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42120151WorldRubberIndustry03010[1]1%20111[2]201512tX783.3B1671-8232(2015)01-0041-061991,,,266042Vol.42No.14146Jan.2015·42·20151[3]1.1[4]LavalULBLeedsKoberSteezENEA1.2290570[5]CBpCBpCBp22.12.1.1CBp67%28%5%CBpCBp3%0.8%CBpCBpCBp13%~16%0.5%·43·421,.2.1.2CBp35~150m2/g65~125cm3/100gCBp[6]2.1.3CBp90%CBpXXPS[7]XPSCOS2%CBpNZnCBpSiNZnZnOCBpSZnZnOSZnSZnSCBpZnSXPSCBpCIGC[7]RoyC[8]N330CBpIGCIGC1/3CBpIGCN7742.1.4CBp2.1.4.1CBpCBpN774[9]CBpCBpCataldoF[10]CBp81m2/gN339CBpN3399CBpCBpCBpCBpCBpCBp1CBp[11]CBpCBpCBpCBp[12]2CBp10%~20%-[13][14]ChaalaA[13]CBpCBp14.6%6.3%42m2/g53m2/gCBp1%65m2/g[15]3CBp[16-17]·44·2015CBpZhouJ[18]NDZ-105CBpCBpNRNRNRCBpZhouJ[18]CBpCBpCBp2.1.4.2CBp[19]CBpCBp1000m2/gMiguelGS[20]925800m2/gGuptaVK[21]2.1.4.3CBpCBpZhouJ[22]NDZ-311CBp2.1.4.4CBp90CBp[23]CBpBRABRACBp2.22.2.1950~970kg/m3321.3~1.51%~1.5%40~43MJ/kg[24][25]2.2.22.2.2.1[26]70%[27]70%21%72%2.2.2.219.297.2·45·42125.5%16.3%32%~37%[28]2.3C2C3C42.43ResearchProgressonthePyrolysisofScrapTireLiuYingjun,QiaoHuijun,DuAihua(CollegeofPolymerScienceandEngineering,QingdaoUniversityofScience&Technology,Qingdao266042,China)Abstract:Scraptire,consideredasblackpollutionafterwhitepollution,isamajorpollution.Manycountriesaroundtheworldaretryingtofindscientificwaystodealwithscraptireinrecentyears.Pyrolysisofscraptireshasbeenpaidmuchattention.Thispaperintroducedtheadvantagesofthepyrolysisofscraptire,thepyrolysistechnologyandprocesses,characterization,modificationandapplicationsofpyrolysisproducts,aswellasthepotentialdevelopmentofpyrolysistechnologyinthefuture.Keywords:ScrapTire;Pyrolysis;PyrolysisProducts;Modification[1].[J].2013608493-496.[2].[R].2011.[3].[J].2002219681-684.[4].[J].201461(5)316-319.[5]MikulovaZ,SedenkovaI,MatejovaL,etal.StudyofCarbonBlackObtainedbyPyrolysisofWasteScrapTyres[J].JournalofThermalAnalysisandCalorimetry,2013,111(2):1475-1481.,.·46·2015[6]HuangK,GaoQ,TangL,etal.AComparisonofSurfaceMorphologyandChemistryofPyrolyticCarbonBlackswithCommercialCarbonBlacks[J].PowderTechnology,2005,160(3):190-193.[7]DarmstadtH,CaoNZ,PanteaDM,etal.SurfaceActivityandChemistryofThermalCarbonBlacks[J].RubberChemistryandTechnology,2000,73(2):293-309.[8]RoyC,ChaalaA,DarmstadtH.TheVacuumPyrolysisofUsedTires:End-UsesforOilandCarbonBlackProducts[J].JournalofAnalyticalandAppliedPyrolysis,1999,51(1):201-221.[9]DuA,ZhangZ,WuM.TheEffectofPyrolyticCarbonBlackPreparedfromJunkedTiresonthePropertiesofEthylene-Propylene-DieneCopolymers(EPDM)[J].ExpressPolymerLetters,2009,3(5):295-301.[10]CataldoF.PreparationofPyrolyticCarbonBlackfromScrapTireRubberCrumbandEvaluationinNewRubberCompounds[J].MacromolecularMaterialsandEngineering,2005,290(5):463-467.[11]NorrisCJ,HaleM,BennettM.PyrolyticCarbon:FactorsControllingin-RubberPerformance[J].Plastics,RubberandComposites,2014,43(1):32-38.[12].NR[J].200451(2)78-82.[13]ChaalaA,DarmstadtH,RoyC.Acid-BaseMethodfortheDemineralizationofPyrolyticCarbonBlack[J].FuelProcessingTechnology,1996,46(1):1-15.[14]MahramanliogluM.AdsorptionofUraniumonAdsorbentsProducedfromUsedTires[J].JournalofRadioanalyticalandNuclearChemistry,2003,256(1):99-105.[15]ChungSH,NaJG.MethodforUpgrade-ProcessingCarbonBlackProducedbyPerformingaPyrolysisProcessonWasteTires:US,8722008[P].2014-5-13.[16].[J].200556(4)720-726.[17]BorahD,SatokawaS,KatoS,etal.CharacterizationofChemicallyModifiedCarbonBlackforSorptionApplication[J].AppliedSurfaceScience,2008,254(10):3049-3056.[18]ZhouJ,YuT,WuS,etal.InverseGasChromatographyInvestigationofRubberReinforcementbyModifiedPyrolyticCarbonBlackfromScrapTires[J].Industrial&EngineeringChemistryResearch,2010,49(4):1691-1696.[19]AriyadejwanichPTanthapanichakoonWNakagawaKetal.PreparationandCharacterizationofMesoporousActivatedCarbonfromWasteTires[J].Carbon,2003(41):157164.[20]MiguelGS,FowlerGD,DallOM,etal.PorosityandSurfaceCharacteristicsofActivatedCarbonsProducedfromWasteTyreRubber[J].ChemicalTechnologyandBiotechnology,2001(77):1-8.[21]GuptaVK.PotentialofActivatedCarbonfromWasteRubberTirefortheAdsorptionofPhenolics:EffectofPre-TreatmentConditions[J].ColloidInterfaceScience,2014(417):420-430.[22]ZhouJ,WangJD,RenXH,etal.SurfaceModificationofPyrolyticCarbonBlackfromWasteTiresandItsUseasPigmentforOffsetPrintingInk[J].ChineseJournalofChemical,2006,14(5):654-659.[23].BRA[J].,2013(10)175-176.[24],.[J].,200331(6)589-594.[25],.[J].,2009(4)59-63.[26]ZabaniotouA,StavropoulosG.PyrolysisofUsedAutomobileTiresandResidualCharUtilization[J].JournalofAnalyticalandAppliedPyrolysis,2003,70(2):711-722.[27]MuruganS,RamaswamyM,NagarajanG.AssessmentofPyrolysisOilasanEnergySourceforDieselEngines[J].FuelProcessingTechnology,2009,90(1):67-74.[28]StanciulescuM,IkuraM.LimoneneEthersfromTirePyrolysisOil(Part2):ContinuousFlowExperiments[J].JournalofAnalyticalandAppliedPyrolysis,2007,78(1):76-84.[]2014-11-11,.