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416200511SCIENTIASILVAESINICAEVol141,No16Nov.,2005张力平1孙长霞1李俊清2刘艳红2(11100083;21100083):,,2:;;:TQ351:A:1001-7488(2005)06-0157-06:2003-12-23;:2005-08-10:(863)(2002AA322060)(30370291)ThePresentConditionsandDevelopmentTrendofPlantPolyphenolsResearchZhangLiping1SunChangxia1LiJunqing2LiuYanhong2(11SchoolofMaterialScienceandTechnology,BeijingForestryUniversityBeijing100083;21CollegeofNaturalResourcesandEnvironment,BeijingForestryUniversityBeijing100083)Abstract:Plantpolyphenols,asoneoftheimportantnaturalproducts,widelyexistsinplants.Ithavebeenusedinmanytraditionalindustries,suchasleather2making,chemicalengineering,medicine,agriculture,foodandmaterial.Especiallyintherecentyears,theencouragementtoenvironmentalprotectionandgreenscienceacceleratedplantpolyphenolsresearchandprogress.Inthispaper,developmenttrendanduseprospectofthisresearchfieldissummarizedfromitsapplicationsontraditionalindustryandfinechemicalsutilizationsindustry.Keywords:naturalproducts;plantpolyphenol;vegetabletannins,,(,1998a;,1994;,1988):()()()(,1998a;,1994;,1997;,2000;,2001;,2002),,(,1998b),,,,,,,,21,,(vegetabletannins)WhiteBate2Smith:500~3000,Haslam(1989),(),,(,2000),2:()()12,,,;,(,1994)1Fig.1Typicalmolecularstructureofhydrolysabletannins2Fig.2Typicalmolecularstructureofcondensedtannins3Fig.3Reactionmodelofplantpolyphenolandprotein111,2080Haslam(1989)/-0,3,,,112-,,,Cr6+Fe3+,(,2000;,1988)113(),,,:PH()+ROO#()yP#+ROOH,200~350nm15841,,(,2000),,,2211(,2000),21111(,1998a)1858,,;,--21112,,(,1997),,,,,,300e,,,,,21113,(,1994;Wheateley,1992),,,,,,,212,21211300~900:,,1)(,1998a),,,,,,,,VcVeSODUVA,,,,2,,,2,,/P0(71596:,2000);,,,,,2),,;(,1997)3),(Haslameetal.,1989)4),(,2000),,,,,,,,,,21212,,,7,(,2000),,,,,,,,213,,,21311,20,21312,(1998),213132:;,2:,2:,,,(2003),:3Cu2+Freundlich,:,,(,1998)16041214,,,;,2,,,,,,,;,,,,(Poweretal.,1988)-,,,(2003),,,,215,(1997)-,ABS,(AIDS)2080,HIV,HIV(Haslameetal.,1989),AIDS,HIV,,,216,(Andrew,1992),2,,,();,;,,,,(1996),,;(2001),,,,,,,,(,1998b)3,1616:(,2004):,,,,,,:(,2005),,,,,,,,,7.2000..,3,.1998a..,(3):20-23,.1998b..,(2):20-23,,.2003..,(6):809-815,.1997.-.,20(1):35-56,,,.1994,.,(4):16-20,,.2003.Cu2+.,23(4):11-16,,,.1997..,17(1):11-15,.20001.:,7:102,.1998a..,8(3):5-25,,,.1998b..,49():43-50,,.2000..,12(2):161-170,,,.2005..,():529-531.19881.:,61-10.2001..,(2):1-6.1997..:,303-307,.1996..,39(4):337-341,,.2002..,25(6):22-23,.2001.-.,21(2):286-289,,,.1998..,18(3):20-22.1994..:,246,,.2004..,31(2):32-34AndrewG.1992.Flavor,colorandstabilityinfruitproducts:theeffectofpolyphenols.In:RHemingwayP.Laks(ed).PlantPolyphenols.NewYork:PlenumPress,827-847HaslamE.1989.Plantpolyphenols)vegetabletanninsrevisited.CambridgeUniversityPress,10HaslameL,CaiY.1989.Traditionalherbalmedicines)theroleofpolyphenols.PlantMedica,55:1-3PowerJC,NagelK.1988.Proteinremovalfromawinebyimmobilizedgrapepronthocyanidins.AmJEnolVitic,39(2):117-120WheatleyM.1992.Useoftanninsinadhesiveapplications:industrialproblemsandpotentials.In:RHemingwayPE.Lakes(ed).Plantpolyphenols.NewYork:PlenumPress16241