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1,2,1,1X(1.,214061;2.,310005)[];;PVC;[],,,,[]TQ325.3[]C[]1009-7937(2003)02-0001-06CurrentsituationanddevelopmenttrendofplasticizerforPVCJIANGPing-ping1,FANGHong-xi2,WEILin-juan1,CHONGMing-ben1(1.InstituteofChemicalandMaterialEngineering,JiangnanUniversity,Wuxi214061,China;2.ZhejiangHuataiFineChemicalCo.,Ltd.ofHualiGroup,Hangzhou310005,China)Keywords:plasticizer;additivesforplastics;PVC;reviewAbstract:ThemarketofPVCplasticizerathomeandabroadisintroduced.Thecurrentsituationofdomesticcommericalplasticsandplasticizerisanalyzedaswellastherelationshipbetweenitsdevel2opmentandconsumptionstructure.Thelatestresearchprogressofcleanprocessfortheproductionofcommericalplasticizerisdescribed,especiallythecatalyticesterifyingprocessesbyusingsolidsuperacid,rareearthsolidacid,solid-supportedheteropolyacid,andcomplexsolidoxideascatalysts.Itispointedoutthatnontoxicorlow-toxic,environment-friendlyproductswithhighandlastingefficien2cy,whichareproducedbycleanprocess,aretheworldwidedevelopmenttrendofplasticaids.2010:PVC,,,21,10%,,,,,,11.1BRC.Townsent:,,,,BCC(BusinessCommunicationCompany):20011701220033PolyvinylChlorideNo.2Mar.,2003X[]2002-10-18[](1957-),,,,,,,,,30,,2005,4%,11t20002005/%DOP1202004.6C9C1030357.425303.71752651:DOP,,DOP2700t/a,(DINP)DOP,,DOPDINP,DOP,DINPDINPDOP,DOPDINPDOPDOPDINPDINPDOP,,DINP,DOPDINP(23),2t19982000/%65.571.31.78.89.61.85.35.71.53.94.52.92.42.72.56.17.13.292.0100.93t19982003/%101.3105.80.93.23.41.21.51.83.72.22.52.61.82.02.11.71.92.2111.7117.42000,60%PVC(4)42000/%12522331541351068761.22002,45.5t,18.3%,,85t2001,76.06t,200012.2%100(),20011t16,2t15,5t8,15t,;,8.27t;3,7.24t::,,,:,,,DOPDBP:(1)2-,,;,,,,,,2PolyvinylChloride20032No.2,2003DOP2/3(2),BASF;,,,,,,,,,,COD,,,,,,,2,19961000t,1574t2001(500)1185t,200013.1%,()2001552001/t/%242.5520.47121.4010.24128.7910.8778.816.6553.964.5553.764.5411.220.95-41.73,,2001100t,200062.7%;5%2002651t,200114.1%,1315t2000PVC280t/a,5t/a10,2000PVC220230t,66PVCPVC/%24.415.530.410.05.014.7,,27kg,100kg,,,20052500t,470t,19.0%;550t,22.0%;400t,16.0%;450t,18.0%;472t,18.9%;78t,3.1%;75t,3.0%,10%,,70%2090,30%PVC,,199545.03t,200067.81t,50.6%,8.5%3,300,,320032No.2,2003:,,2080,,200132.66t,20016.7%20021517.04t,200131.0%,80%3,2080,,,,,,,3.173/%/%S-/ZrO2S,3.47093.00189.24285.31P-/ZrO2P,4.05089.52188.70287.05B-/ZrO2B,1.05089.18185.34283.43HPW/SiO2HPW,30075.58165.903S-/ZrO2:;P-/ZrO2:;B-/ZrO2:(H0-11.9),,,,,,ZrO2SiO2,,DOP,73.1.1SO42-/MxOySO42-,MO,L,,,:;;SO42-BL11LB3.1.2:(1)(),(SO42-),SO42-,,,;(2),,,,;(3),,;(4)SO42-,+6+4,,,,4PolyvinylChloride20032No.2,20033,3.2,DOPGd2O3Lu2O3,,1--3--4--5(HPMBP),pH78,HPMBP,,8501h,DOP,2002204h,99%3.3,:(1),;(2);(3)/;(4);(5)PW12,,DOP,,PW12/SiO2PW12/CPW12/ZrO2,,,PW12/SiO2,Na2SiO49H2O,H7[PW12O42]7H2O,,12,,,1202h,3503h,,DOP,/=2.5/1(),4%,2.5h,99%,DOP,,3.4Al2O3NaOHLiOH,4SnOZnODOP,88DOP()/%hAPHA/%/(mgKOH/g)Al2O3/NaOH1.0/1.01803.5-0.21(AV)Al2O3/NaOH/LiOH0.77/0.33/0.0421702183.0799.8TiO21.352002.51099.52.01952001.61099.040.5752153.01099.0SnO0.52002.010152.0(AV)ZnO3.652006.01597.04,,,,:(TOTM)20011.5t,TOTMPVC(105),,,20052.5t,(),(PMMA)(DMEP),,CTX,,,,(9),(28)520032No.2,2003:3PVC-U,:(1)PVC-U18.3%,62%75%,;(2)PVC-U1/2;(3)70%;(4)1tPVC-U12t[7],[812],,PVC-U,[][1].(UPVC)[J].,1996,(2):4-9.[2].[J].,2000,(1):76-80.[3].HDPE[J].,1998,(4):8-10.[4].[P].:CN1196013A.[5].[P].:CN1196013A.[6].[P].:CN1231632A.[7].[M].:.[8]ASelwood,AKTaraiya,IMWard.ThePreparationandPropertiesofDie-drawnPolyvinylchlorideTubes[J].PlasticsandRubberProcessingandApplications,1988,(10):85-91.[9]SAHansard,JRAtkinson,IMWard.HighStrengthOri2entedMDPEPipes[J].Plastics,RubberandCompositesProcessingandApplications,1994,(1):1-8.[10]Aelwood,BParsons,IMWard.TheProductionandPropertiesofDie-drawnPolyethylenePipes[J].PlasticsandRubberProcessingandApplications,1989,(11):229-233.[11]PLCarr,DWWoods,IMWard.TheProductionofOri2entedDie-drawnTubesinPolyphenyleneSulphideandinPoly4-methylPentene1HomopolymerandCopoly2mer[J].PlasticsandRubberProcessingandApplications,1994,(22):199-205.[12]SNKukureka,GGraggs,IMWard.AnalysisandMod2ellingoftheDieDrawingofPolymers[J].JMaterSci,1992,(27):3379-3388.[:](5),,,,PVC9199920002010/(109)m31.5235(1),,,,,(2)(3)2010,10%,()-()2003,[][1],.[J].,2002,21(5):328-330,348.[2],.[J].,2002,22(7):13-17.[3],.(2-)[J].,2002,60:1102-1105.[4],.ZrO2/SO42-(2-)[J].,1996,37(9):466-469.[5]SommerJ,JostR.Carbeniumandcarboniumionsinliquid-andsolid-superacid-catalyzedactivationofsmallalkanes[J].PurApplChem,2000,72(12):2309-2318.[6]ReddyJS,SayariA.Nanoporouszirconiumoxidepreparedusingthesupramoleculartemplatingapproach[J].CatalLett,1996,38:219-223.[7]HuangY,SachtlerWMH.Preparationofmesostructuredlamellarzirconia[J].ChemCommun,1977,1:181-184.[8]DebraJM,RonaaldAK.Tailoringtheporesizeofmeso2poroussulfatedzirconia[J].MicropMesopMater,2000,37:281-289.[:]82PolyvinylChloride20032No.2,2003