有机化学十五个人名反应

十五个人名反应1.通过Witting反应合成吖丙啶-1,2-二羧基纤维素OR1R2R3NCO2EtR4R1R2R3NCO2EtR4R5PH2PHCR52.N-乙烯基甲酰胺和甲基乙烯基酮在碱性催化剂条件下发生Michael加成反应H2CCHNHHCO+H2CCHCOCH3H2CCHNHCCH2CH2COCH3O3.Diels-Alder反应+OOO20C°苯OOO4.烯丙基苯醚的Claisen重排反应OH2CCHCH2190~200C°OHH2CCHCH2邻烯丙基苯酚5.Fries重排反应OHC2H5COClOCOC2H5CS2OHCOC2H5+OHCOC2H56.Beckmann重排PhCOPhNH2OHCNH2OPhPhOHH2SO4,100C°OCHNPhPh苯甲酰苯胺7.Fisher重排反应NH3CNOHCl的乙醇溶液氨水或Na2CO3NH3CHNO8.Clemmensen还原反应OHC(CH2)5CH3OZn-Hg,HClOHCH2(CH2)5CH39.Wolff-Kishner-黄鸣龙还原反应CH3CONHCCH2CH2COOHOH2NNH2H2O,KOH140~160C°CH3CONHCH2CH2CH2COOH10.Hofmann重排反应MeMeO2COOHCOOHNH3CONH2CONH2NaOClNH2NH211.Perkin反应CHOOH+(CH3CO)2O(CH3COO)2CaOO