微胶囊电泳显示技术

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王静冯亚青*李祥高孟舒献谢建宇李刚(300072),26,,*,E-mail:yqfeng@tju.edu.cn863(2002AA325050)2004-11-15,2004_12_10/0/0,MicroencapsulatedElectrophoreticDisplayTechnologyWangJing,FengYaqing*,LiXianggao,MengShuxian,XieJianyu,LiGang(SchoolofChemicalEngineering,TianjinUniversity,Tianjing300072)AbstractMicroencapsulatedelectrophoreticdisplayisareversible,bistable,flexibledisplaytechnology.Its/singleparticle0and/dualparticles0displaymechanismsaredescribed.Thethreeimportantprocessesincludingsurfacemodificationofelectrophoreticparticle,preparationofdisplayfluidandmicroencapsulationareintroducedindetail.Itsrecentresearchhasbeenreviewedandfuturedevelopmenttrendispresented.KeywordsReversible,Bistable,Flexible,Surfacemodification,Electrophoreticdisplay(MIT),E-Ink[1~5],[6][7]6[8],,[9],,1,/0/0[10]111,,1[11]1,,,#432#20056http:PP(1a);,,(1b),1Fig.1Singleparticledisplaymechanism2Fig.2Dualparticlesdisplaymechanism112,,2[12]2,,,,(2a);,,,(2b),,,2211,,,;[13],,21111,[14~16]:M=LE=ENE6PG=qE12PrGM;L;G;E;NZeta;E;q;r,,Zeta,(),[17],,(CCA),,,[18]:,;,#433#http:PP[19]:R)SO3HR)SO3-+H+Partical)NH2+H+Partical)NH3+,,,:21112,,[20],/0,,,[21],Comiskey[9]Gordon[22],,,,Chen[23]212,,,(2)(10~158Pcm)(5cst)(10-5)(115)(90e)(112)[24]1,,[24,25]P[26]3Fig.3Thestructureofmicroencapsulatedelectrophoreticdisplaypaper213,,[27],,[28],,(PET)(PC)(PI)[29,30],,3[31]#434#20056http:PP[32];,,[33],,,50~150nm,,21311(interfacialpolymerization)XY,)(X)Y))n[34],4[35]4Fig.4Interfacialpolymerizationofpreparingmicrocapsule:X,Y;:)(X)Y))n)(X))n5Fig.5insituPolymerizationofpreparingmicrocapsule:X,Y;:)(X)Y))n)(X))n21312(insitupolymerization)-XY,)(X)Y))n[36],5[35]21313(coacerationapproach)[37],pH[38],6[35]6Fig.6Theencapsulatedtechnicsofcoacerationapproach(a);(b);(c);(d)[39],[40],7,-#435#http:PP(a);(b)3/0,,,,1996/0,199910,E-Ink,,2000,E-Ink[41]20014,E-InkIBM(ActiveMatrix),,9,310nm,20016,E-Ink/020021,E-Ink/Ink-InMotion0,,[42]200224,E-Ink8LIBRI†Fig.8Electronicbook-LIBRI†ofmicroencapsulatedelectrophoreticdisplay,,2002/020022,E-InkVSTE-InkVST,VST[43]20044,SONYE-Inke-paper,190mm@126mm@13mm,190g,,170ppi,800@600,5000,10000,8[44],,,,,[45~48],E-Ink,,(),,,,,,,,,[1]JMCrowley,NKSheridon,LRomano.JournalofElectrostatics,2002,55:247~2591#436#20056http:PP[2]ANKrasnov.Displays,2003,24:73~791[3]RAHayes,BJFcenstra.Nature,2003,425:383~3851[4]RCThibault,RAHayes,BJTeenstraetal.J.Appl.Phys.,2004,95(8):4389~43961[5]JLub,DJBroer,PVWitte.ProgressinOrganicCoating,2002,45:211~2171[6]WGEhrfeld.ElectrochimicaActa,2003,48:2857~28681[7]JARogers.Science,2001,291(5508):1502~15031[8]DButler.Nature,2001,411:51[9]BComiskey,JDAlbert,HYoshizawaetal.Nature,1998,394:253~2551[10]JMJacobson,THWhitesides,RWZehner.WO:2004023202,20041[11],,.,2003,34(4):386~3891[12]YChen,JAu,PKazlasetal.ElectronDevicesMeeting,20021IEDM.021Digest.International8-11Dec,2002:389~3921[13]KHayakawa,SHarada,MMorita.USP:6693621,20041[14]TBert,HDSmet.Displays,2003,24:103~1101[15]TBrian,FICornelius.J.Chromatogr.A,2002,953:263~2771[16]LSMOrlando,PHEver,LMichaeletal.Electrophoresis,2003,24:390~3981[17]AAChiang.USP:4285801,19811[18]FESchubert.USP:5380362,19951[19]MYanagisawa.USP:6765713,20041[20]TBert,HDSmet.Display,2003,24:223~2301[21],,.(),1995,23(10):148~1541[22]JGGordon,HMWhitney,SSAm.USP:5914806,19991[23]JHChen,FESchubert.USP:6194488,20011[24]JDAlbert,BComiskey,JMJacobsonetal.USP:6727881,20041[25],,.CN:1477608A,20041[26]MYanagisawa.JP:2003096191,20031[27]GPGrawford.IEEESpectrum,2000,37:40~461[28]RWisnieff.Nature,1998,394:225~2271[29]YShunpei,AYasuyuki.USP:173890,20031[30]GMDuthaler,KRAmundson,BComiskeyetal.WO:2004023195,20041[31].,2003(32):27~29.[32]OAkiko.USP:041423,20021[33]WPHsu,PChen,DLerouxetal.USP:151029,20031[34]HXGao,TJiang,BXHanetal.Polymer,2004,45:3017~30191[35],,..:,2001:54,75,129[36],,.,2004,21(1):76~801[37]SGouin.TrendsinFoodScience&Technology,2004,15:330~3471[38]KNakagawa,SIwamoto,MNakajinoetal.JournalofColloidandInterfaceScience,2004,278:198~2051[39]ALoxley,BComiskey.USP:6262833,20011[40]KSadao.JP:2003222913,20031[41]JARoger.Science,2001,291(5508):1502~15031[42].,2004,1:14~181[43],.,2003,4:9~101[44]comefrom:http:PPitinfo.pcicp.comPnewsPdigilifeP[45],,.,2004,18(1):46~511[46],,.,2004,35(1):105~1071[47],,.,2004,14(6):717~7191[48]HLGuo,XPZhao.OpticalMaterials,2004,26:297~3001#437#http:PP

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