A2SBR工艺反硝化除磷系统的快速启动与稳定运行

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40220122CHEMICALENGINEERINGCHINAVol.40No.2Feb.20122011-05-23-200905991971-E-mailzhanglanhe@163.com。A2SBR121111.1320122.150090A2SBR。COD200mg/L4—11mg/L25mg/L55mg/L“2.5h-1h-3.5h-1h”31dA2SBRCOD、77%90%84.96%。92%91%COD80%0。X703.1A1005-9954201202-0012-05Quickstart-upandsteadyoperationofdenitrifyingdephosphorizationprocessbyusinganaerobic/anoxicsequencingbatchreactorZHANGLan-he12LIUQiang1JIAYan-ping1LIJun11.SchoolofChemicalEngineeringNortheastDianliUniversityJilin132012JilinProvinceChina2.NationalEngineeringResearchCenterofUrbanWaterResourcesHarbin150090HeilongjiangProvinceChinaAbstractInordertoachievethesimultaneousdenitrificationanddephosphorizationfromwastewateralong-termlabexperimentwascarriedoutbyusingananaerobic/anoxicsequencingbatchreactorA2SBRtoinvestigatethestart-upandoperationperformanceofdenitrifyingdephosphorizationprocess.TheresultshowsthatundertheconditionsofinfluentCODmassconcentration200mg/LPO3-4—Pmassconcentration4-11mg/LandNO-3—Nmassconcentrationinanoxicphasefrom25mg/Lto55mg/LA2SBRprocesscanbesuccessfullystartedupwithin31dbyusingaperiodicaloperationmodeofanaerobicoperation2.5h-sludgesedimentationandwaterdischarge1h-anoxicoperation3.5h-sludgesedimentationandwaterdischarge1h.TheremovalefficiencyofCODNO-3—NandPO3-4—Pinanaerobicphaseare77%90%and84.96%respectively.WhentheA2SBRwasoperatedsteadilytheremovalefficiencyofNO-3—NandPO3-4—Pare92%and91%respectivelyandthatofCODishigherthan80%withtheeffluentmassconcentrationofPO3-4—Pnearlyzero.Thewholesystemshowsagoodperformanceofdenitrificationanddephosphorizationafterasteadyoperation.Keywordsdenitrifyingphosphorusremovalbacteriaquickstart-updenitrifyingdephosphorizationPAO1。PAO2-9。DPBPHA。DPB。。。。Lee10/TOC、92%88%100%DPBPAO64%。HwanAhn11A2-MLSS。NO-3MLSSNO-2MLSS。、12A2SBR、250∶60∶8、。13NO-2NO-2—N35±5mg/L、pH8.0±0.1pH7.2±0.1COD400mg/L。14ρNO-3—N/ρCOD0.04ρNO-3—N/ρCOD0.095。。A2SBR-COD、A2SBR。11.11。2.5L1.7L。SBR38h15①2.5h②40min10min10min③3.5h④10min⑤30min10min10min。。。38h4①2.5h②3.5h55mg/L③10min④90min10min10min。1-2-3-4-pH5-DO6-ORP7-8-9-10-11-12-1A2SBRFig.1SchematicdiagramofA2SBRsystem。2.5g/L。20—30℃pH6.8—820d。1.2、ρCOD200mg/LρPO3-4—P4—6mg/LNO-3—NρNO-3—N25—55mg/LNH4Cl0.02g/LMgSO4·7H2O0.6g/LCaCl2·2H2O0.07g/LEDTA0.01g/L。L2mLFeCl3·6H2O1.5g/LH3BO30.15g/LCuSO4·5H2O0.03g/LKI0.03g/LMnCl2·4H2O0.12g/LCoCl2·6H2O0.15g/LZnSO4·7H2O0.12g/L。1.3ρCODρPO3-4—PρNO-3—NMLSSpHpHs-2CpH。22.1A2SBR2A2SBR。13.32mg/L4.35mg/L·31·A2SBRDPB。PAODPB。PAOPAO。。1010.89mg/L2020.17mg/L。3134.53mg/L0.89mg/L84.96%NO-3—N。2Fig.2VariationlawofreleaseanduptakeofPO3-4—P2.2A2SBRCODDPBPHB。PHBDPB。3COD。CODρCOD=200mg/LρCOD=178mg/L24%。CODρCOD=46mg/L77%。4。13.32mg/L。。3135.42mg/L。34COD。COD。CODDPBCOD。2.3A2SBRDPBPHB。5ρNO-3—N25mg/L166.32%NO-3—N。588.84%ρNO-3—N=2.79mg/LNO-3—N6ρNO-3—N35mg/LρNO-3—N=9.53mg/L77.7%。ρNO-3—N55mg/L90%。·41·20124025Fig.5VariationlawofNO-3—Ninanoxicphase2.4A2SBR6。31A/OA2SBRDPB23DPB。6A2SBRρPO3-4—PFig.6VariationofPO3-4—Pmassconcentrationatdifferentoperationtimeduringstart-upofA2SBR3—6、2。126466686。8h。1DPBCODPHB。1Table1Statisticsofabnormalcyclesduringexperimentaloperationmg/LρPO3-4—P2563.245.442610.42.634.62275.126.458.97285.637.9610.03294.5312.1714.19455.2410.0413.61469.923.556.42475.6515.7319.75484.2112.4814.52495.0915.3818.79655.4220.4224.426610.245.637.32676.0626.7331.22855.7428.2132.828610.318.3910.34875.9225.4230.151294727.96mg/L12.17mg/L3.55mg/L15.73mg/L。。Loosdrecht15。47872。。31dA2SBR5.03mg/L94.29%COD80.52%。2.5A2SBRA2SBR32“2.5h-3.5h-10min-110min”。720dρPO3-4—P、ρNO-3—NρCOD。ρCOD0.5h200mg/L105.7mg/LρPO3-4—P4.67mg/L20.5mg/LDPBCODPHB。ρCOD·51·A2SBRρPO3-4—P48.74mg/L37.56mg/L。1hρNO-3—NρPO3-4—P55mg/L37.56mg/L20.87mg/L16.57mg/L。CODNO-3—NPO3-4—P80.17%92%91%。10minρCODρNO-3—NρPO3-4—P100%。7A2SBRρCODρPO3-4—PρNO-3—NFig.7VariationofCODPO3-4—PandNO-3—Nmassconcentrationsatdifferenttimeafterstart-upofA2SBR31ρCOD200mg/LρPO3-4—P4—11mg/LρNO-3—N25mg/L55mg/L“---”31dA2SBRNO-3—N5.03mg/L94%。2A2SBRρCOD200mg/LρNO-3—N55mg/L2.5h3.5h92%91%COD80%ρPO3-4—P0。3。1WENTZELMCEKAMAGALOEWENTHALREetal.Enhancedpolyphosphateorganismsculturesinactivatedsludgesystems.PartⅡExperimentalbehaviourJ.WaterSA198915271-81.2AKINBSUGURLUA.TheeffectofananoxiczoneonbiologicalphosphorusremovalbyasequentioalbatchreactorJ.BioresourceTechnology20049411-7.3PENGYongzhenWANGXiaolianLIBaikun.AnoxicbiologicalphosphorusuptakeandtheeffectofexcessiveaerationonbiologicalphosphorusremovalintheA2OprocessJ.Desalination20061891/2/3155-164.4PATELJNAKHLAG.InteractionofdenitrificationandPremovalinanoxicPremovalsystemsJ.Desaliena-tion20062011/2/382-99.5CARVALHOGLEMOSPCOEHMENAetal.Deni-trifyingphosphorusremovallinkingtheprocessperform-ancewiththemicrobialcommunitystructureJ.WaterResearch200741191-14.6ZOUHuaDUGuochengRUANWenquanetal.RoleofnitrateinbiologicalphosphorusremovalinasequencingbatchreactorJ.WorldJournalofMicrobiologyandBio-technology2006227701-701.7TSUNEDASatoshiOHNOTakashiSOEJIMAKoichi.Simultaneousnitrogenandphosphorusremovalusingdeni-trifyingphosphate-accumulatingorganismsinasequen-cingbatchreactorJ.BiochemicalEngineeringJournal2006273191-196.8WANGYayiPANmianliYANMin.Characteristicsofanoxicpho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