《》20103920Material&HeatTreatment,,,、[1-2]。,。、,,[3],。,,,。,,,,、、、、(、、),。11.1,。,,,,,,、。,:Al2O3;。,。,。,,[4](TEM),,60nm,20nm。,6,,。1.2,。,,。,1,1,2,3(1.,123000;2.,116024;3.,116024):,。:;;;:TG178:A:1001-3814(2010)20-0123-05ProgressStateofSurfaceModificationTechnologyforAlAlloyCHUXin1,RENXin1,HAOShengzhi2,XUYang3(1.CollegeofMaterialScienceandEngineering,LiaoningTechnicalUniversity,Fuxin123000,China;2.LaboratoryofMaterialsModificationbyLaser,IonandElectronBeams,DalianUniversityofTechnology,Dalian116024,China;3.CollegeofMaterialScienceandEngineering,DalianUniversityofTechnology,Dalian116024,China)Abstract:Theresearchandapplicationofsurfacemodificationtechnologiesforaluminumalloyinrecentyearsweresummarized.Thefeaturesofsurfacemodificationtechnologyandprospectofhighcurrentpulsedelectronbeamcombinedtreatmenttechnologywerediscussed.Keywords:aluminumalloy;surfacemodification;highcurrentpulsedelectronbeam;surfacecombinedtreatment:2010-09-09:(1985-),,,,;:18904084727;E-mail:chuxin406@163.com123HotWorkingTechnology2010,Vol.39,No.20Material&HeatTreatment201010,。。3:①,。②,,,。③,。,[6]。,:,,,,,、。1.3Ni-P、、、,[7-8]。,,。,,。、、,,、。[9-11]。,:→→→→→→→→→→→→→→→→→。[12]Ni-W-P,WNi-W-P。:Ni-W-P400℃1h,1080HV25,10。,,,,、。,,、,。1.4,,[13-16]。,,,。[17]6061,,,。w(NaCl)=5%、,。,6061、、、;,,。1.5、,。(、PVD、CVD、-、),,,[18-20]。,。。Fe、Ni、Cr、BSi,。Fe、NiAl,、。、,,。[21]Ni-CrZL108,CO2。,。、、X。:Ni-Al,、Al-Si;230HV,3;2。124《》20103920Material&HeatTreatmentJin[22]Al60050~80μmCr,,,。,(、),、。,[23],,,,(≥5×104kW/cm2),。:Cu、NiTiCWCCuNi[24-25]。[26]CO238CrMoAlNiCrBSi+WC(25%),,、、。Cr1.8W3.2B3、Cr23C6、Ni3BWC1-x、。γ-Ni、,,。,。1.6,、。,,,。(),、。2070,“”,,,。,,,,、、,,,、、,。、、,,。,。、[27]。,。Al、Ti、Mg、Zr、TaNb(ValveMetal),,,、,。200μm,3000HV,、。、、,、,,、、。,、、、、。[28],Zr(OH)4。、XRD、EPMA。,t-ZrO2、m-ZrO2、α-Al2O3γ-Al2O3,t-ZrO2,,α-Al2O3。,1~2μm。,Zr(OH)4,。,、“、”“”,,。,1980、、“125HotWorkingTechnology2010,Vol.39,No.20Material&HeatTreatment201010”,,、、、、、、、,、,:①+();②+()++(),[29]。2,,。,,,,、;,,、;,,,、、,。,,[30]。(1),(),,,,。,,。(2)、,。90%,。(3),、,。,、、,。(4)、。。(5),,。(6),、、。,、。,。,,“”(μmmm),“”,,,,、,。,,[31]。,、,(),。,-,,。,,[32]316L。,316L。,。5MnS。20,1/15,。Rotshtein[33],,。Ivanova[34]WC-TiC-Co,,WC,。126《》20103920Material&HeatTreatment。6063,,+。,:15~30keV;1~6J/cm2;1~10kA;1~6ms;0.10.2Hz,10-3Pa。,,Ni-P,,,。,。3,,。,,。:[1]KcongKG,ShaW.Crystallizationandphasetransformationbehaviorofelectrolessnickel-phosphorusdepositsandtheirengineeringproperties[J].SurfaceEngineering,2002,18(5):329-343.[2].[J].,1995,14(2):22-24.[3].[M].:,2004.2-8.[4],,.[J].,2001,35(3):394-396.[5].[J].,1977,34(1):14-15.[6],,.[J].,2005,12(19):60-63.[7],,.Ni-P[J].,2006,25(8):41-43.[8].ZL101Ni-P[J].,2008,37(8):66-69.[9].Ni-P[J].,2001,(1):40-44.[10].Ni-P[J].,2002,(3):31-32.[11].[J].,2003,(5):46-49.[12],,.Ni-W-P[J].,2007,17(5):737-742.[13]FrankJ,Hermanek.Thermalspraying:whatitwasandwhatithasbecome[J].Int.J.PowderMetall,2002,38(7):36-39.[14]KnightR.Thermalspray:thesecondcentury-throughthelookingglass[J].Int.J.PowderMetall,2002,38(7):32-35.[15]RobertC,TuckerJ.Thermalspraycoatings:broadandgrowingapplications[J].Int.J.PowderMetall,2002,38(7):45-48.[16]ZakharovSV,SerenkoAN,RoyanovVA.BondingBstrengthCofthermallysprayedcoatings[J].WeldingInternational,2002,16(8):654-657.[17],,.[J].,2008,29(6):109-112.[18],.[J].,2001,34(3):20-22.[19].[J].,2000,33(1):9-11.[20].[J].,2002,35(2):9-11.[21],,,.[J].,2004,28(6):565-568.[22]JinKS,JeongHS,JoungS,etal.Effectoflasersurfacemodificationonthecorrosionresistanceofalloy600[J].SurfaceandCoatingsTechnology,1998,107:94-100.[23]YangJ,GongSK.Textureandsurfacemorphologyofyttria-stabilizedzirconiabufferlayeronNi-basedtapesbyelectronbeamevaporation[J].Phys.,2003,386:337-341.[24]ErdalCelik.Sol-gelprocessingofbufferlayersonNitapesForYBCOSurfaceCoatedconductors[J].IEEETran.Appl.Supercond.,2000,10(1):1162-1165.[25]OkuyucuH,CelikE.TexturedbufferlayersforYBCOcoatedconductorsbycontinuoussol-gelprocessing[J].IEEETran.Appl.Supercond.,2002,11(1):2889-2892.[26],,,.Ni60+WC[J].,2001,(5):26-31.[27]YoshitakaNakamura.YBCOthinfilmsonTiO2bufferlayerdepositionbyRFmagnetronsputtering[J].IEEETran.Appl.Supercond.,2005,15(2):3028-3030.[28],.[J].,2009,24(1):107-110.[29],,.[J].,2005,25(5):4-5.[30].[M].:,1992.11.[31]ProskurovskyDI.Useoflow-energy,high-currentelectronbeamsforsurfacetreatmentofmaterials[J].SurfaceandCoatingTechnology,1997,96:117-122.[32],.316L[J].,2007,43(1):71-76.[33]RotshteinVP,ProskurovskyDI,OzurGE,etal.Surfacemodificationandalloyingofmetallicmaterialswithlow-energyhigh-currentelectronbeams[J].SurfaceandCoatingsTechnology,2004,180-181:377-381.[34]IvanovaYF,RotshteinaVP.Pulsedelectron-beamtreatmentofWC-TiC-Cohard-alloycuttingtools:wearresistanceandmicrostructuralevolution[J].SurfaceandCoatingsTechnology,2000,125:251-256.127