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TheworldisourinspirationIntroductionofIntroductionofNewNewHighPerformanceHighPerformanceBioBasedBioBasedTransparentPATransparentPARilsanRilsan®®ClearG830ClearG830RnewRne®ClearMarketManager2TechnicalPolymersBusinessUnit20073.3%5%ArkemaTechnicalpolymersSALES%ofArkemaSalesR&D%ofSales60yearsofinnovation3R&DCenters9FactoriesWORLDLEADER…Polyamides12&Polyamide11-Rilsan®A&Rilsan®BPolyetherBlockAmide-Pebax®HeatsealCopolyamides-Platamid®High-performancebiobasedpolymers-Rilsan®B&Pebax®Rnew~10%3RenewableacleargoalforArkema««MovingforwardinMovingforwardintheenvironmentaltheenvironmentalperformanceperformance»»200620062006DemonstrateitsenvironmentalperformanceDevelopadditivesforBioplastics200720072007BiobasedGeneration1BiobasedGeneration1withlowVOC2010…2010…2010…NewproductsfromBio-refineryconcept200820082008FirstbiobasedtransparentpolyamideBiobasedalloys-ExpandedpropertiesPrimerlessconcept200920092009NewHighPerformancePolyamideBiobasedGeneration2‘‘GOAL:Renewableswillrepresent10%ofArkematurnoverin2010’’ThierryLeHénaffArkemaCEO41stgenerationTransp.PA(Semi-aromaticPolyamideorPASA)Rigid2ndgenerationTransparentPA(Cyclo-aliphaticPolyamideorPACA)LimitedFlexibility2006GenerationTransp.PA:Rilsan®ClearG350Introducedin2006HongKongOpticalFairOutstandingflexibilitySuperlightExcellentChemicalresistanceEasyprocessabilityRilsan®Clearbackground5FirstBiobasedTransparentPA:Rilsan®ClearG830Rnew53%BiobasedEnvironmentfriendly,ReduceCO2emissionSuperLight–Density1,02g/cm3HighFlexibilityandshaperetention,FullTransparencyExcellentchemicalresistanceEasyProcessAppliedforNewBiobasedRilsan®Clear6Rilsan®ClearG350ismoretransparentthanglassandforanythicknessHighTransparency8890909091.591.5928687888990919293PCGlassRilsan®ClearG110Rilsan®forSkiRilsan®ClearG350Rilsan®ClearG350biobasedPMMARilsan®ClearG350TRANSMITTANCE[%](ISO13468:Thickness:2mm,Wavelength:560nm)Rilsan®ClearG830RnewRilsan®ClearG1107Rilsan®ClearG350thelightesttransparentpolymer,20%lighterthanPC“Fasterspeed&agility”“Energysavings”criticalforsports&transportation“Ultracomfort”UltraLightweight0.991.021.051.191.19Rilsan®ClearG350Rilsan®ClearG350BiobasedRilsan®ClearG170PMMAPCRilsan®ClearG350DENSITY:Rilsan®ClearG830RnewRilsan®ClearG1708FlexibilityRilsan®ClearG350themostflexibleoftransparentthermoplasticRilsanClearG830:theBio-PAwithgoodflexibility“Longlastingendurance”“GreatShaperecovery”“Vibrationdampening”3,2002,4001,8001,4901,4801,3600500100015002000250030003500PMMAPCRilsan®ClearG110RilsanClear®G350Biobased2ndgenerationtranspPARilsanClear®G350Rilsan®ClearG830RnewFLEXURALMODULUS(Mpa)Rilsan®ClearG350Rilsan®ClearG1109EnvironmentalStressCrackingResistancetestResults:5=nothingappears;4=smoothcrack;3=importantcrack;2=crackwithneck-in,1=break(ESCR)IFCsamplesputunderstresswereimmersedinpuresolventduring22hoursat23°C(ISO4599)Puresolvent@23°CIFCsamplesunderstress012345Rilsan®ClearG110Rilsan®ClearG170Rilsan®ClearG350Rilsan®ClearM-G830RnewEthanolIsopropanol☺☺☺☺=VerygoodresistancetoethanolRilsan®ClearG830RnewRilsan®ClearG350Rilsan®ClearG170Rilsan®ClearG11010ProductG830RnewG350CompetitionDensity1.020.991.00Biobasedcontent(%)5300Glasstransition(°C)135145155Transmittance(%)560nm-2mm91.591.591.5RefractiveIndex1.5121.5071.509TensileModulus(MPa)154014201600FlexuralModulus(MPa)149013601490Stressatyield(MPa)555155Strainatyield(%)786Stressatbreak(MPa)565662Strainatbreak(%)165175180Charpynotched23°C(kJ/m²)91011Charpynotched-30°C(kJ/m²)101112MainpropertiesofRilsan®ClearG830Rnew=G830RnewisthefirstAmPAbasedon50%biobasedrawmaterialsAppliedfor11Marketing/CommunicationMarketingsupport:Websitededicated::castorplant…NonediblecropsSeveralharvestsinayearNocompetitionwithfoodNonGMOGrownonpoorsoilinsemiaridareasAscomparedtocorn,soyUseveryfewwaterUseveryfewpesticideRobustcultureIncreasingdemandbutlesssensitivetospeculationBecauseit’saspecialtyoilNotascompetitiveasrapseedsorcornforbiofuels14RenewablesPolymersSynthesisamino11-monomer-Rilsan®B-polyamide11-MONOMERSYNTHESISPOLYMERIZATIONChina,India&BrazilMarseille(France)Serquigny(France)Birdsboro(USA)castorseedscastorplantsHARVESTINGGRINDINGcastoroilPebax®Rnew-elastomer-PTMG-softblock-fossilresourcesPlatamid®Rnew-copolyamides-monomerrenewableresourcesglycerinesterolAesterol11heptylalcoholheptaldehydeheptanoicacidRilsan®FinePowders-coatingpowders-Polyamide11-hardblock-15Rilsan®BTheonlyHighPerformancepolymer100%basedonrenewableresourcesWeatherresistanceLonglifetimeunderUVexposition.ProcessabilityGoodMeltFluidity,highspeedofrecrystallisation.Lightness20%lighterthanPC,15%lighterthanPA6,PA66.ChemicalresistanceMuchbetterthanotherpolyamides.ToughnessDownto–60°C.BiomassBased(issuedbyJORA)16Pebax®RnewFirstengineeringthermoplasticElastomerrangemadefromRenewableresourcesElasticityBestflexfatigueresistance&highestenergyreturn.Weather