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Schiff(,712000)Schiff,Schiff,Schiff:2008-03-24:(1980),,,ApplicationandResearchDevelopmentofSchifBasesandTheirComplexesZhangYinli(XianyangNormalUniverity,ShanxiXianyang712000)AbstractTheschiffbaseligandsandthecorrespondingcomplexesarebecomingratherimportantfortheirex2tensiveappliances.ThedevelopmentprocessesofSchiffbasesandtheresearchinbiochemistry,catalystchemistry,a2nalysischemistryandmaterialchemistrywerereviewed.Theschiffbaseligandsandthecorrespondingcomplexeswillbemorewidelyappliedinthefuture.KeywordsSchiffbasemetalcomplexapplicationresearchSchiffRCN,HSchiff1864[1]CN,Nsp2,,,[2],[34],,Schiff11.1,Schiff[5],,,,HChenJRhodes[6]SchiffNakahara[7]Schiff,,Hodnett[8]RC6H4CHNC6H4R’24Schiff,,R2-MeR2-OHSchiff,,Schiff,HMatloubia[9]Schiff,Schiff[10][11](),6522520085ChemicalIndustryTimesVol.22,No.5May.5.2008;()()();[1213]Schiff,(sal):Cu(sal-Gly)Cu(sal-Ala)Cu(sal-Val)Cu(sal-Leu),R(RH,CH3,CH(CH3)2),,[1415],,Schiff,,1.2Schiff,Schiff[16],[17]Schiff,,1.3,,(O2-),(SOD)(O2-)O2H2O-SchiffSchiffO2-[18]Er-Schiff,,[1921]NOSSchiffCu(II),Zn(II),,O2-,[22]O2-,O2-,()22.1Schiff,,,STGirousi[23]Schiff,,HYaminiShrivastava[24],,,[25]DL-L-L-L-5Schiff()()()(),,[26]N-2.2Schiff,,,:[27]Schiff,CAA,,,Khuhawar[28],,[29]Schiff,SchiffPVC,Schiff,[3031]3Schiff,,75Schiff20081Vol122,No.5,,Schiff,,[32][33]Schiff,,Schiff,[34],Schiff,Schiff,[3536]Mn()Schiff,[37],,1988SakateCo(1-Co),,EilmesCo(2-Co),1989NakajimaKijima[38]54,CasellaGullotti[39]Co(Sal-L-Ala)(L-Ala=L-)[40],SchiffSchiff:[41]SchiffMMA,[42]SchiffMMA[43]4Schiff--,-,Schiff5,,,,,,,,()Schiff,O2N2,,O2N2,O2,N2Schiff-O2N2,SchiffSchiff[44]62SchiffCN,,[45]SchiffSchiff,,,,[46]Schiff,Schiff,,[47],,8520081Vol122,No.5Reviews[48],Schiff,,[4950],[51],Schiff[1],,,.[M].:,2000[2].[2+2]Schiff[J].,2004,24(12):16331636[3]MAshok,BSHolla,BPoojary.Convenientonepotsyn2thesisandantimicrobialevaluationofsomenewMannichbasescarrying4-methylthiobenzylmoiety[J].EuropeanJournalofMedicinalChemistry,2007,42(8):10951101[4]MShiradkar,GVSureshKumar,VDasari.,etal.Club2bedtriazoles:Anovelapproachtoantituberculardrugs[J].EuropeanJournalofMedicinalChemistry,2007,42(6):807816[5]AVogt,SWolowiec.,etal.Synthesisandcharacterizationofnickel(II),copper(II),manganese(III)andiron(III)complexeswithnewchiralsalen-typeligand[N,N-bis(3,5-di-tert-butylsalicylidene)-(1R,3S)-1,3-diamine-1,2,2-trimethylcyclopentane][J].Polyhed2ron,1998,17(8):12311240[6]HChen,JRhodes.Schiffbaseformingdrugs:mech-an2ismsofimmunepotentiationandtherapeuticpoten-tiM[J].Mol.Med.,1996,74:497504[7]PLumme,HEloHonnu.,etal.Antitumoractivityandmetalcomplexesofthefirsttransitionseries.Trans-bis(salicylaldoximato)copper(II)andrelatedcopper(II)complexes,anovelgroupofpotentialantitumoragents.[J].Inorg.Chim.acta,1984,92(4):241251[8]EMHolnett,WJDunn.AntiproliferativeeffectsofsomeN-benzylideneanilines[J].Med.Chem.,1970,13:768770[9]HMatloubian,AShafieeb,NSaemiana,GShirvania,FJDaha.Synthesisofcarbon-14analogueof1,5diaryl-5-[14C]-1,2,3-triazoles[J].AppliedRadiationandIso2topes,2004,60:665668[10],.()---[J].,1997,13(1):5357[11],,.4Cu(1I)Zn(1I)Co()Ni(1I)[J].,1995,29(2):197201[12],.()[J].,1996,12(4):423426[13],,.N-3d[J].,1995,12(6):1316[14],.5-(II)[J].,1996,11(2):6971[15],,.5--N-(2-)Schiff[J].,1998,20(1):4243[16],,.N-11,2,4-[J].,1996,(10):614[17],,,.Schiff[J].,2000,30(5):4243[18],,.[J].,2001,18(1):14[19],.Schiff[J].1999,14(2):145147[20],.Cu,Zn-SODO2-[J].,1999,16(6):656658[21],.NOSSchiff()()[J].,1999,16(3):265267[22],,.,,O2-[J].,1999,11(4):402405[23]STGirousi,EEGolia,ANVoulgaropoulos.Flu-oro2metricdeterminationofformaldehyde[J].Springer-Ver2lag,1997,358:667668[24]HYShrivastava,BUNair.Afluorescence-basedassayfornanogramquantificationofproteinsusingaproteinbindingligand[J].AnalBioanalChem,2003,375:169174[25],.N-95Schiff20081Vol122,No.5[J].,1992,14(3):301304[26],.N-[J].,1993,15(2):111113[27].-[J].,1999,23(4):373374[28]MYKhuhawar,SNLanjuani.High-perfor-manceliq2uidchromatographicdeterminationofu-raniumusingsol2ventextractionandbis(salicylade-hyde)tetramethyl2enediimineascomplexingreagent[J].Chromatographia,1995,42:19251929[29],,.(HPMaFP)EN[J].,1996,18(6):327329[30]MReza,TPoursaberi,FBasiripour.Highlyselectivethio2cyanatepoly(vinylchloride)membraneelectrodebasedoncadmi-umSchiff’sbasecomplex[J].FreseniusJAnalChem,2001,370:10911095[31]ZYSun,RYuan,YQChai.,eta1.Studyofabisfural2dehydeSchiffbasecopper(I)complexascarrierforprepa2rationofhighlyselectivethiocyanateelectrodes[J].A2nal.BioanalChem.,2004,378:490494[32],,,.()-[J].,2001,22(1):7780[33],,Wkraus.Schiff[J].,1995,17(1):6568[34],.(I)Schiff(BPMBNDI)[J].,1998,56(5):484488[35],.Schiff(I)[J].,1997,18(4):567570[36],.()[J].,1997,12(1):2630[37],,,.(Mn,Co,Ni)SalenNaOCl[J].,1998,18(2):228234[38]KNakajina,MKojima,KToriumi.,etal.Crystal-Structuresof[VO(Sal-L-Ala)(OCH3)(CH3OH)](Sal-L-Ala=N-Salicylidene-L-Alaninate)and[[VO(Sal-L-Ala)]20]2.2CH2Cl2,andtheCatalyticActivityofTheseandRelatedComplexesonAsymmetricOxidationofMethylPhenylSulfidewithTert-butylHy2droperoxide[J].Bull.Chem.Soc.Jpn.,1989,62(3):760767[39]LCasella,MGullotti.,Synthesis,stereochemistry,andoxygenation