AAAMPSHPA极限黏度的影响因素及其与性能的关系冯婕

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SyntheticinfluentialfactorsontheutmostviscosityofAA/AMPS/HPAandtherelationshipbetweentheutmostviscosityofthecopolymeranditscapacitiesFengJie,LiHesheng,WangDong(ResearchInstituteofBeijingYanshanPetrochemicalCo.,Ltd.,SINOPEC,Beijing102500,China)AA/AMPS/HPA,,(,102500)[]、2--2-,AA/AMPS/HPA,、、,。[];;[]TQ085+.412[]A[]1005-829X(2010)05-0046-03Abstract:CopolymerAA/AMPS/HPAhasbeensynthesizedbyusingAA,AMPSandHPAasrawmaterials.Thefactors,suchasdosageofinitiator,molecularweightregulator,reactiontemperatureandreactiontime,whichhaveeffectsontheutmostviscosityofpolymersarestudied.Andthescaleinhibitingcapacityandoxidationresistanceofthepolymerhavingdifferentutmostviscositiesareevaluated.Keywords:sulfonicacidcopolymers;utmostviscosity;recirculatingcoolingwaterCa3(PO4)2。Ca、Ba、Mg,Ca3(PO4)2,,,,〔1-3〕。2--2-(AMPS),,,,〔4〕。AA/AMPS/HPA,。11.1:DF-101S,722N,ZK-,,,,,,。:(HPA)、AMPS(),(AA)、()、()。1.2AA/AMPS/HPA、、,;,AA、AMPSHPA,,;,AA/AMPS/HPA。22.1GB/T16632—1996CaCO3。〔5〕402403,Ca3(PO4)2。30520105IndustrialWaterTreatmentVol.30No.5May,201046——2010-05,30(5)2.21、0.25g/L,20d,。33.13.1.1AA/AMPS/HPA、,14%,,AA/AMPS/HPA,,。,,。,,,,,,。3.1.2AA/AMPS/HPA、,AA/AMPS/HPA。,,,AA/AMPS/HPA。50~60℃,AA/AMPS/HPA;60℃,。,,,,;,,,。,,70~80℃。3.1.3AA/AMPS/HPA、,,AA/AMPS/HPA,1。1,,,3h。3.2AA/AMPS/HPA3.2.1AA/AMPS/HPAAA/AMPS/HPA,CaCO3、Ca3(PO4)2。8mg/L,2。2:AA/AMPS/HPACa3(PO4)2,Ca3(PO4)2,95%,100%;,,,,0.08dL/g,70%;CaCO3,50%,CaCO3。3.2.2AA/AMPS/HPA,,。8mg/L,Ca3(PO4)2,3。,:AA/AMPS/HPA47——2010-05,30(5)10cm,Na2SO41g/L,0.6m3/h,500g,pH3,15V,Fe2+1mmol/L,90min,91.2%。(2),,,,,。[][1],,.[J].,2006,20(3):61-62.[2],,,.[J].,2004,24(10):56-59.[3],,,.[J].,2001,23(2):125-128.[4]ZhouDing,CaiWeimin,WangQunhui.Astudyontheuseofbipolar-particles-electrodesindecolorizationofdyeingeffluentsanditsprinciple[J].WaterSci.Tech.,1986,19(3/4):391-400.[5],,,.[J].,2005,31(l):59-61.[6],,,.[J].,2004,5(6):43-47.[7],,.COD[J].,2001():6-9.[8],,,.[J].,2003,24(2):27-30.[9],,.[J].,1995,21(6):359-362.[10]MoyersB,WuJS.Removaloforganicprecursorsbyperman-ganateoxidationandalumcoagulation[J].WaterResearch,1985,19(3):309-314.[11]SantosVL,LinardiVR.Biodegradationofphenolbyafilamen-tousfungiisolatedfromindustrialeffluents-identificationanddegradationpotential[J].ProcessBiochemistry,2004,39(8):1001-1006.[12]LiXiaoyan,CuiYuhong,FengYujie,etal.Reactionpathwaysandmechanismsoftheelectrochemicaldegradationofphenolondiffer-entelectrodes[J].WaterResearch,2005,39(10):1972-1981.[13].[M].4.:,2002:460-462.[14],,.-Fenton[J].:,2008,35(6):84-89.(29)!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!![](1966—),1989,,。:0415-6225092,E-mail:ddxiayi@163.com。[]2009-11-19()3,Ca3(PO4)2,95%;,0.08dL/g,,0.09dL/g。4(1)。,,;,;,。(2)AA/AMPS/HPACa3(PO4)2,;0.08dL/g,70%。(3)AA/AMPS/HPACa3(PO4)2,,,0.09dL/g。[][1].AMPS[J].,2005,34(1):21-23.[2].AMPS[J].,2000,3(1):38-40.[3],,,.AMPS[J].,2000,1(12):12-15.[4].[J].,2000,20():5-8.[5].[M].:,1990:375-382.[](1980—),2006,。:010-80344845,E-mail:fengj1@126.com。[]2009-12-12()48——

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