KAIZHUOCHEMICALCO.,LTDMaterialSafetyDataSheet第1頁I.物品名稱與廠商資料Identificationofthesubstance/preparationandcompany物品名稱/編號ProductInformation/Number:去渍油/solvent製造商或供應商名稱地址及電話InformationonProducer/SupplierName、Addresses、Phone:广州市凯卓化工有限公司/增城市石滩镇沙庄街土江村KAIZHUOCHEMICALCO.,LTD./TujiangVillage,ShaZhuangStreet,ShiTangTown,ZenChengCity/020-82905858緊急聯絡電話/傳真EmergencyPhone/Fax:020-82905858/020-82905868國家化學事故應急咨詢電話NationalConsultinghotlineforChemicalAccidents&Emergencies:0532-83889090II.危害辨識資料HazardIdentification緊急信息Informationinemergency:高度易燃Extremelyflammable.物品危害分類Producthazardclass:易燃液體第2級、腐蝕/刺激皮膚物質第3級、水環境之危害物質(慢毒性)第2級、吸入性危害物質第1級.Flammableliquidclass:2,burn/irritateskinmaterialclass:3,Hazardoustotheaquaticenvironment(Chronictoxicity)class:2,theinbreathedamagematerialclass:1標示:火焰fire,健康危害heathhazard刺激物質irritateskinmaterial環境危害Hazardoustotheaquaticenvironment警示語:危險SIGNALWORD:Danger危害成分:去渍油HAZARDOUSCOMPONENTS:solvent危害警告訊息:WARNINGFORHAZARD:1.易燃液體和蒸氣1.Flammableliquidandvapor.2.造成輕微皮膚刺激2.Lightlyirritationtoskin3.造成眼睛刺激3.Irritationtoeyes.4.長期或重複暴露可能會對器官造成傷害4.Hazardousorganifexposeforlongterm.5.如果吞食並進入呼吸道可能致命5.Itmaybedeathifswallowandgointotherespiratorysystem.6.對水生生物有毒並具有長期持續影響6.Ithaspoisontoaquaticanimalandeffectforlongterm.危害防範措施:AVOIDHAZARDPROCEDURES:1.遠離火源-禁止吸煙1.Keepawayfromflameandnosmoking.2.操作時通風良好,不用時容器蓋緊2.Useinawell-ventilatedarea,keepcontainerclosedtightly.3.配戴防護口罩和手套3.Useappropriaterespiratorandgloves.4.蓋緊容器4.Closeupthecontainer.眼睛接觸EyeContact:如不及時清除,會刺激眼睛,或傷害眼膜.Irritatingandmayinjureeyetissueifnotremovedpromptly.皮膚接觸SkinContact:經常或長期接觸會引起刺激或皮炎,重複或長期接觸會引起皮膚脫脂,導致皮膚刺激或乾燥.Frequentorprolongedcontactmayirritateandcausedermatitis.Repeatedorprolongedcontactmaycausede-fattingoftheskin,whichmayleadtoskinirritationand/ordryness.吸入Inhalation:吸入過量可能會刺激呼吸道,引起眼部刺激或嘔吐,應注意吸入的濃度不要超過TWA值.Overexposuremaybeirritatingtorespiratorypassagesandcauseothereffectssuchaseyeirritationornausea.CareshouldbetakennottoexceedtheTWA.食入Ingestion:刺激口,喉,胃.可能會引起胃部紊亂或傷害.在吞食或嘔吐時少量液體會滲入呼吸系統,可能會引起肺部浮腫,支氣管肺炎.Irritatingtomouth,throatandstomach.Maycausegastrictractdisorderand/ordamage.Smallamountofliquidaspiratedintotherespiratorysystemduringingestionorfromvomiting,maycausebronchopneumoniaofpulmonaryedema.III.成分辨識資料Composition/InformationonIngredientsKAIZHUOCHEMICALCO.,LTDMaterialSafetyDataSheet第2頁混合物Mixing:化學性質ChemicalCharacteristics:危害物質成分之中英文名稱HazardousComponentsName化學文摘社登記號碼CASNo.濃度或濃度範圍Concentration/Percentage(%)NFPA危害等級NFPAHazardRating去渍油SOLVENT8032-32-499.6%H:1/F:3/R:0*H:健康HealthF:火災FireR:反應ReactivityIV.急救措施FirstAidMeasures吸入Inhalation:將患者移至空氣清新處.如果呼吸困難,立即供氧;如果呼吸停止,立即施予人工呼吸並送醫治療.Removetofreshair.Ifbreathingisdifficult,giveoxygen.Ifbreathinghasstopped,giveartificialrespiration.Getmedicalattention.皮膚接觸SkinContact:以大量清水或肥皂水洗清.脫掉嚴重污染的衣服,鞋.在再穿之前洗淨,如果刺激持續,請就醫.Flushwithlargeamountofwater;Usesoapifavailable.Removegrosslycontaminatedclothing,includingshoesandlaunderbeforere-use.Discardshoes.Ifirritationpersists,getmedicalattention.眼睛接觸EyeContact:立即翻起上下眼瞼以大量水沖洗15分以上,並及時送醫治療.Immediatelyflusheyeswithlargeamountofwaterforatleast15minutes,liftingupperandlowerlids.Getpromptmedical食入Ingestion:避免催吐,如患者清醒,給予牛奶或水以稀釋胃液,注意保暖,保持休息,並送醫治療.Donotinducevomiting.Ifindividualisconscious,givemilkorwatertodilutestomachcontents.Keepwarmandquiet.Getpromptmedicalattention.最重要症狀及危害效應Themostimportantsymptomsandhazardouseffects:毒性極低,主要是抑制中樞神經Lowerpoison,anditmainlyeffectsoncentralnervoussystem.對急救人員之防護Theprotectionoffirst-aiders:應穿著C級防護裝備在安全區實施急救ThepersonwhoshouldwearCclassprotectsuitandcarryoutfirst-aidinsafetyarea.對醫師之提示Notetophysician:若是吸入,請考慮輸氧,若是食入,應考慮胃的傷害,避免碳酸鹽或重碳酸鹽.Forinhalation,consideroxygen.Foringestion,considergastricravage.Avoidcarbonates,bicarbonates.V.滅火措施FireFightingMeasure閃點FlashPoint:44℃自燃點Auto-ignition:280℃燃燒上下限Low/UpperFlammablelimits:1.1–9.4%適用滅火劑ExtinguishingMedia:適用滅火劑ExtinguishingMedia:使用水霧,泡沫,化學乾粉或二氧化碳滅火劑.Usewaterspray,foam,drychemicalorcarbondioxide.滅火程式Firefightingprocedures:消防人員須佩戴便攜式呼吸器以防止有毒或刺激性氣體.Firefightersshouldbeequippedwithself-containedbreathingapparatustoprotectagainstpotentiallytoxicandirritatingfumes.滅火時可能遭遇之危害Specifichazardsmaybeencounteredduringfire-firhting:1.氣體比空氣重,會傳播至遠處,遇火源可能造成回火。2.火場中可能產生毒性氣體。3.液體會浮於水面上,反而將火勢蔓延開。4.火場中容器遇熱可能爆炸.1.Thesteamisheavythanair,itwillspreadfaraway.Itmightbetemperwhensomewherehasfire.2.Itmightbeproducepoisonairinthefirescene.3.Theliquidwillfloatonthewater,anditwillhelpfirespreadeasily.4.Thecontainermightbeexplodedwhenit’sinthefirescene.滅火程式Specificfire-fightingmethods:1.不宜用水霧滅火,但可噴水霧吸熱冷卻容器及保護暴露於火場的物質。2.如外洩物未著火,可噴水霧驅散蒸氣、保護止洩人員並將外洩物沖離。3.撤退並自安全距離或受保護的地點滅火。4.位於上風處以避免危險的蒸氣和有毒的分解物。5.滅火前先阻止溢漏,如果不能阻止溢漏且周圍無任何危險,讓火燒完,若沒有阻止溢漏而先行滅火,蒸氣會與空氣形成爆炸性混合物而再引燃。6.隔離未著火物質且保護人員。7.安全情況下將容器搬離火場。8.以水霧冷卻火場的貯槽或容器。9.以水霧滅火可能無效,除非消防人員受過各種易燃液體之滅火訓練。10.如果溢漏未引燃,噴水霧以分散蒸氣並保護試圖止漏的人員。11.以水柱滅火無效。12.大區域之大型火災,使用無人操作之水霧控制架或自動搖擺消防水瞄。13.儘可能撤離火場並允許火燒完。14.遠離貯槽。15.貯槽安全閥已響起或因著火而變色時立即撤離。1.Thefireisnotsuitabletousewater,butitcanusewatertocooldownthecontainersandprotectthematerialsinthefirescene.2.Iftheleakmaterialisn’tonfire,itcanusethewatertocooldown,andwashawaythelea