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MSDS#31/engAzodicarbonamidepage1of4AZODICARBONAMIDEMATERIALSAFETYDATASHEETHazardousaccordingtoInternationalCriteriaDateofIssue:OCT.20071.CHEMICALPRODUCTANDSUPPLIERIDENTIFICATIONProductName:AZODICARBONAMIDESynonymes:1,1'-AZOBISFORMAMIDEC-C'-AZODI(FORMAMIDE)SupplierIdentification(CHINA):2.COMPOSITION,INFORMATIONONINGREDIENTSChemicalEntityCASNo.Proportions(%)EINECS#1,1'-AZOBISFORMAMIDE123-77-397204-650-8RiskPhrases:53.HAZARDSIDENTIFICATIONEMERGENCYOVERVIEWAppearance:orange-red.Warning!Maycauseeyeandskinirritation.Maycauserespiratoryanddigestivetractirritation.Self-reactivesubstance.TargetOrgans:None.PotentialHealthEffectsEye:Dustmaycausemechanicalirritation.Skin:Maycauseskinirritation.Ingestion:Maycauseirritationofthedigestivetract.Thetoxicologicalpropertiesofthissubstancehavenotbeenfullyinvestigated.Inhalation:Maycauserespiratorytractirritation.Thetoxicologicalpropertiesofthissubstancehavenotbeenfullyinvestigated.Chronic:Noinformationfound.4.FIRSTAIDMEASURESEyes:Flusheyeswithplentyofwaterforatleast15minutes,occasionallyliftingtheupperandlowereyelids.Getmedicalaidimmediately.Skin:Getmedicalaid.Flushskinwithplentyofsoapandwaterforatleast15minuteswhileremovingcontaminatedclothingandshoes.Washclothingbeforereuse.Ingestion:Ifvictimisconsciousandalert,give2-4cupfulsofmilkorwater.Nevergiveanythingbymouthtoanunconsciousperson.Getmedicalaidimmediately.Inhalation:Removefromexposuretofreshairimmediately.Ifnotbreathing,giveartificialrespiration.Ifbreathingisdifficult,giveoxygen.Getmedicalaid.NotestoPhysician:Treatsymptomaticallyandsupportively.Antidote:Nonereported.5.FIREFIGHTINGMEASURESMSDS#31/engAzodicarbonamidepage2of4GeneralInformation:Asinanyfire,wearaself-containedbreathingapparatusinpressure-demand,MSHA/NIOSH(approvedorequivalent),andfullprotectivegear.Duringafire,irritatingandhighlytoxicgasesmaybegeneratedbythermaldecompositionorcombustion.Maybeignitedbyheat,sparks,andflame.Vaporsordustmayformexplosivemixturewithair.Mayburnviolently.Decompositionmaybeself-acceleratedandproducelargeamountsofgas.Self-decompositionorself-ignitionmaybetriggeredbyheat,chemicalreaction,frictionorimpact.ExtinguishingMedia:Forsmallfires,usedrychemical,carbondioxide,watersprayorregularfoam.Coolcontainerswithfloodingquantitiesofwateruntilwellafterfireisout.Forlargefires,floodfireareawithwaterfromadistance.6.ACCIDENTALRELEASEMEASURESGeneralInformation:UseproperpersonalprotectiveequipmentasindicatedinSection8.Spills/Leaks:Avoidrunoffintostormsewersandditcheswhichleadtowaterways.Cleanupspillsimmediately,observingprecautionsintheProtectiveEquipmentsection.Sweepuporabsorbmaterial,thenplaceintoasuitableclean,dry,closedcontainerfordisposal.Avoidgeneratingdustyconditions.Removeallsourcesofignition.Provideventilation.7.HANDLINGANDSTORAGEHandling:Washthoroughlyafterhandling.Removecontaminatedclothingandwashbeforereuse.Usewithadequateventilation.Minimizedustgenerationandaccumulation.Avoidcontactwitheyes,skin,andclothing.Keepcontainertightlyclosed.Avoidingestionandinhalation.Storage:Storeinatightlyclosedcontainer.Storeinacool,dry,well-ventilatedareaawayfromincompatiblesubstances.8.EXPOSURECONTROLS,PERSONALPROTECTIONEngineeringControls:Useadequateventilationtokeepairborneconcentrationslow.ExposureLimits:ChemicalNameACGIHNIOSHOSHA-FinalPELsAzodicarbonamidenonelistednonelistednonelistedOSHAVacatedPELs:Azodicarbonamide:NoOSHAVacatedPELsarelistedforthischemical.PersonalProtectiveEquipmentEyes:WearappropriateprotectiveeyeglassesorchemicalsafetygogglesasdescribedbyOSHA'seyeandfaceprotectionregulationsin29CFR1910.133orEuropeanStandardEN166.Skin:Wearappropriateprotectiveglovestopreventskinexposure.Clothing:Wearappropriateprotectiveclothingtopreventskinexposure.Respirators:FollowtheOSHArespiratorregulationsfoundin29CFR1910.134orEuropeanStandardEN149.AlwaysuseaNIOSHorEuropeanStandardEN149approvedrespiratorwhennecessary.9.PHYSICALANDCHEMICALPROPERTIESPhysicalState:CrystallinepowderAppearance:orange-redOdor:Nonereported.MSDS#31/engAzodicarbonamidepage3of4pH:Notavailable.VaporPressure:Notavailable.VaporDensity:Notavailable.EvaporationRate:Notavailable.Viscosity:Notavailable.BoilingPoint:Notavailable.Freezing/MeltingPoint:225degCdecAutoignitionTemperature:Notavailable.FlashPoint:225degC(437.00degF)NFPARating:(est.)Health:1;Flammability:1;Reactivity:1ExplosionLimits,Lower:Notavailable.Upper:Notavailable.DecompositionTemperature:225degCSolubility:Solubleinhotwater.SpecificGravity/Density:MolecularFormula:C2H4N4O2MolecularWeight:116.0810.STABILITYANDREACTIVITYChemicalStability:Stable.However,maydecomposeifheated.ConditionstoAvoid:Incompatiblematerials,dustgeneration,excessheat,strongoxidants.IncompatibilitieswithOtherMaterials:Oxidizingagents.HazardousDecompositionProducts:Carbonmonoxide,irritatingandtoxicfumesandgases,ammoniaand/orderivatives,nitrogen.HazardousPolymerization:Hasnotbeenreported.11.TOXICOLOGICALINFORMATIONRTECS#:CAS#123-77-3:LQ1040000LD50/LC50:Notavailable.Carcinogenicity:Azodicarbonamide-NotlistedbyACGIH,IARC,NIOSH,NTP,orOSHA.Epidemiology:Noinformatio