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：2009-02-250(BCN)BN，BCN(h-BCN)BN(h-BN)，，，；BCN(c-BCN)BN(c-BN)，c-BN，。BCN、、，、、、、、、、、。BCN，，BCN(、、、、)。BCN。1BCNBCN、(CVD)、(PVD)、、、。1.1BCN1971，Kosolapova[1]B，N2NH3，1800~2000℃h-BCN。，，。Kawaguchi[2](CH2CHCN)nBCl3400℃，1000℃BC3N。90％，，。Hubacek[3]BC4N。Huang[4]CH3CN·BCl3Li3N，，330℃8~9MPa，BCN。1.2CVDBCN，BCN。BerkeleyBCl3CH，Kaner[5]CVDBNBCN。…………………………………………………②CVDB、C、N，h-BNB、C、N，B、C、N。Kouvetakis[6]CVD，BCl3CH3CN，750~900℃BC2N，。Yu[7]CVD(HFCVD)，N2、H2、CH4BCl3(B2H6)BCN，BCN、BCN、BCNBCN。1.3CVD、。BCN，，（，210009）BCN、、、，。BCN(、、、、)。BCN；;JiangsuCeramics42320096Vol.42,No.3June,2009B(s)+C(s)+N2/NH3(g)BCN(s)…………①1800~2000℃BCl3(g)+C2H2(g)+NH3(g)BCN(s)+HCl(g)+H2(g)400~700℃25，BCN。Dinescu[8]，h-BN，(10-5Pa)N2(1~100Pa)，SiBC2N。，BCN。[9]，B4CBB-C300~500℃、8×10-2Pa，BCN。Zhang，BN、CNiCo，1000℃1200℃N2，BCN[10]。1.4BN，BCN。Knittle[11]30GPa、1227℃BCN(BN)1-xCx(x=0.3~0.33，0.5，0.6)，。[12]BCN。B2CN，Ca3B2N4，5.5GPa、1600℃BCN。B2CN。1.5。，，，、、，BCN。Yao[13]BN，120hBC2***GPa880KBCN。[14]，120h，1200℃6h，、B0.49CN0.11，BCN。1.6，，BCN。Riedel[15]－BCN，BH3·C5H5NBH3·C4H10N21050℃，、BC4NBC2N，。Terrones[16]CH3CNBCl3CH3CN·BCl3，900~1000℃，CoBCN。－(Sol－gel)。Volger[17]－，()，1200℃B4CN4BCN。2BCN，BCN，BCN，CBCN，CB、NBCN。B-C-NB、N，。，BCN、、、、、、。、、、、BCN。[1]KosolapovaTY,MakarenkoGN,SerebryakovaTI,etal.Boroncarbonitride..Conditionsforpreparingboroncarbonitride[J].Poroshk.Metall.,1971,1:25~27[2]KawaguchiM,KawashimaT.Synthesisofanewgraphite-likelayeredmaterialofcompositionBC3N[J].J.Chem.Soc.,Chem.Com-mun.,1993,(14):1133~1134[3]HubacekM,SatoT.PreparationandpropertiesofacompoundintheB-C-Nsystem[J].J.SolidStateChem.,1995,114(1):258~264[4]HuangFL,CaoCB,XiangX,etal.SynthesisofhexagonalJiangsuCeramics2009642326boroncarbonitridephasebysolvothermalmethod[J].DiamondRelat.Mater.,2004,13:1757~1760[5]KanerRB,KouvetakisJ,WarbleCE,etal.Boron-carbon-ni-trogenmaterialsofgraphite-likestructure[J].Mater.Res.Bull.,1987,22:399~404[6]KouvetakisJ,SasakiT,ShenC,etal.NovelaspectsofgraphiteintercalationbyfluorineandfluoridesandnewB/C,C/N;andB/C/Nmaterialsbasedonthegraphitenetwork[J].SyntheticMetals,1989,34:1~7[7]YuJ,BaiXD,AhnJ,etal.HighlyorientedrichboronB-C-Nnanotubesbybias-assistedhotfilamentchemicalvapordeposi-tion[J].Chem.Phys.Lett.,2000,323:529~533[8]DinescuM,PerroneA,CaricatoAP,etal.Boroncarbonni-tridefilmsdepositedbysequentialpulseslaserdeposition[J].Appl.Surf.Sci.,1998,127-129:692~696[9]LeiMK,YuanLJ,ZhangZL,etal.Cubic-BN-likeB-C-Nstructurefilmssynthesizedbyplasmasourceionnitriding[J].Chin.Phys.Lett.,1999,16(1):7l~73[10]ZhangY,GuH,SuenagaK,etal.HeterogeneousgrowthofB-C-Nnanotubesbylaserablation[J].Chem.Phys.Lett.,1997,279(5-6):264~269[11]KnittleE,KanerRB,JeanlozR,etal.High-pressure**nthe-sis,characterization,andequationofstateofcubicC-BNsolidsolu-tions[J].Phys.Rev.B,1995,51:12149~12156[12]HeJL,TianYJ,YuDL,etal.OrthorhombicB2CNcrystalsynthesizedbyhighpressureandtemperature[J].Chem.Phys.Lett.,2001,340(5-6):431~436[13]YaoB,LiuL,SuWH.Formation,characterization,andprop-ertiesofanewboron-carbon-nitrogencrystal[J].J.Appl.Phys.,1999,86:2464~2467[14],,,.[J].,2005,56(2):363~367[15]RiedelR,BillJ,PassingG.Anovelcarbonmaterialderivedfrompyridine-borane[J].Adv.Mater.,1991,3(11):551~552[16]TerronesM,BenitoAM,Manteca-DiegoC,etal.PyrolyticallygrownBxCyNznanomaterials:nanofibresandnanotubes[J].Chem.Phys.Lett.,1996,257(5-6):576~582[17]VolgerKW,KrokeE,GervaisC,etal.B/C/NmaterialsandB4Cs***hesizedbyanon-oxideSol-Gelprocess[J].Chem.Mater.,2003,15(3):755~764ResearchProgressonPreparationMethodsofBCNCompoundsPanLimei,YangJian,QiuTai（CollegeofMaterialsScienceandEngineering,NanjingUniversityofTechnology,Nanjing210009）AbstractOwingtoespecialpropertiesinelectrical,optical,thermalandmechanicalpropertiesaswellaspromisingapplicationprospect,novelBCNcompoundshavebecameoneofthehottestfieldsininternationalmaterialsresearch.Inthispaper,preparationmethodsofvariousBCNcompounds(includingfilm,powder,fiber,nano-rod,nano-tube)werereviewed.KeywordsBCNcompound,preparationmethod,researchprogress：BCN!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!，。，。，，、。。，10~15，。，，、、，，，。，（），，、、、、、、、、、，，，。，、、，15。20℃～1300℃。300W1000，，。“，”。，；，，，、、、KTV、、，。。，，，。27