高考化学新热点_等电子微粒

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,,.,,.,101418..1011(1)10Ne,1510.10::Na+Mg2+Al3+NH+4H3O+;:N3-O2-F-OH-NH-2;:NeHFH2ONH3CH4.(2)10:OH-+H3O+2H2ONH-2+NH+42NH3OH-+NH+4NH3+H2ONH-2+H3O+H2O+NH3NH3+H3O+H2O+NH+4NH3+HFNH+4+F-F-+H3O+HF+H2OMg2++2OH-Mg(OH)2Al3++3OH-Al(OH)3Al3++4OH-AlO-2+2H2O211(199727)abcdefg,10,1.1abcdefg01+1-02+1+0be;d;cfg.:(1)a.(2)be().(3)d.(4)g.(5)c;f().54():10:10O2-F-Na+Mg2+Al3+10HFOH-10H2ONH-210NH3H3O+10CH4NH+4aNe,bNa+,cOH-,eMg2+.d,dNH3.c(OH-)fg,10,fH3O+,gH2O..:(1)(2)NaOHMg(OH)2;(3)NH3+H2ONH3H2ONH+4+OH-;(4);(5)OH-,H3O+.1811(1)1810,18::K+Ca2+;:P3+S2-O2-2HS-Cl-:ArHClH2SPH3SiH4;1019,9118.HFH2ONH3CH41FOHNH2CH3,,F2H2O2N2H4CH3CH3CH3FCH3OHCH3NH218.(2)18:2HCl+S2-H2S+2Cl-(2H++S2-H2SHCl+HS-H2S+Cl-(H++HS-H2S);H2S+F2S+2HFH2S+H2O2S+2H2OCH3OH+HClCH3Cl+H2O2.2(200429)ABCDE,18,AC,BDE,ABCD;E.:(1)5:A,B,C,D,E.(2)AB.:18::ArHClH2SPH3SiH4F2H2O2:S2-HS-Cl-K+Ca2+,A+BC+D,AC,BD,18,2HCl+S2-H2S+2Cl-,AS2-;BHCl;CCl-;DH2S.E18,EF2H2O2.:(1)AS2-;BHCl;CCl-;DH2S;EF2H2O2(2)S2-+2H+H2S141.14Si;Si14,147N,14N2;N,14CO;CO64()Li2OC2-2.14::C2-2;:Si;:Li2OCON2.213(200527),.,.(1),;(2),;(3),O2;(4),;(5).:C2-2N2COSi,..,;;.,,:C2-2O2-2,CaC2Na2O2,CaC2,C2-2,14.14,Si,N2,CO.:(1)CaC2+2H2OCa(OH)2+2C2H2(2)3CO+Fe2O32Fe+3CO2CO+CuOCu+CO2(3)N2+O22NO;(4)Si,(5).1.(),.CH4NH+4CO2-3NO-3CO2N2ONO-2N2COCN-C2H6N2H2+6C2O2-4N2O4.(),.2.4(2004,22)1919,Langmuir:,..(1),2,;;.(2),.,,,,.,NO-2:.:,..(1),2;;;.2CNOF,N2O2F274()CONO,CO2N2ONO2,,,N2CO,CO2N2O.(2)NO-2:3;318.CN,O,FSPCl,O3CO2N2ONO2SO2CS2ClO2,O3SO2.(235121)ABCD::(1),ABC.D,C.()D,B.(2).D,ABCD.D,ABCD.():,,ADBC,ACB.,.:::NaMgAlFeCu,CSiNPOSClBr,.(1)NaMgCu.(2)Al,Al3+Al(OH)3[Al(OH)4]-.AAl3+AlCl3DNaOH,BCAl(OH)3Na[Al(OH)4];A[Al(OH)4]-Na[Al(OH)4],DHCl,BCAl(OH)3AlCl3.(3)Fe,FeFe2+Fe3+.DFe,ACl2(HNO3),BFeCl3[Fe(NO3)3],CFeCl2[Fe(NO3)2];AFe3+FeCl3,DZn,BCFeCl2Fe.(4),A,DO2,BCCOCO2.,CO2.:ANaOH,DCO2,BCNa2CO384()

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