全氟辛烷

©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(,123002):,,,:;;PerfluorooctaneWANGEn2ren,WANGKui(FuxinFluorochemicalCo.,Ltd,Fuxin123002,China)Abstract:Thepropertiesandapplicationsofperfluorooctaneareintroducedanddifferenttechnologicalroutesforsyn2thesizingperfluorooctanearesummarized.Preparationmethodofperfluorooctanebasedonn2octaneandanhydroushydro2genfluorideasstartingmaterialsviaelectrochemicalfluorinationisdescribedindetailfinally.Keywords:perfluorooctane;hydrogenfluoride;electrochemicalfluorination,,(F2113),37011MPa,10148118,;,800;,400500,11/65/-60/104/(g/cm3)1176(25)/(mPas)018(25,10-4)/(m2/s)0175/(mN/m)14(N25)11271(215mm)/kV41(10-4)/%1111.1,HeN2CO2(),,,,,1.2(AgF2)(CoF3),250;,,(CoF2),,CoF3:11X:2004203216:(19432),,,,4128Vol.12,No.82004421FineandSpecialtyChemicals©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.:C8H18+18HF58V,05C8F18+18H215%30%,(C7F16,82)(C6F14,56),,,,,,,,,20%C8F17SO2Cl+HFNaF,58V1520C8F17SO2F+C8F181.4Simons,(,HF0102%),,,35mm,58V,010050101A/dm2,-55,-40,,,(NaHF2),,,5%,,30145,103105,,,98%2,,,,,,,(C7F16C10F18),,,1US2,519,9832US3,957,5963(5).:,1993.10021014..:,2001.312335..1998(2):452486...:,1990.87.J.,1998(4):102158..:,1995.30121128