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第十五届中国覆铜板技术·市场研讨会暨覆铜板产业协同创新国际论坛论文集彭康1郭金雷1胡娇1徐庆玉2王洛礼21.江汉大学湖北省化学研究院2.华烁科技股份有限公司苯并嗪作为一种新型的酚醛树脂，因其一些独特的优异性能正受到研究者的广泛重视。本文分别从新型结构苯并嗪和环境友好型苯并嗪的合成、苯并嗪复合材料的制备以及苯并嗪的应用等几个方面，综述了近两年苯并嗪的研究进展。Abstract:Benzoxazine,anovelphenolicresinwithavarietyofuniquecharacteristics,hasattractedintensiveattention.Thisarticledescribedthesynthesisofbenzoxazinewithnovelmolecularstructureandenviron-ment-friendlybenzoxazine,preparationofbenzoxazine-basedcompositeandapplicationsofbenzoxazineinrecentyears.Keywordsbenzoxazine;moleculardesign;environment-friendly;composite;ternarysystem;printedcircuitboard134--13-3,4-dihydro-1,3-benzoxazineBOZ、Mannich1-1。、、。。。[1,2]。2~10%[3,4][5]。。、、1-1198--第十五届中国覆铜板技术·市场研讨会暨覆铜板产业协同创新国际论坛论文集。、、、、。。、。2、、。2.1、、。Takeichi[6]3-、A、130℃30minB-3pyB-3pyA-B-aPB-3pyB-aPB-aPB-3py5%10%Td850℃PB-a。[7]。[8]、10%293℃800℃53%。[9]402℃800℃60%150℃2.1-2.30.003。[10]。[11]3-Si-O-Si。[12]Dielse-Alder120℃。[13]Tg205℃Td=384℃1GHz3.90.0090.25%UL94V-0PCB。[14-16]、[17,18]、[14,15,19]。199--第十五届中国覆铜板技术·市场研讨会暨覆铜板产业协同创新国际论坛论文集2.2、、。、、。Ishida[20]4MPa120MPa。[21]、53%62%。Sini[22]MannichVa-BzBOZ[23,24]800℃65%。[25]U-daP-daU-da180℃。[26-28]、[24,29]、[30]。2.3[31]Hummers、、。、[32]。(PolyhedralOligomericSilsesquioxanePOSS)/、POSS、POSS[33]POSS[34-36]。Zhang[37]OPSOPSA-BOZPOSS/PBzPOSS10Hz~1MHz。Jana[38]TgA-BOZSMPUBOZSMPU。、17.4200--第十五届中国覆铜板技术·市场研讨会暨覆铜板产业协同创新国际论坛论文集91%。Dumas[39]-CNTsCNTsCNT0.3wt%38%。[40]A、。2.42000RimdusitIshida[41]、。、。。。。Rimdusit[42-44](PM-DA)、3,3’,4,4’(S-BPDA)、3,3’,4,4’(BDTA)3。tanδ。、。。2-1。[45]。134%。[46][10][10,2-1201--第十五届中国覆铜板技术·市场研讨会暨覆铜板产业协同创新国际论坛论文集47][48]。3ChemicalAbstractsBenzoxazineResearchTopic2012、2013400~5002014273201485。、。。参考文献[1]NairCPR.Advancesinaddition-curephenolicresins[J].ProgressinPolymerScience,2004,29(5):401-498.[2]IshidaH,LowHY.AStudyontheVolumetricExpansionofBenzoxazine-BasedPhenolicResin[J].Macro-molecules,1997,30(4):1099-1106.[3]DongJ-P,ChiuS-G,HsuM-W,etal.Effectsofreactivelow-profileadditivesonthevolumeshrinkageandinternalpigmentabilityforlow-temperaturecureofunsaturatedpolyester[J].JournalofAppliedPolymerScience,2006,100(2):967-979.[4]AlcoutlabiM,McKennaGB,SimonSL.Analysisofthedevelopmentofisotropicresidualstressesinabis-maleimide/spiroorthocarbonatethermosettingresinforcompositematerials[J].JournalofAppliedPolymerScience,2003,88(1):227-244.[5]IshidaH,AllenDJ.Physicalandmechanicalcharacterizationofnear-zeroshrinkagepolybenzoxazines[J].JournalofPolymerSciencePartB:PolymerPhysics,1996,34(6):1019-1030.[6]ShibayamaY,KawauchiT,TakeichiT.Synthesisandpropertiesofpolybenzoxazinescontainingpyridylgroup[J].HighPerformancePolymers,2014,26(1):60-68.[7]刘孝波,徐明珍,杨旭林.一种腈基树脂单体和聚合物及其制备方法:CN,102976972A[P].2013-03-20.[8]王标兵,张淑娴,王留阳.一种含磷苯并嗪的制备方法:CN,102863618A[P].2013-01-09.[9]陈金州.新型耐高温低介电双苯并嗪树脂:CN,103059296A[P].2013-04-24.[10]许凯,苏江勋,付子恩,etal.含Schiff碱结构苯并嗪单体、苯并嗪树脂及其制备:CN,103058948A[P].2013-04-24.[11]ZhouC,LuX,XinZ,etal.Corrosionresistanceofnovelsilane-functionalpolybenzoxazinecoatingonsteel[J].CorrosSci,2013,70:145-151.[12]ChenN-H,LiH-Y,LaiJ-Y,etal.Synthesisandcharacterizationofbenzoxazine-containing,crosslinkable,andsulfonatedpolymerthroughDiels-Alderreactionfordirectmethanolfuelcells[J].Polymer,2013,54(8):2096-2104.[13]WuHH.Melaminecompoundandmethodformanufacturingthesame:US,8299244B1[P].2012-10-30.[14]刘文彬,李悦,王军,etal.苯并嗪封端芴基聚醚酮酮热塑性树脂及其制备方法:CN,102875807A[P].2012-9-14.其余略202--