常用基团

aelectron-pairacceptorsite电子对-接受体位置Acacetyl(e.g.AcOH=aceticacid)乙酰基（如AcOH乙酸）Acacacetylacetonate乙酰丙酮酸酯Addnaddition加入AIBNα,α’-azobisisobutyroniytileα,α’-偶氮双异丁腈Amamyl=pentyl戊基anhanhydrous无水的aqaqueous水性的/含水的Araryl,heteroaryl芳基，杂芳基azdistazeotropicdistilation共沸精馏9-BBN9-borobicyclo[3.3.1]nonane9-硼双环[3.3.1]壬烷BINAP(R)-(+)-2,2’-bis(diphenylphosphino)(R)-(+)2,2’-二(二苯基膦)-1,1’-二萘-1,1’-binaphthylBoct-butoxycarbonyl叔丁基羰基Bubutyl丁基t-But-butyl叔丁基t-BuOOHtert-butylhudroperoxide叔丁基过氧醇n-BuOTSn-butyltosylate对甲苯磺酸正丁酯Bzbenzoyl苯甲酰基Bzlbenzyl苄基Bz2O2dibenzoylperoxide过氧化苯甲酰CANceriumammonirmnitrate硝酸铈铵Catcatalyst催化剂CbCbzbenzoxycarbonyl苄氧羰基CCcolumnchromatography柱色谱（法）CDIN,N’-carbonyldiimidazoleN,N’-碳酰(羰基)二咪唑Cetcetyl=hexadecyl十六烷基Chcyclohexyl环己烷基CHPCAcyclohexaneperoxycarboxylicacid环己基过氧酸concconcentrated浓的Cpcyclopentyl,cyclopentadienyl环戊基，环戊二烯基CTEABcetyltriethylammoniumbromide溴代十六烷基三乙基铵CTEABcetyltrimethylammoniumbuomide溴代十六烷基三甲基铵dextrorotatory右旋的electron-pairdonorsite电子队-供体位置reflux,hea回流/加热DABCO1,4-diazabicyclo[2.2.2]octane1,4-二氮杂二环[2.2.2]辛烷DBN1,5-diazabicyclo[4.3.0]non-5-ene1,5-二氮杂二环[4.3.0]壬烯-5DBPOdibenzoylperoxide过氧化二苯甲酰DBU1,5-dizzabicyclo[5.4.0]undecen-5-ene1,5-二氮杂二环[5.4.0]十一烯-5o-DCBorthodichlorobenzene邻二氯苯DCCdicyclohexylcarbodiimide二环己基碳二亚胺DCE1,2-dichloroethane1,2-二氯乙烷DCU1,3-dicyclohexylurea1,3-二环己基脲DDQ2,3-dichloro-5,6-dicyano-1,4-benzoquinone2,3-二氯-5,6-二氰基对苯醌DEADdiethylazodicarboxylate偶氮二羧酸乙酯Decdecyl癸基，十碳烷基DEGdiethyleneglycol=3-oxapentane-1,5-diol二甘醇DEPCdiethylphosphorylcyanide氰代磷酸二乙酯derivderivative衍生物DETdiethyltartrate酒石酸二乙酯DHP3,4-dihydro-2H-pyran3，4-二氢-2H-吡喃DHQdihydroquinine二氢奎宁DIBAH,DIBALdiisobutylaluminum氢化二异丁基氯hydride=hdrobis-(2-methylpropyl)aluminumdiglymeditthyleneglycoldimethylether二干醇二甲醚dildilute稀释的dilndilution稀释Dioxdioxane二恶烷/二氧六烷DIPTdiisopropyltartrate酒石酸二异丙酯DISIABdisiamylborane=di-sec=isoamylborane二仲异戊基硼烷Distdistillation蒸馏dlracemic(rac.)mixtureofdextro-and外消旋混合物leborotatoryformDMAN,N-dimethylacetamideN,N’-二甲基乙酰胺DMAP4-dimethylaminopyridineoxide4-二甲氨基吡啶DMAPO4-dimethylaminopyridineoxide4-二甲氨基吡啶氧化物DME1,2-dimethoxyethane=glyme甘醇二甲醚DMFN,N-dimethylformamideN-N-二甲基甲酰胺DMSOdimethylsulfoxide二甲亚砜DmsoanionofDMSO,”dimsyl”anion二甲亚砜的碳负离子Doddodecyl十二烷基DPPAdiphenylphosphorylazide叠氮化磷酸二苯酯DTEABdecyltriethylammoniumbromide溴代癸基三乙基胺EDAethylenediamine1，2-乙二胺EDTAethylenediamine-N,N,N’,N’-tetraacetate乙二胺四乙酸e.e(ee)enantiomericexcess:0%ee=racemization,对映体过量100%ee=stereospecificreactionEGethyleneglycol=1,2-ethanediol1，2-亚乙基乙醇E,Ielectrocheminduced电化学诱导的Etethyl(e.g.EtOH,EtOAc)乙基Fmoc9-fluorenylmethoxycarbonyl9-芴甲氧羰基Gas,ggaseous气体的，气相GCgaschromatography气相色谱（法）Glyglycine甘氨酸Glyme1,2-dimethoxyethane(=DME)甘醇二甲醚hhour小时Halhalo,halide卤素，卤化物Hepheptyl庚基Hexhexyl己基HCAhexachloroacetone六氯丙酮HMDShexamethyldisilazane=bis(trimethylsilyl)amine双（三甲基硅基）HMPA,HMPTAN,N,N’,N’,N”,N”-hexamethylphosphoramide六甲基磷酰胺=hezamethylphosphotriamide=tris(dimethylamino)phosphinoxidehνirradation照光（紫外光）HOMOhighestoccupiedmolecularorbital最高己占分子轨道HPLChigh-pressureliquidchromatography高效液相色谱HTEABhexyltriethylammoniumbromide溴代己基三乙基铵Huningbase1-(dimethylamino)naphthalene1-二甲氨基萘i-iso-(e.g.i-Bu=isobutyl)异-（如i-Bu=异丁基inhinhibitor抑制剂IPCisopinocamphenyl异莰烯基IRinfra-red(absorption)spectra红外（吸收）光谱Lligand配（位）体Lleborotatory左旋的LAHlithiumaluminumhydride氢化铝锂LDAlithiumdiisopropylamide二异丙基酰胺锂Leuleucine亮氨酸LHMDSLihexamethyldisilazide六甲基二硅烷重氮锂Liq,lliquid液体，液相Lnlanthanide稀土金属LTAleadtetraacetate四乙酸铅LTEABlautyltrethylammoniumbromide溴代十二烷基三乙基铵（dodecyltriethylammoniumbronmide）LUMOlowestunoccupiedmolecularorbital最低空分子轨道Mmetal金属Transitionmetalcomplex过渡金属配位化合物MBKmethylisobutylketone甲基异丁基酮MCPBAm-chloroperoxybenzoicacid间氯过氧苯甲酸Memethyl(e.g.MeOH,MeCN)甲基MEMmethoxyethoxymethyl甲氧乙氧甲基Mes,Msmesyl=methanesulfonyl甲磺酰基minminute分molmole摩尔（量）MOMmethoxymethyl甲氧甲基MSmassspectra质谱MWmicrowave微波n-normal正-NBAN-bromo-acetamideN-溴乙酰胺NBPN-bromo-phthalimideN-溴酞酰亚胺NBSN-bromo-succinimieeN-溴丁二酰亚胺NCSN-chloro-succinimideN-氯丁二酰亚胺NISN-iodo-succininideN-碘丁二酰亚胺NMON-methylmorpholineN-oxideN-甲基吗啉-N-氧化物NMRnuclearmagneticresonancespectra核磁共振光谱Nonnonyl壬基Nunucleophile亲核试剂Octoctyl辛基o.p.opticalpurity:0%o.p.=racemata,100%o.p.=pureenantiomer光学纯度OTEABoctyltriethylammoniumbromide溴代辛基三乙基胺ppressure压力PCCpyridiniumchlorochromate氯铬酸吡啶嗡盐PDCpyridiniumfluorochromate重铬酸吡啶嗡盐PEpetrolther=lightpetroleum石油醚PFCpyridiniumfluorochromate氟铬酸吡啶嗡盐Penpentyl戊基Phphenyl(e.g.PhH=benzene,PhOH=phenol)苯基（PhH=苯,PhOH=苯酚）Phthphthaloyl=1,2-phenylenedicarbonyl邻苯二甲酰基Pin3-pinanyl3-蒎烷基polympolymeric聚合的PPApolyphosphoricacid聚磷酸PPEpolyphosphoricester多聚磷酸酯PPSEpolyphosphoricacidtrimethylsilylester多聚磷酸三甲硅酯PPTSpyridiniump-toluenesulfonate对甲苯磺酸吡啶盐Prpropyl丙基Protprotectinggroup保护基Prpyridine吡啶Ralkyl,etc烷基等racracemic外消旋的r.t.roomtemperature=20~25oC室温=20~25oCs-sec-仲satdsaturated饱和的ssecond秒senssensitizer敏化剂,增感剂sepnseparation分离siasec-isoamyl=1,2-dimethylpropyl仲异戊基solsolid固体solnsolutin溶液t-tert-叔-Tthymine胸腺嘧啶TBAtribenzylammonium三苄基胺TBABtetrabutylammoniumbromide溴代四丁基铵TBAHStetrabutylammoniumhydrogensulfate四丁基硫酸氢铵TBAItetrabutylammoniumiodide碘代四丁基铵TBACtetrabutylammoniumchloride氯代四丁基铵TBATFAtetrabutylammoniumtrifluoroacetate四丁胺三氟醋酸