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Nov．20132111FineandSpecialtyChemicals201311(中化化工科学技术研究总院，北京100083)、、。、、。。ＲesearchstatusanddevelopmenttrendofionicliquidsZHAOXinYINDong-yuanWUZhen-yiCentralＲesearchInstituteofChinaChemicalScienceandTechnologyBeiJing100083ChinaAbstractIonicliquidsasanewtypeofmaterialormediumisusedascatalystanddissolventithasmanyadvan-tagesuchasgreennontoxicshortreactiontimeshighselectivityhighyieldandwideapplication.Ionicliquidsclassi-ficationtheresearchandapplicationprogressofionicliquidsingreencatalystcleansynthesisandelectrochemistrywerereviewed.Theresearchworkinphosphoniumionicliquidswasalsoreported.Thedevelopmenttrendofionicliq-uidsispointedinthefinal.Keywordsionicliquidphosphoniumgreencatalystcleansynthesiselectrochemistryinsulatingoil2013-09-18Z111100568110371960-、。。“”“”100℃1～2。。3。、。、、、。、4～5。、。。11.1、、6～7。1.2Al2Cl7－Al3Cl10－Au2Cl7－Fe2Cl7－Sb2F11－Cu2Cl3－Cu3Cl4－BF4－PF6－NO3－NO2－SO42－CH3COO－SbF6－ZnCl3－SnCl3－NCF3SO22－NC2F5SO22－NFSO22－CCF3SO23－·42·201311CF3CO2－CF3SO3－CH3SO3－。1.3AlCl4－7～9。210～111、。2。3、、。4。5。6。33.1。。12。。ChristopherHardacre13、COPdn∶nPd250∶1n∶nPd100000∶1CO80℃8h63%。14、14-2-。、、、。7∶18%50%140～150℃3h。80μg/gEN590。15Pt/C。4、。85℃、0.2MPa、4h、Pt/C0.2g、1000r/min86.54%48.98%。。16NN-DMFEOCO2EC。、EC。DMFI－。ECEO6.6∶1100℃2.5MPa2h。EO98.4%EC99.6%。5。17C6H133PC14H29Br/·52·2111ZnCl2CO230mmolZnCl20.3mmolC6H133PC14H29Br0.6mmol2MPa100℃15min97%95%。。18/、30%。n∶n∶nN-∶n=50∶1∶5∶22010mmol7.5h90.5%。、、。191500t/aBILE-3。5%45～65gKOH/100g50%～70%95%99%BILE-3、、、。3.220EmimBF4、。50℃8h。。21。221--3-BmimCl5-HMF。100℃60minＲ=5Ｒm∶m=1∶3HMF50%。、。23、。13.05%、9.10g/L、0.72g/L99.27±0.55%8.60%。。3.3241--4-TBEPIDSC。EIS、CVATＲ-FTIＲTBEPI、TiO2TiO2//。TBEPI、。TBEPITiO2TiO2//12--3-DMPIIDSCη7.1%7.5%。251--3-BMIMBF4CV、CP、FTIＲSp-MT。D=3.4×10-7cm2/s。·62·20131126～27BMIMBF4p-MT。4。MBT/DBT28。MBT/DBTFriedel-Crafts。。MBT/DBT。LewisBu3PC14H29Cl/nZnCl2Friedel-CraftsMBT/DBT1∶33∶1100℃5hMBTDBT98.5%35。BnCl+2?/ZnCl2膦520127《》“”。、、、、、。、、-Friedel-Crafts、、、、、、。MBT/DBT、。1.、J.200217142-50.2.M.2009.3.M.2006.4JyriPekkaMPasiVHannuKetal.Supportedionicliquidscatalystsforfinechemicalscitralhydrogenation.J.GreenChemistry20068197-205.5.J.200727101236-1243.6.J.2003156471-476.7.J.200332177-185.8.J.200634192-194.9.J.200522162-65.10.J.20088191671-1819.11.-J.20031017.12.J.20073610975-984.13ChristopherHardacreJohnDHolbreySuhasPKatdareaetal.AlternatingcopolymerisationofstyreneandcarbonmonoxideinionicliquidsJ.GreenChemistry20024143-146.14.J.201243215-18.·72·211115.J.201118335-40.16.J.2013426671-674.17./CO2J.20122911-6.18.J.20122612095-2098.19.J.2010272147-150.20.J.200932458-60.21.J.200833180-84.22.5-J.2012283686-692.23.J.2013333130-134.24.J.20133471697-1702.25.BMIMBF4J.2012282421-426.26.J.2013411440-43.27.J.2012293245-251.28.J.2007284檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪檪殏殏殏殏47-52.Bond-Laminates20131030Bond-LaminatesTepex75%1300m2、2014。“———。”WernerBreuers。“Bond-Laminates。Tepex‘’。。”TepexBond-Laminates。Tepex、。TepexA8。Tepex、。、、、、。Tepex。Tepex。201291175003152、、、。DJSI、FTSE4GoodCDLI。Bond－Laminates199710020062012Bond－Lami-nates。JochenBauder“。。”(王晨)·82·