ZirconiumPowderSectionI.ChemicalProductandCompanyIdentificationChemicalName:ZirconiumMetalPowderSynonym:ZirconiumMetalPowderWettedCASNumber:7440-67-7ChemicalFormula:ZrSectionII.CompositionandInformationonIngredientsMaterialCAS#%OSHAACGIHZirconiumWater7440-67-77732-18-570%30%5mg/m³NotEstablished5mg/m³NotEstablishedSectionIIIHazardsIdentification:Dangerousclass:No4.3Bynow,havenotreporttedfortheindustrialpoisoningSectionIV.FirstAidMeasuresoFirstAidForEye:Incaseofcontact,immediatelyflusheyeswithplentyofwaterforatleast15minutes.Callaphysician.oFirstAidForSkin:Incaseofcontact,flushskinwithwater.Washclothingbeforereuse.Callaphysicianifirritationoccurs.oFirstAidForInhalation:Ifinhaled,removetofreshair.Ifnotbreathing,giveartificialrespiration.Ifbreathingisdifficult,giveoxygen.Callaphysician.oFirstAidForIngestion:Ifswallowed,callaphysicianimmediately.SectionV.FireandExplosionDataoFlammability:Non-FlamableoFlashPoints:NotApplicableoAuto-Ignition:NotApplicableoFlammableLimits:NotApplicableoExtinguishingMedia:UseapprovedclassDextinguishersorsmotherwithdrysand,drygroundlimestoneordryclay.DONOTUSEWATER.DonotusecarbondioxideextinguisheronthismaterialoFireFightingProcedure:Wearself-containedbreathingapparatusandprotectiveclothingtopreventcontactwithskinandeyes.FLAMMABLESOLID.oFire/ExplosionHazards:Emitstoxicfumesunderfireconditions.SectionVI.AccidentalReleaseMeasuresSupplier:LinyiPengluInternationalTradingCo.,Ltd.103,HongqiRoad,LinyiCity,276000,ChinaTel:865398071883MaterialSafetyDataSheetoSpillOrLeakProcedures:Shutoffallsourcesofignition.Utilizerecommendedprotectiveclothingandequipment.Usenonsparkingtools.Cleanspillsinamannerthatdoesnotdispersedustintotheair.Sweepup,placeinabagandholdforwastedisposal.Spillareacanbewashedwithwater.Collectwashwaterforapproveddisposal.Keepfromenteringwaterorgroundwater.SectionVII.HandlingandStorageoStorageTemperatures:StoreatambienttemperatureoShelfLife:Unlimitedintightlyclosedcontainer.oSpecialSensitivity:NoneoHandling/StoragePrecautions:Avoidbreathingdust.Avoidgettingineyesoronskin.Washthoroughlyafterhandling.Storeinadryplaceawayfromdirectsunlight,heatandincompatiblematerials(seeSectionX).Resealcontainersimmediatelyafteruse.Storeawayfromfoodandbeverages.oAdditionalInformation:Zirconiumreactswithcarbontetrachloride,copperoxide,leadoxide,potassiumchlorateandnitrate,borax,sulfates,tungstates,molybdates,alkalimetalhydroxides,chromates,anddichromates.Itscombustioninairisstimulatedbythepresenceoflimitedamountsofwater.Autoignitiontemperatureofdustcloudis68°F.Itwillburninanatmosphereofcarbondioxide.Zirconiummetalpowderispackagedwith30%ormoreofwater.Donothandledry!Handleonlyunderaminimumof30%waterorinprotectiveargonatmosphere.Zirconiumpowdercanautoigniteinairwhendry.Itisextremelysensitivetoshock,heat,frictionandstaticelectricity.Settledzirconiummayformahardcake,reslurrybyrollingtheshippingcontaineronaball-milltyperollerforaminimumof30minutes.Donotattempttoremovezirconiumifithassettledinthecontainer.Frictioncancauseignitionifwatercontentofthematerialislow.Routineinspectionofproductcontainersforpossibleleakageordryingishighlyrecommended.SectionVIII.ExposureControls/PersonalProtectionoEyeProtection:Safetyglassesorgoggles.oSkinProtection:PVCgloveswithimperviousboots,apronorcoveralls.Employeesshouldwashtheirhandsandfacebeforeeating,drinkingorusingtobaccoproducts.oRespirator:Workambientconcentrationsshouldbemonitoredandiftherecommendedexposurelimitisexceeded,aNIOSH/MSHAapproveddustrespiratormustbeworn.oVentilation:Uselocalventilationifdustingisaproblem,tomaintainairlevelsbelowtherecommendedexposurelimit.oAdditionalProtectiveMeasures:Emergencyshowersandeyewashstationsshouldbeavailable.Educateandtrainemployeesinthesafeuseandhandlingofhazardouschemicals.SectionIX.PhysicalandChemicalPropertiesoPhysicalForm:AmorphousPowderoColor:Bluish-BlackoOdor:OdorlessoMolecularWeight:91.22oBoilingPoint:3577&3176CoMelting/FreezingPoint:1845°CoSolubilityInWater:InsolubleoSpecificGravity:6.49SectionX.StabilityAndReactivityoStability:StableoHazardousPolymerization:WillNotoccuroIncompatibilities:StrongAcids,StrongOxidizingAgents,HydrogenFluoride,Phosphorus,Oxygen,Lead,andSensitiveToAiroInstableConditions:Excessivetemperatures(seeIncompatibilities).oDecompositionTemperature:UnknownoDecompositionproducts:UnknownSectionXI.ToxicologicalInfomationoRTECSNumber:ZH7070000oRoutesofExposure:Eyecontact.Ingestion.Inhalation.Skincontact.oToxicityData:Tothebestofourknowledge,thechemical,physical,andtoxicologicalpropertieshavenotbeenthoroughlyinvestigated.oChronicToxicEffects:Thisproducthasnoknownchroniceffects.Repeatedorprolongexposuretothiscompoundisnotknowntoaggravatemedicalconditions.oAcuteToxicEffects:Irritatingtotheskinandeyesoncontact.Inhalationwillcauseirritationtothelungsandmucusmembrane.Irritationtotheeyeswillcausewateringandredness.Reddening,scaling,anditchingarecharacteristicsofskininflammation.Followsafeindustrialhygienepracticesandalwayswearprotectiveequipmentwhenhandlingthiscompound.SectionXII.EcologicalInformationoEcotox