmDOD100%1C1000070C1%–4085RFID[22]207030[23-25]LiNi1/3Mn1/3Co1/3O2Daiso20152LiFePO4polyethyleneoxidePEOLi4Ti5O12[26]KOLIBRIPEO[27]KOLIBRI97300kg55kW1.4L90km600kmPEOPEO33620132PEOPEO[28-30]22Table2Technicalparametersoflargescaleinorganicall-solid-statelithiumcellsininternationalmajorresearchinstitutesCompanyDesignideaCathodeElectrolyteAnodeEnergydensity/W·h·kg–1Powerdensity/W·kg–1ProgressToyotaflattypeLiCoO2Li10GeP2S12graphitetypeabout3001200trialproductIdemitsuKosanflattypeLiNi0.8Co0.15Al0.05O2Li2S-P2S5lithiumindiumalloyabout2501000trialproductSamsungYokohamaInstituteflattypeLiNi0.8Co0.15Al0.05O2Li2S-P2S5graphitetype300times85%left16.4V4.1V×416.26V4.065V/Li7P3S11LiCoO2LiMn2O42010A6A641416V100μm100150W·h/kg300W·h/kg2012LiNi0.8Co0.15Al0.05O2Li2S-P2S50.5mA/cm2105mA·h/g30085400μm/6LiCoO20.3A·h0.2C120mA·h/g8mΩ·m2[31]33374 6LiCoO2Fig.6Initialcharge-dischargecurvesandcompleximpedanceplotsofall-solid-statelithiumcellsusingLiCoO2asacathodematerial/1SEISEI[32-34][35]77(a)Li-P-S-Li-Ge-P-SLi2S-P2S510–3S/cm 7abFig.7aAschematicdiagramandbaequivalentcircuitofpolycrystallinesolidelectrolytesinahalfcell33820132[36-39]thio-LISICONlithiumionsuperioniccondutors2.210–3S/cm/LiCoO2thio-LISICONLiCoO2/[36]LiMO2M=CoNi8/8//[38-39] 8Fig.8Thediagramofpotentialchangeintheheterojunctionbetweenaionicconductorandsemiconductor/[40-42]99/[43-45]3394 9Fig.9Thedesignandconstructionofall-solid-statelithiumcellsbasedoninorganicmaterials4/[1]ZhangWenliangWuBinLiWufengLaiXiaokang.DiscussionondevelopmenttrendofbatteryelectricvehiclesinChinaanditsenergysupplymode[J].PowerSystemTechnology20093341-5.[2]HuYingyingWenZhaoyinRuiKunWuXiangwei.State-of-the-artresearchanddevelopmentstatusofsodiumbatteries[J].EnergyStorageScienceandTechnology20132281-90.[3]PengJiayueZuChenxiLiHong.FundamentalscientificaspectsoflithiumbatteriesIThermodynamiccalculationsoftheoreticalenergydensitiesofchemicalenergystoragesystems[J].EnergyStorageScienceandTechnology20132155-62.[4]ZhangWenliangQiuMingLaiXiaokang.Applicationofenergystoragetechnologiesinpowergrids[J].PowerSystemTechnology20083271-9.[5]LuXiaLiHong.FundamentalscientificaspectsoflithiumbatteriesII—Defectchemistryinbatteriesmaterials[J].EnergyStorageScienceandTechnology201322157-164.[6]WenZhaoyin.Sodiumsulfurcellanditsenergystorageapplication[J].ShanghaiEnergyConservation200727-10.[7]ZhangHuaminZhouHantaoZhaoPingYiBaolian.Actualityandprospectofenergystoragetechnologies[J].EnergyEngineering2005131-7.[8]HuXuejie.Li-ionbatteryanditskeymaterials[J].MaterialsChina201029846-52.[9]ZhaoXinbingXieJian.Recentdev