固体有机垃圾厌氧消化处理的研究进展

陈庆今刘焕彬胡勇有(,510640):,,,:;:X705,S2164:A:1000-1166(2001)03-0003-06AReviewontheDevelopmentofAnaerobicDigestionofOrganicSolidWastes/CHENQingjin,LIUHuanbin,HUYongyou/(CollegeofPapermakingandEnvironmentalEngineering,SouthChinaUniversityofTechnology,Guangzhou,510640)Abstract:Manylatestmaterailswasquotedtointroducethedevelopmentintheresearchonanearobicdigestionofsolidorganicwastes(SOW)TheconclsionwasmadethattheanearobicdigestionisthemostbiologicallysoundandeconomicallyfeasibleapproachuptodateinSOWtreatment.Keywords:OrganicSolidWastes;AnaerobicDigestion,85%~90%,,,,,,,1,,1.1在生态环境保护方面具突出优势Baldasano[1],Eldelmann(1999)[2],,Kubler(1999)[3],++++0.2t1.2在经济上是可行的,,,,,100~150m3:2000-12-04:2001-05-15:(1971-),,,,3ChinaBiogas2001,19(3),Edelmann(1999)[2]10000t!a-1+,Kubler(1999)[3],15000t!a-1,75kWh!a-1,,240kWh!a-122.1基本反应及反应动力学,,,,,,[7],,,MonodContois,Siegrist(1993)[4],,pH,,(JMataAlvarez,etal.1999)[5],,,VeekenHammelers(1999a)6(,,,,)20∀0.003~0.15d-1,40∀0.24~0.47d-1Vavilin(1996)###MonodContois()###,,,,Monod,Contois,,,,,,,A.RodriguezAndara(1999)[6]Vavilin,,,,,0.75d-10.048d-1,Sanders(1999),4mg!m-2h-1,,,F.GarciaOchoa,etal.(1999)[7],6,4ChinaBiogas2001,19(3)COD,3LilianaBoarzacconi(1997)[8],Monod0.8∃10-3d-1,VFA,Kyeli(1997)[9],1[3]K/d-1()()0.005~0.010(Christ,1999)0.015~0.075(Christ,1999);0.081~0.177(Zeeman,1999,pHdependent)0.025~0.200(Christ,1999)0.4(Vavilin,1999)0.012~0.042(Kalyuzhnyi,1999)0.03~0.15(20∀)(VeekenandHamelers,1999a);0.24~0.47(40∀),,pHAngelidaki[10](1998),,pH,VFA,819##2.2厌氧消化微生物研究,Geoffery(1989)[11],,Silvey(1999)[12],18~38d,60~90d,,#,,,(denaturinggradientgelelectrophoresis),,(),,2.3厌氧消化反应阻抑研究,,10000mg!L-1,1000mg!L-1,,,,5ChinaBiogas2001,19(3)MarekMosche(1999)[13],pH,pH/1,/,,,,KaarehvidHansen(1998)[14]CSTR,6gN!L-1,pH8,1.1gN!L-1,Fujishima(2000)[15],,,750mgN!L-1,3400mgN!L-1,4400mgN!L-1:1;2C/NPoggiVaraldo(1997)[16]COD/N90,80,6550,,,,COD/N50,pH6.5~8.5,NH4+N,NH4+N1670~3720mg!L-1,90%,4090~5550mg!L-150%,5880~6600mg!L-1,,,500mg!L-1,,NH4+3,,,3.1化学处理,Jihgawlin(1997)[17]NaOH,,,(38%~163%),Ghosh(1999)[18]0.5gNaOH!100g-1,35%NallathambiGunaseelanV(1995)[19],45%60%Schieder(1999)[20],,,Clarkson(1999)[21],,M.Weemaes(2000)[22]67%,29%%3%,38%%9%,0.1gO3!gCOD-1,1.8,2.20.7~3.0gO3!gCOD-1,,0.375EUR!kgTDS-1()6ChinaBiogas2001,19(3)3.2生物预处理[3],,,H2SAmendaWard(1998)[23],(24h),,3.3机械预处理,,:,,,[19,24];,(Palmowsky,2000)[25]Hartmann(1999)[26],25%,Angelidaki(1999)[20],17%,,520mm,InWookNah(2000)[27]30Pa,,(13d6d),,Engelhart(1999)[28]()25%4,,,,,,:[1]BaldasanoJM,SorianoC.Emissionofgreenhousegasesfromanaerobicdigestionprocesses:Comparisonwithothermunicipalsolidwastetreatments[J].WatSciTech,2000,41(3):15-18[2]WEdelman,etal.Ecological,energeticandeconomiccomparisonofanaerobicdigestionwithdifferentcompetingtechnologiestotreatbiogenicwastes[J].WatSciTech,2000,41(3):263-274.[3]H.Kubler,etal.Fullscalecodigestionoforganicwaste[J].Wat.Sci.Tech,2000,41(3):195-202.[4]SiegristH,etal.Mathematicalmodellingofanaerobicmesophilicsewagesludgetreatment[J].WaterSciTechnol,1993,27(2):25-36.[5]J.MataAlvarez,etal.1999.Anaerobicdigestionoforganicsolidwastes:Anoverviewofresearchachievementsandperspectives.BioresourceTechnology74(2000)316[6]ARodriguezAndara,etal.Kineticstudyoftheanaerobicdigestionofthesolidfractionofpiggeryslurries[J].BiomassandBioenergy,1999,17:435-443.[7]FGarciaOchoa,etal.KineticModelforAnaerobicDigestionofLivestockManure[J].EnzymeandMicrobialTechnology,1999,25:55-60.[8]LilianaBoarzacconi,etal.HydrolysisconstantandVFAinhibitioninacidogenicphaseofMSWanaerobicdegradation[J].WatSciTech,1997,36(6-7):479-484.[9]KielyG,etal.Physicalandmathematicalmodellingofanaerobicdigestionoforganicwastes[J].WaterRes,1997,31(3):534-540.[10]IriniAngelidaki,etal.Comprehensivemodelofanaerobicbioconversionofcomplexsubstratestobiogas[J].BiotechnologyandBioengineering,1999,63(3):363-372.[11]GeoffreyLR,Gordonetc.DegradationandUtilizationofCelluloseandStrawbythreedifferentanaerobicFungifromtheOvineRumen[J].ApplEnvironMicrobiol,1989,55(7):1703-1710.7ChinaBiogas2001,19(3)[12]PSilveyPC,etal.Microbialecologyoftheleachbedanaerobicdigestionofunsortedmunicipalsolidwaste[J].2000,WatSciTech,41(3):9-16.[13]MarekMosche,etal.Comparisonofdifferentmodelsofsubstrateandproductinhibitioninanaerobicdigestion[J].WatRes,1999,33(11):2545-2554.[14]KaarehvidHansen,etal.Anaerobicdigestionofswinemanure:inhibitionbyammonia[J].WatRes,1998,32(1):5-12.[15]Fujishima,etal.Effectofmoisturecontentonanaerobicdigestionofdewateredsludge:ammoniainhibitiontocarbohydrateremovalandmethaneproduction[J].WatSciTech,2000,41(3):119-128.[16]PoggiVaraldo,etal.Inhibitionofmesophilicsolid-substrateanaerobicdigestionbyammonianitrogen.ApplMicrobiolBiotechnol,1997,47(3),284-291.[17]JihgawLin,etal.Enhancementofanaerobicdigestionofwasteactivatedsludgebyalkalinesolubilization[J].BioresourceTechnology,1997,62:85-90.[18]SGosh,etal.Pilotscalegasificationofmunicipalsolidwastebyhighrateandtwophaseanaerobicdigestion(TPAD)[J].WatSciTech,2000,41(3):101110.[19]NallathambiGunaseelanV.Effectofinoculum/substrateratioandpretreatmentsonmethaneyieldfromparthenium[J].Biomas