2硫氰基甲基硫代苯并噻唑在工业水处理中的应用文明通

2-文明通1,邵丽文2,陈伟国2(1.广东工业大学,广东广州,510090;2.广东省石油化工研究院,广东广州　510665)　　[]2-(TCMTB),。　　[]2-;;　　[]TU991.2;TQ085+.412　[]A　[]1005-829X(2001)07-0008-04Theapplicationof2-(thiocyanomethylthio)benzothiazoletoindustrialwatertreatmentWENMing-tong1,SHAOLi-wen2,CHENWei-guo2(1.GuangdongUniversityofTechnology,Guangzhou,510090,China;2.GuangdongPetro-chemicalIndustryResearchInstitute,Guangzhou510665,China)Abstract:Theapplicationof2-(thiocyanomethylthio)benzothiazoletoindustrialwatertreatmentasbiocidesisintroduced.Somesuggestionsofitsdevelopmentarealsomade.Keywords:2-(thiocyanomethylthio)benzothiazole;biocides;synergisticeffect　　。,,,;,,,;,pH,。,。　　(GB50050-1995):5×105mL-1;4mL/m3。,,。　　2-(TCMTB)(),(LD501590mg/kg)〔1〕,,、,。、、、、、、、、。,TCMTB,BuckmanTCMTB,:MECT、MECT-WB、MECT-5、TCMTB-1030、TCMTB-5,Nalco、Betz、。TCMTB。2-,。1　TCMTB1.1　TCMTB与戊二醛复配　　NalcoChemicalCo.〔2〕,m(TCMTB)/m()()19∶1～1∶9,1～100mg/L,4h、24h,(Pseudomonasaeruginosa)(MIC)1。　　:TCMTB。4h,TCMTB,;24h,m(TCMTB)/m()19∶1～1∶9,。1.2　TCMTB与双-(三氯甲基)砜复配　　NalcoChemicalCo.TCMTB-(—8—2001年7月第21卷第7期　　　　　　　　　　IndustrialWaterTreatment　　　　　　　　　　　Jul.,2001Vol.21No.7表1　对细菌最低抑制浓度和协同作用试验结果MIC/mg·L-1SI4hTCMTB80Glut2019∶1901.299∶1801.204∶1501.001∶1200.631∶4200.851∶9100.4624hTCMTB70Glut2019∶1400.649∶1400.714∶1400.851∶1200.641∶4200.851∶9200.92:SI;m(TCMTB)/m(glut)。),、、,(Aspergillusniger)、(Saccharomycescerevisiae)(Pseudomonasaeruginosa)。m(TCMTB)/m(-())90/10～10/90,pH2.5～9.5〔3〕。　　TCMTB-(),2。　　;(Aspergillusniger)、(Saccharomycetes);14d(30℃)。表2　杀菌剂对酵母、霉菌的协同作用试验结果m(TCMTB)/m()SI()SI()90/100.906()0.906()10/900.51()0.38()50/500.53()0.33()75/250.765()0.465()25/750.491()0.325()　　TCMTB-()3。表3　杀菌剂对细菌的协同作用结果m(TCMTB)/m()SI90/100.50()75/250.50()50/500.50()25/750.75()10/900.50()　　TryptoneGlucoseExtractAgar(TGE);;14d(30℃)。　　2、3:TCMTB-()。1.3　TCMTB与异噻唑啉酮复配　　LaMarreTCMTB,5%～95%()(5--2--4--3-75%2--4--3-25%)95%～5%2-,1～10mg/L、、〔4〕。4。　　:TryptoneGlucoseExtractAgar;Pseudomonasaeruginosa;48h(37℃)。表4　杀菌剂对细菌的协同作用试验结果m(TCMTB)/m()()SI90/100.7831()10/900.4581()75/250.6041()25/750.3941()50/500.5751()1.4　TCMTB与2,2-二溴-3-氮川丙酰胺(DBNPA)复配　　BuckmamLaboratories,Inc,TCMTB2,2--3-,、、,、、。():10%～30%TCMTB,90%～70%2,2--3-〔5〕。　　(1)5。表5　对球毛壳霉的最低抑制浓度和协同指数m(TCMTB)/m(DBNPA)()MIC/mg·L-1SI100/02—90/1020.9170/3020.7230/7020.3410/9040.310/10032—　　(2)—9—2001-07,21(7)　　　　　　　　　　2-硫氰基甲基硫代苯并噻唑在工业水处理中的应用6。表6　对大肠杆菌的最低抑制浓度和协同指数m(TCMTB)/m(DBNPA)()MIC/mg·L-1SI100/030—30/701.00.8510/901.00.950/1001.0—　　(3)7。表7　对色球藻的最低抑制浓度和协同指数m(TCMTB)/m(DBNPA)()MIC/mg·L-1SI100/02—30/701.00.8510/901.00.950/1001.0—1.5　TCMTB与2-羟乙基-2,3二溴丙酸(HEDBP)或2-羟乙基-2-溴丙烯酸盐(HEBA)的复配　　BuckmanLaboratories,Inc.,、,、、。():15%～85%2-,85%～15%2--2,32--2-,0.1～100mg/L〔6〕。　　(1)8。表8　对黑曲霉的抑制浓度和协同指数m(TCMTB)/m(HEDBP)()MIC/mg·L-1SI100/012—87/1350.4980/2070.7573/2750.5767/3350.620/1005—　　(2)9。表9　对大肠杆菌的抑制浓度和协同指数m(TCMTB)/m(HEDBP)()MIC/mg·L-1SI100/015—80/20150.8567/33150.760/10015—　　(3)10。　　(4):5TCMTB25HEDBP,4.5～7.5mg/L,。　　,TCMTB表10　对藻类的抑制浓度/mg·L-1HEDBPHEDBP/TCMTB(80/20)HEDBP/TCMTB(67/33)TCMTBChlorellaPyrenoidosa()0.5444414440240404000080000ChlorocoocumHypnosporum()0.5444014430240004300080000Phormidiuminundatum()0.5444414444242324100080000:4-、3-、2-、1-、0-。,:　　(1)TCMTB+2,4,6-(BuckmanLaboratoriesInternational)〔7〕。　　(2)TCMTB+3--2--N-(3-iodo-2-propynyl-N-butylcarbamate)(BuckmanLaboratoriesInternational)〔8〕。　　(3)TCMTB+(methylene-bisthiocyanate)(KatayamaChemical,Inc.)〔9,10〕。　　(4)TCMTB+(polyetherphosphonates)(CalgonCorporation)〔11〕。　　(5)TCMTB+(BuckmanLaboratoriesInternational)〔12〕。　　(6)TCMTB+(quaternaryphosphonium)(AlbrightandWilsonLtd.)〔13〕。　　(7)TCMTB+(tetrakishydroxymethylphosphoniumsulfate,THPS)(HakutoChemicalCo.,Ltd.)〔14〕。　　(8)TCMTB+(diiodomethylp-toyl-sulfone)(BetzLaboratories,Inc.)〔15〕。—10—专论与综述　　　　　　　　　　　　　　　　　　　　　　　　　　　2001-07,21(7)　　(9)TCMTB+-1,3,5-(2-)-s-(hexahydro-1,3,5-tri(2-hydroethyl)-s-triazine)(BuckmanLaboratoriesInternational,Inc.)〔16〕。　　(10)TCMTB+5--3,4--1,2-(5-oxo-3,4-dichloro-1,2-dithiolane)〔17〕。　　(11)TCMTB+4,4,-(4,4-dimethyloxazolidine)3,4,4-(3,4,4-dimethyloxazolidine)(BuckmanLaboratoriesInternational,Inc.)〔18〕。　　(12)TCMTB+(tetramethylthiuramdisulfide)〔19〕。2　　　:TCMTB、,(Chaetomiumglobosum)(Chlorococcumhypnosporum),MIC2mg/L,,。,TCMTB。　　:1)、、;2)pH;3),,;4),;5)。,:　　(1)TCMTB,,。　　(2)TCMTB-1030,,,,。　　(3)TCMTB(MBT),。,,、、。[][1].()[M].1981:97.[2]NalcoChemicalCo.GlutaraldehydeplusTCMTBasabiocideforindustrialwaters[P].US5198453,1992.[3]NalcoChemicalCo.Synergisticfungicide/biocideofTCMTBandbis(trichloromethyl)sulfone[P].US4479961,1984.[4]NalcoChemicalCo.SynergisticbiocideofTCMTBwithamixtureof5-chloro-2-methyl-4-isothiazolin-3-oneand2-methyl-4-isothiazolin-3-one[P].US4595691,1985.[5]BuckmanLaboratories,Inc.Slimecontrolcompositionsandmethodsofusingthesame[P].US4285765,1980.[6]BuckmanLaboratories,Inc.Slimecontrolcompositionsandmethodsofusingthesame[P].US4293559,1978.[7]BuckmanLaboratories,Inc.CombinationofTCMTBandatrihalogenatedphenol[P].US4983618,1989.[8]BuckmanLaboratories,Inc.Amicrobiocidepreservativecompositioncomprisingacarbamateandabenzothiazolederivative[P].EP266110,1988.[9]ItoYosuke,etal.Industrialantisepticmildew-proofinga