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氨基酸表面活性剂的市场现状及应用突破Marketanalysisandapplicationbreakthroughofaminoacidsurfactants广州天赐高新材料股份有限公司GuangzhouTinciMaterialsTechnologyCo.Ltd.毛华丽LilyMao2014.01.11•2009年毕业于浙江工业大学，专业为微生物与生化药学，获得硕士学位。GraduatedfromZhejiangUniversityofTechnologywithMaster'sdegreeforMicrobiology&BiochemicalPharmacyat2009.•毕业后在国内某知名日化企业从事日化产品研发，现任天赐日化事业部技术服务工程师，负责氨基酸类表面活性剂的应用及推广。Servedinafamouspersonalcarecompanyforpersonalcareproductsresearchbefore,nowserveinTincipersonalcaredepartmentastechnicalserviceengineerforapplicationandpromotionofaminoacidsurfactants.联系方式Tel：15989228970邮箱Email：maohuali@tinci.com目录氨基酸表面活性剂的市场现状分析Marketanalysisofaminoacidsurfactants1什么是氨基酸表面活性剂？Aminoacidsurfactantsintroduction氨基酸表面活性剂在洗发香波中的应用及选择Applicationandoptimalsolutionforaminoacidsurfactants结晶型氨基酸洁面膏介绍及推广IntroductionofcrystallizedaminoacidfacialcleanserCONTENTS2341、氨基酸表面活性剂的市场现状分析Marketanalysisofaminoacidsurfactants氨基酸表面活性剂的市场应用分类及选择Marketanalysisandoptimalsolutionofaminoacidsurfactants数据来源Source：GNPD,2010.9-2012.9全球范围内，含氨基酸表面活性剂的产品的前5公司Top5companiesofaminoacidsurfactantsconsumption(Global)12345SodiumLauroylSarcosinate6.39%4.49%2.85%2.33%1.99%PotassiumCocoylGlycinate16.80%13.90%9.80%6.70%5.90%SodiumLauroylGlutamate7.92%7.92%5.94%3.96%3.96%OriflameL’orealLaboratoiresphytosolbaAvonP&GKoseCosmeportUnilieverSkinFoodKaneboCosmeticNatureRepublicL'OccitaneDMDrogerieMarktSanteNaturkosmetikRossmannAubreyOrganics0.00%2.00%4.00%6.00%8.00%10.00%12.00%14.00%16.00%18.00%Ratio/%Top5companiesofaminoacidsurfactantsconsumption数据来源：GNPD,2010.9-2012.9氨基酸表面活性剂应用区域全球前7使用氨基酸表面活性剂的国家（2011.1-2012.12）ApplicationregionofaminoacidsurfactantsTop7countriesinaminoacidsurfactantsconsumptionSouthKorea,48,4Japan,156,1China,61,2UnitedKingdomGermany,57,3SaudiArabiaBrazilAmerica,23,6Italia,45,5Thailand,17,7排名Ranking1234567国家Country日本Japan中国China德国Germany韩国SouthKorea意大利Italy美国USA泰国Thailand产品数量Numbers156615748452317数据来源Source：GNPD,2011.1-2012.12，含月桂酰谷氨酸钠（钾）及椰油酰甘氨酸钾的产品ProductscontainSodium(Potassium)LauroylGlutamateandPotassiumCocoylGlycinate椰油酰甘氨酸钾(全球，国家)ApplicationregionofPotassiumCocoylGlycinate(Global)数据来源：GNPD，162个新品，2010.10-2012.10Source:GNPD,162newproducts,2010.10-2012.10氨基酸表面活性剂在个人护理品（新品）中应用占有率Aminoacidsurfactantsmarketshareinnewproducts0.0%5.0%10.0%15.0%20.0%25.0%2009.92010.92011.92012.92013.92014.9AminoacidsurfactantsmarketshareinnewproductFace/neckcareproductSoap/showerproductShampooSoap/showerproductforbaby(0-4yearsold)Soap/showerproductforchild(5-12yearsold)Products2008.10-2009.92009.10-2010.92010.10-2011.92011.10-2012.92012.10-2013.9面部/颈部护理产品数量Totalface/neckcareproducts711683408188100599679面部/颈部含氨基酸产品数量Face/neckcareproductswithaminoacidsurfactants784876955116712416-22%香皂/淋浴产品数量Totalsoap/showerproducts8847987194601032910118香皂/淋浴含氨基酸产品数量Soap/showerproductswithaminoacidsurfactants614768802997958洗发水产品数量Totalshampooproducts37074159404445444346洗发水含氨基酸产品数量Shampooproductswithaminoacidsurfactants445518566739674婴幼儿（0-4岁）香皂/淋浴产品数量Soap/showerproductsforbaby(0-4yearsold)411463408440419婴幼儿（0-4岁）香皂/淋浴含氨基酸产品数量Soap/showerproductsforbaby(0-4yearsold)withaminoacidsurfactants7874658381儿童（5-12岁）香皂/淋浴产品数量Soap/showerproductsforchild(5-12yearsold)376382373431482儿童（5-12岁）香皂/淋浴含氨基酸产品数量Soap/showerproductsforchild(5-12yearsold)withaminoacidsurfactants2444466252数据来源Source：GNPD,2008.9-2013.92、什么是氨基酸表面活性剂？Aminoacidsurfactantsintroduction氨基酸类表面活性剂的结构组成Structureandcompositionofaminoacidsurfactants离子性Ionicity亲水基Hydrophilicgroup亲油基Lipophilicgroup无机盐Inorganicsalt阴离子Anion谷氨酸Glutamicacid月桂基lauryl椰油基Cocoyl--C8、C10、C12、C14（水溶性好Goodwatersolubility）--C12、C14、C16、C18（水溶性差PoorWatersolubility）钠盐sodiumsalt（较硬hard）：膏体产品pasteproduct钾盐sylvite（较软soft）液体产品liquidproduct三乙醇胺盐TEAsalt盐又可分为氯化物、硫酸化物Inorganicsaltmayincludingchloride,sulfate甘氨酸Glycine肌氨酸Sarcosine丙氨酸Alanine氨基酸类表面活性剂典型反应1、酰氯的合成SynthesisofAcylchloride2、脂肪酰氨基酸钠的合成SynthesisofAcylaminoacid-typesurfactantRCOCl+CH3NHCH2COONaRCONCH3CH2COONa+NaClNaOH+3RCOCl+HNHHCCOONaCH2CH2COOH+NaOHCH3(CH2)10CONHCHCOONaHOOCH2CH2C+NaCl肌氨酸类Sarcosine谷氨酸类GlutamicacidRCOCl+NH2CH2COONaRCONHCH2COONa+NaClNaOH+甘氨酸类Glycine3RCOOH+PCl33RCOCl+H3PO3氨基酸表面活性剂合成工艺Manufacturingprocessofaminoacidsurfactants①脂肪酰氯+氨基酸钠③反酸洗盐②氨基酸表面活性剂⑤喷粉烘干④回调pH⑥压片-成品pH约为12，盐含量约占5-7%Contains5-7%saltandpH12盐含量约占0.5%Contains0.5%saltFattyacylchloride+AminebasesaltsAminoacidsurfactantBackacidandreducesaltcontentpHAdjustmentSpraydryingFlaking-product氨基酸表面活性剂反应副产物Byproductsofaminoacidsurfactans氨基酸表面活性剂反应副产物Byproductsofaminoacidsurfactans盐残留Residualsalt氨基酸盐残留Residualsodiumofaminoacid脂肪酸皂SoapRCOCl+H2O+NaClNaOH+RCOONa反应过程中采用氨基酸盐过量Extraadditionofsodiumofaminoacid＜0.1%适量无机盐可增加氨基酸表活溶液的透明性；在配方应用时，同样可以辅助增稠AppropriateamountofsaltwillincreasetheclarityofaminoacidsurfactantsolutionShowsauxiliarythickeningability≤0.5%皂含量高，透明性差，溶液粘度高，易增稠；做洁面膏类产品，配方容易做；皂含量低，膏体偏硬，突变温度窄，膏体较粗Highsoapcontentleadstolowclarity,highviscosityandeasytoincreaseviscosity;itiseasytogetfacialcleanser;lowsoapcontentleadstonarrowchangingtemperaturerangeandroughappearance.≤1.5%050100150200250300567899.5258216186194179172245200159147201200FoamHeight/mmpHFoa