生物炭吸附有机污染物的研究进展-王宁

31320123ENVIRONMENTALCHEMISTRYVol．31No．3March201220111017．*KZCX2-YW-Q02-024080111811HZR07．＊＊[e-mail]*123212＊＊1．2500002．3610003．361000biochar．．．、、．．、PAHs、PCBs、．“”、．．1、2、34．、．．、、．1．、、、、70%．、、、、56．CO27．Kuzyakov814C20001400．．、、、288319-10．、11-14．300℃—500℃700℃1011．1100℃50．34%700℃84．61%6.09%42．8%1．25%13．04%．SA100℃SA0．65m2·g－1300℃19.92m2·g－1400℃SA112．4m2·g－1500℃SA236．4m2·g－1600℃SA206．7m2·g－1700℃SA491m2·g－13．312-3．．1C、H、N、O3Fig．1PercentageofelementsCHNOandspecificsurfaceareainbiochar11．2．．2060Yang15、400—25000．05%．．/．．．2．1、．、3289、．2070Chiou16-19．．34-4-．/-．．2．2．Freundlich．4Freundlich3、、/．．．Chiou20211998HSACM．．、、π．．πππ-π．ππ-ππ-π-．π-π-、．π-π-HOMOLUMO．π．Chun22/．Zhu23π-π4-、24-、246-．．2．3、24-26．．Walter27PignatelloXing2829“”“”．“”“”“”．．29031π29．22-2330-32Accardi-DeyGschwend33-．．2．4．1．Michiel34πππ-π．Nguyen32．Braida35-．3．．3．1、、、．3．1．131-32、31、22、36、371338．37-39．、、、40．YuanXu41454、、Ca、MgK5、、、．、．3．1．231．Satio14．．．2．4243．50、100150g·kg－1、、44．45．32913．50%1nm80%2nm．3．1．3KOM“”“”3．“”≤300℃4-≥400℃“”“”“”300℃KOM．．3．1．4．—OH、—CO—、—O—、—COOH．CECO/CCECO/C、46．23．-．Zhu23．Zhu234-、246-．-．-．23．．Yang47．．38-39π-π．pH48-50．、、、．．3．2、、、、、、、．、、、、、．2923151-52ππ-π-．3451．Bornemann31．、．、．．32．．Chen37200℃700℃．53．3．3pH．53pH．Yang47pHpH．pHpHpH．．54．4、55-57．58k．kk．、PCP95960．61．、62-65．、154166．3293．5．．1．．2．3-．4．、．1．J．2007271125-1282．-J．2007444650-6553．J．B2008386530-5374．3/J．2008272813-8195HossainMKStrezovVChanKYetal．InfluenceofpyrolysistemperatureonproductionandnutrientpropertiesofwastewatersludgebiocharJ．JournalofEnvironmentalManagement．2011921223-2286SohiSLoez-CapelEKrullEetal．Biochar'srolesinsoilandclimatechangeAreviewofresearchneedsM．UKCSIROLandandWaterScienceReport05/092009647WoolfD．BiocharasaSoilAmendmentAreviewoftheEnvironmentalImplicationsM．SwanseaSwanseaUniversity20088KuzyakovYSubbotinaIChenHetal．Blackcarbondecompositionandincorporationintosoilmicrobialbiomassestimatedby14ClabelingJ．SoilBiologyandBiochemistry2009412210-2199WenBLiRJZhangSZetal．ImmobilizationofpentachlorophenolinsoilusingcarbonaceousmaterialamendmentsJ．EnvironPollut20091573968-97410LehmannJGauntJRondonM．Bio-charsequestrationinterrestrialecosystemsareviewJ．MitigationandAdaptationStrategiesforGlobalChange200611403-42711LehmannJ．Bio-energyintheblackJ．TheEcologicalSocietyofAmerica200757381-38712WeberWJMcGinleyPMKatzLE．Adistributedreactivitymodelforsorptionbysoilsandsediments．1．conceptualbasisandequilibriumassessmentsJ．EnvironSciTechnol1992261955-196213ZhouDDZhuLZShenXY．SorptioncharacteristicsandmechanismsoforganiccontaminanttocarbonaceousbiosorbentsinaqueoussolutionJ．ScienceinChinaSeriesBChemistry2008b51464-47214SaitoYMoriMShidaSetal．Formaldehydeadsorptionanddesorptionpropertiesofwood-basedcharcoalJ．MokuzaiGakkaishi2000466596-60115YangYNShengGY．EnhancedPesticidesorptionbysoilscontainingparticulatematterfromcropresidueburnsJ．EnvironSciTechnol2003373635-363916ChiouCTPetersLJFriedVH．Aphysicalconceptofsoil-waterequilibriafornonionicorganiccompoundsJ．Science1979206831-83217ChiouCTLeeJFBoydSA．ThesurfaceareaofsoilorganicmatterJ．EnvironSciTechnol1990241164-116618ChiouCTLeeJFBoydSA．ReplytocommentonThesurfaceareaofsoilorganicmatterJ．EnvironSciTechnol199226404-40619ChiouCTRutherfordDWManesM．SorptionofN2andEGBEvaporsonsomesoilclaysandmineralsoxidesanddeterminationof29431samplesurfaceareabyuseofsorptiondataJ．EnvironSciTechnol1993271587-159420ChiouCTKileDE．DeviationsfromsorptionlinearityonsoilofpolarandnonpolarorganiccompoundsatlowrelativeconcentrationsJ．EnvironSciTechnol199832338-34321ChiouCTKileDERutherfordDW．Sorptionofselectedorganiccompoundsfromwatertoapeatsoilanditshumic-acidandhuminfractionsJ．EnvironSciTechnol2000341254-125822ChunYShengGChiouCTetal．CompositionsandsorptivepropertiesofcropresiduederivedcharsJ．EnvironSciTechnol2004384649-465523ZhuDQKwonSPignatelloJJ．Adsorptionofsingle-ringorganiccompoundstowoodcharcoalspreparedunderdifferentthermochemicalconditionsJ．EnvironSciTechnol2005393990-399824KaranfilTKilduffJE．Roleofgranularactivatedcarbonsurfacechemistryontheadsorptionoforganiccompounds．1．PrioritypollutantsJ．EnvironSciTechnol199933183217-322425PaulsenPDMooreBCCannonFS．ApplicabilityofadsorptionequationstoargonnitrogenandvolatileorganiccompoundadsorptionontoactivatedcarbonJ．Carbon199937111843-185326MahajanOPWalkerJRPhilliPL．EffectofinorganicmatterremovalfromcoalsandcharsontheirsurfaceareasJ．Fuel1979585333-33727WalterJWerberJrHuangW．Adistributedreactivitymodelforsorptionbysoilandsediments4．IntraparticleheterogeneityandphasedistributionrelationshipsundernonequilibriumconditionsJ．EnvironSciTechnol199630881-88828XingBPignatelloJJGigllottiB．CompetitivesorptionbetweenatrazineandotherorganiccompoundsinsoilandmodelsorbentsJ．EnvironSciTechnol1996302432-244029XingBPignatelloJJ．Dual-modesorptionoflow-polaritycompoundsinGlassypolyVinylChlorideandsoilorganicmatterJ．EnvironSciTechnol199731792-79930KubickiM．StructuralaspectsofphasetransitionsJ．SolidStatePhenomena2006121-2031BornemannLCKookanaRSWelpG．Differentialsorptionbehaviorofaromatichydrocarbonsoncharcoalspreparedatdifferenttemperaturesfrom