–148–1678911PDA(Portable)(Wearable)RateCapabilityA&TBatteryCorporationA&TBattery(AdvancedLithium-ionBattery)LiCoO2MCF(HighCapacityMesophase-pitch-basedCarbonFiber)(Li-ionBattery)(LiPolymerBattery)(BatteryManufacture)AlLaminatedFilmElectrodeCoil/ElectrolytePositiveTabNegativeTabA&TBatteryALB8911167–149–LiBF4/EC-GBLLAB363562B3.6mm×35mm×62mm680mAhALBGSM(PulseMode)-20°C70%20°C680mAh1(20°C60mΩ→-20°C120mΩ)20%30%GSMPDA(150170°C)ALBA&TALBABGSMPDACALBGSMALBALBLAB363562ALAB363562B(540mAh)(680mAh)20°C,4.4VNR,NFNR,NF(ExternalShortCircuit)(OverchargeTest)1.10V,1ItANR,NF(70°C)NR,NF(77°C)2.12V,3ItANR,NF(118°C)NR,NF(112°C)3.24VNR,NF(44°C)NR,NF(OvenTest)1.150°C,4.3V,1hNR,NF(153°C)NR,NF(153°C)2.170°C,4.4V,1hNR,NF(177°C)NR,NF(178°C)(NailingTest)NR,NF(110°C)NR,NF(115°C)4.4V,φ2.5mm(CrushTest)NR,NF(115°C)NR,NF(118°C)4.4V,φ10mm,2.0tonNR:NoRupture,NF:NoFire,():Max.TemperatureCharge:1ltA-4V,3hrs.,(CC-CV),20°CDischarge:1.700mA-0.6msec100mA-4msec,3.0Vcut4.54.03.53.02.52.05004003002001000020406080100CapacityRatio(%vs20°CCapacity)-20°C-10°C0°CDC-Impedance(m-ohm)TerminalVoltage(V)–150–1678911DA&TBattery3.6mm172Wh/kg366Wh/lHitachi-Maxell,Ltd.Hitachi-Maxell1.PLSType(StackedElectrodeSystem)UV(ChemicalCross-LinkedGelPolymer)25µm50080%116mm×89mm×3.0mm55g1500mAhPLS3089116199910PDA2.PLCType(CoiledElectrodeSystem)(PhysicalCross-LinkedGelPolymer)20µm62mm×35mm×3.6mm640mAh14.5gPLC363562200010PLSPLCPositiveelectrodeCollectorLaminatedFilmSeparatorNegativeelectrodePositiveelectrodeNegativeelectrodeSeparator(Non-wovenfabricsheetmorethan25µmt)ChemicalCross-linkedgelpolymer(radicalpolymerizationbyUVrays)PLS3089116SpecificationDimensions(mm)NominalCapacity(mAh)Weight(g)3.0t89w116h150055(a)(b)MaxellPLS(a)(b)8911167–151–SANYOElectricCo.,Ltd.SANYO(GelPolymerBattery)(Pre-polymer)UPF36356262.0×34.5×3.5mm13.8g156Wh/kg286Wh/l62.0×34.5×3.8mm700mAh15.8g163Wh/kg319Wh/l(HighCollectorLaminatedFilmLowerProductionCostthanPLSTypePositiveelectrodeSeparatorNegativeelectrodePLC363562SpecificationDimensions(mm)NominalCapacity(mAh)Weight(g)3.6t35w62h64014.5PositiveelectrodeNegativeelectrodeSeparator(MicroporousFilmlessthan20µmt)Physicalcross-linkedgelpolymer(Heatpolymerizedtype)(a)(b)MaxellPLCPLSMaxellPLC(a)(b)ItemTestConditionPLC363562PLS3089116Over1C12V25°CNoRupture,NoFireNoRupture,NoFireChargeDelaminatedDelaminatedShort4.25Vcharge60°CNoRupture,NoFireNoRupture,NoFireCircuit10mΩNail4.25VCharge25°CNoRupture,NoFireNoRupture,NoFirePenetrationϕ3mmCrush4.25VCharge25°CNoRupture,NoFireNoRupture,NoFire13kNPlaneOven4.25VCharge150°CNoRupture,NoFireNoRupture,NoFireHeat10minDelaminatedDelaminated–152–1678911Reliability)(-20°C)(3CRate)(500)100°C50.6mm0.15mmMatsushitaBatteryIndustrialCo.,Ltd.MatsushitaPVdFPHFP(ThermalWelding)160Wh/kg(2CRate,90%Capacity)Mixtrueofpre-polymerandelectrolytesolutionSimilarmanufacturingprocessasLIBCasing(aluminum/resinlaminatedfilm)NegativeelectrodeSeparator(microporousfilm)PositiveelectrodePositivetabNagativetabInjectionHeatingPolymerization(forminggel)Voltage(V)Capacity(mAh)Size(mm)Weight(g)Energydensity(Wh/kg)(Wh/l)3.75803.534.562.0approx.13.8156286Dischargecurrent:0.2CEndvoltage:3.0VSANYOSANYOSANYOTestItemTestMethodTestResultAbnormalChargeChargeat1C-12VNoBursting&NoFireShortCircuitNail(φ2.5mm)PenetrationNoBursting&NoFireCrushCrushthecellwithpoleφ10mm)NoBursting&NoFireHeatHeatup5°C/minandmaintainNoBursting&NoFirefor3Hoursat150°CHighTemperature100°C5hrsNoBursting&NoFireStorageSwelling0.6mm(hotstate)0.15mm(aftercooldown)8911167–153–MatsushitaGS-MELCOTECCo.,Ltd.GS-MELCOTECLTLTLYLY(Micro-PorousPolymer)(MeltDown)2CRate(1120mA)90%520mAh-20°C560mAhUnit(Stack)Cell(Layer-built)SeparatorSeparatorCurrentCollectorCurrentCollectorCurrentCollectorPositivePositiveNegativeNegativeBothelectrodesandseparatorsincludePolymer(PVdF+PHFP)andareadheredtoeachotherviathermalwelding.LaminateFilmThecellcapacitycanbechangedbythenumberofstacks.Matsushita(Lamin-ation)2.5mm3.6mm17g38g7001650mAh2001MatsushitaWeightCapacitySize(mm)(g)(mAh,0.2CatRT)SampleMassTentativeThicknessWidthLengthAverageProductionMinimumFP-2563702.5637017700650NowFP-3663703.663702711501070NowFP-2563952.56395241000930'00/4QFP-3663953.663953816501535'00/4Q'01/2Q–154–1678911GS-MELCOTEC(AbuseTest)AGS-MELCOTECMatsushitaGS-MELCOTEC90mAh80080%150060%ItemTestResultShort-CircuitTestatRTNoExplosion,NoFireElectricaltestShort-CircuitTestat60°CNoExplosion,NoFireAbnormalChargingTestNoExplosion,NoFireCrushTestNoExplosion,NoFireImpactTestNoExplosion,NoFireMechanicalTestShockTestNoExplosion,NoFireVibrationTestNoExplosion,NoFireHeatingTestNoExplosion,NoFireEnvironmentalTestTemperatureCyclingTestNoExplosion,NoFireAltitudeSimulationTestNoExplosion,NoFireFlamingParticlesTestNoIgnitionofClothScreenOthers(Gasburner)ProjectileTestNoPenetrationofWireScreenNegativeTerminalPositiveTerminalSeparator+PolymerNegativeElectrodePositiveElectrodeAluminumLaminatedFilmCaseNegativeElectrodeInorganicParticleBinderPolymerLayerSeparator8911167–155–BCD“Power2000”,Proceedingofthe8thAnnualInternationalCoferenceonPowerRequirementsforMobileComputingandWireless