三维石墨烯宏观体的制备及其能源中的应用

。。、。SynthesisofThree-dimensionalGrapheneArchitecturesandTheirApplicationsinEnergyandEnvironmentalFieldsZHOUHui-ming,MAJie,YANGMing-xuan,CHENJun-hong(StateKeyLaboratoryofPollutionControlandResourceReuse,TongjiUniversity,Shanghai200092,China)Abstract:Graphenehasattractedgreatattentionandinterestfromglobalscientists.Thefabricationmethodsandapplicationsofthree-dimensionalgrapheneareunderinitialstage,thus,thisreviewaimstodescribethedifferentsyntheticprocessesforpreparationthree-dimensionalgraphenearchitecturesandtheirmeritsanddemerits;Moreover,thedifferentfieldsofapplicationsuchasadsorption,capacitivedeionization,microbialfuelcells,supercapacitorandhydrogenstoragearealsoreviewed;Finally,suggestionsforfurtherresearcharepresentedintheendofthepaper.Keywords:three-dimensionalgraphenesyntheticmethodsapplicationenvironmentenergy。··、、。。、。、、、、。。。。、、。℃。、、。··。℃。。。。。。。。。。Ω。。。、、。。。。∶。。、。、、、。1NovoselovK.S.GeimA.K.MorozovSV.etal.ElectricfieldeffectinatomicallythincarbonfilmsJ.Science2004306(5696)666-669.2NardecchiaS.CarriazoD.FerrerML.etal.Threedimen-sionalmacroporousarchitecturesandaerogelsbuiltofcarbonnanotubesand/orgraphenesynthesisandapplica-tionsJ.ChemicalSocietyReviews201342(2)794-830.3XuY.ShengK.LiC.etal.Self-assembledgraphenehy-drogelviaaone-stephydrothermalprocess.AcsNanoJ.20104(7)4324-4330.4ChenZ.RenW.GaoL.etal.Three-dimensionalflexibleandconductiveinterconnectedgraphenenetworksgrownbychemicalvapourdepositionJ.Naturematerials201110(6)424-428.5WorsleyM.A.OlsonT.Y.LeeJR.etal.Highsurfaceareasp2-cross-linkedthree-dimensionalgraphenemonolithsJ.TheJournalofPhysicalChemistryLetters20112(8)921-925.6ChenW.L.Yan.Insituself-assemblyofmildchemicalreductiongrapheneforthree-dimensionalarchitecturesJ.Nanoscale20113(8)3132-3137.7ShengK.-x.XuY-x.LiC.etal.High-performanceself-assembledgraphenehydrogelspreparedbychemicalredu-ctionofgrapheneoxideJ.NewCarbonMaterials201126(1)9-15.8XieX.YuG.LiuN.etal.Graphenespongesashigh-pe-rformancelow-costanodesformicrobialfuelcellsJ.Ene-··!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!rgy&EnvironmentalScience20125(5)6862-6866.9YongvY.-C.DongX.-CChan-ParkM.B.etal.Macroporousandmonolithicanodebasedonpolyanilinehybridizedthree-dimensionalgrapheneforhigh-performancemicrobialfuelcellsJ.ACSnano20126(3)2394-2400.10XuY.LinZ.HuangX.etal.FlexibleSolid-StateSuper-capacitorsBasedonThree-DimensionalGrapheneHydr-ogelFilmsJ.ACSnano20137(5)4042-4049.11BurressJ.W.GadipelliS.FordJ.etal.Grapheneoxideframeworkmaterialstheoreticalpredictionsandexperime-ntalresultsJ.AngewandteChemieInternationalEdition201049(47)8902-8904.。。。。、、。。。。。、。。。。。。。、。。。。。。。1.-J.2008(10)12-15.··