AMBBRSMBBR与AO工艺处理石油发酵工业废水的对比研究于玲红

373Mar．201720173ModernChemicalIndustryAMBBＲ/SMBBＲA/O111212*131．0140102．1000853．272000AMBBＲ/SMBBＲA/OA/OCOD、NH3－N、TP96.4%、78.79%、96.8%AMBBＲ/SMBBＲCOD、NH3－N、TP98.1%、96.3%、95.9%NH3－N1.44mg/LAA/O。AMBBＲ/SMBBＲ1.5～2.0、NH3－N3～5A。AMBBＲ/SMBBＲA/O。AMBBＲ/SMBBＲA/OX703A0253－4320201703－0179－04DOI10．16606/j．cnki．issn0253－4320．2017．03．043AcomparativestudyontreatmentofpetroleumfermentationindustrialwastewaterbyAMBBＲ/SMBBＲandA/OprocessYULing-hong1SUIXiu-bin1YANGWen-huan1ZHANGJing-zhao2ZHUHao-jun12*LIWei-ping1ZHANGＲui31．InnerMongoliaUniversityofScienceandTechnologyBaotou014010China2．Sino-DanskeCloningBeijingBiologicalTechnologyCo．Ltd．Beijing100085China3．TheCathayIndustrialBiotechJining272000ChinaAbstractAcombinedpilot-scaleAMBBＲ/SMBBＲprocessistoimprovethetreatmenteffectofpetroleumfermentationindustrialwastewaterwithhighsaltcontent．TheeffluentqualityiscomparedwiththattreatedbytheconventionalA/Oprocess．TheresultsshowthattheaverageremovalrateofCODNH3-NandTPintheeffluenttreatedbyA/Oprocessis96.4%78.79%96.8%respectively．BycontrasttheaverageremovalrateofCODNH3-NandTPintheeffluenttreatedbyAMBBＲ/SMBBＲprocessis98.1%96.3%and95.9%respectively．InparticulartheaverageconcentrationofNH3-Nintheeffluentis1.44mg/Lmeetingnationaldischargestandard．AMBBＲ/SMBBＲissuperiortoA/OprocessontheremovalofNH3-N．AMBBＲ/SMBBＲalsoshowshighresistancetoimpactloadingcapacityundertheconditionofincreasingtheinletflowrateby1.5－2.0timesandincreasingtheconcentrationofNH3-Nby3－5times．Theammoniaconcentrationintheeffluentcouldreachfirstgradenationalstandard．TheAMBBＲ/SMBBＲprocessfacilitatestheupgradingandreconstructiononthebasisofA/Oprocessoftheoriginalfactory．KeywordsAMBBＲ/SMBBＲA/Opetroleumfermentationindustri[e-mail][e-mail]。、、。。《》2017A。TNCOD、TP1－2。A/O《》CJ343—2010《》。A/O、、·971·373、、3－5。MBBＲMBBＲ、6－8。AMBBＲ/SMBBＲA/OSDC－019、、SDC－01。AMBBＲ/SMBBＲA/O。11.1、、、、。4+、SMBBＲ、158、448、184L1。AMBBＲ3、、SMBBＲ。SDC－01、、、。1AMBBＲ/SMBBＲAMBBＲ/SMBBＲ10、11MBBＲA/O。AMBBＲ－HＲT=1.0dSMBBＲ－HＲT=5.2d100%～200%20～30℃AMBBＲDO0.4～0.6mg/LSMBBＲDO2～5mg/L3000～3500mg/L。A/O。AA－HＲT=1.0dOO－HＲT=3.0dOO－HＲT=2.4d、10000～12000mg/L4000～5000mg/L6.25h。AMBBＲ/SMBBＲ。A/O2。2A/O1.2、、、、、。、、、。1mg/LCODNH3－NTPpH4500～1000015～8045～3004000～160004.5～6.1《》CODNH3－NTP·081·20173AMBBＲ/SMBBＲA/O。pHPHS－3EDOAZ－8403OLYMPUSCX21。2。AMBBＲ/SMBBＲ、。、SAMBBＲ/SMBBＲ、AA/O。2。2AMBBＲ/SMBBＲA/Omg/LCODTP6236.439.5125.2A/SMBBＲ121.31.45.7A/O222.68.583.92544d。2.1COD3COD5000～8000mg/LA/OCOD85～399mg/L222.6mg/L93.8%～98.8%96.4%。AMBBＲ/SMBBＲ0～24dCOD86～187mg/L121.30mg/L96.5%～98.9%98.1%AMBBＲ/SMBBＲCODA/O。A/OCODAMBBＲ/SMBBＲ1—2—S3—A4—S5—NSAMBBBＲ/SMBBＲAA/O3CODA/O1/412－13。AMBBＲSMBBＲ、、AMBBＲ、。2.2439.34mg/L。A/O78.79%A/O。AMBBＲ/SMBBＲ0～24dAMBBＲ/SMBBＲSMBBＲ。252.42mg/L97.4%0.5～2.0mm。SMBBＲ3000～3500mg/L。AMBBＲ/SMBBＲ1.44mg/L95.5%。AMBBＲ/SMBBＲA/OA。1—2—S3—A4—S5—N4NH3－N2.350～200mg/L。A/OTP96.8%5A/O·181·373A/O。AMBBＲ/SMBBＲTP87.5%A/MBBＲ。95.9%、、、14PH315。。A/MBBＲA/O。1—2—S3—A4—S5—N52.4AMBBＲ/SMBBＲ2.4.16DN53～5160.0mg/L245mg/L150mg/L2.25mg/L1.45mg/L99.08%。。SMBBＲ、、2。1—S2—S3—S62.4.21.5～2.015d3AMBBＲ/SMBBＲ。3COD/mg·L－15738.4039.56115.80/mg·L－1125.801.593.46/%97.8096.0097.0031AMBBＲ/SMBBＲCOD121.30mg/L1.44mg/L5.7mg/LA/O、。1。2AMBBＲ/SMBBＲAMBBＲ/SMBBＲ、。A/O16。3AMBBＲ/SMBBＲA/O。1．J．2011204475－481．184·281·373、、、。。。1/140℃0.089g/L。－252.77℃H2－259.2℃。。。H2CH4、CO2、N2H2S。、PSA3。1.1。。－252.75℃、、－161.5、－60.4、－195.8、－78.5℃。。1.2。。。、、、。。。1.3pressingswingadsorptionPSA。。。。PSA。2PSA、、、6。櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆櫆1822．J．201233180－84．3Diya'uddeenBHDaudWMAWAzizAＲA．Treatmenttechnol-ogiesforpetroleumrefineryeffluentsAreviewJ．ProcessSafetyandEnvironmentalProtection201189295－105．4．A/OJ．2008241999－101．5．/AMBBＲ/A/OJ．20104122776－2780．6．MBBＲJ．20102621152－156．7．A/OJ．201535180－86．8．/MBBＲJ．20112731－4．9．CN201330132291．6P．2013－12－04．10．A/O－J．20126103481－3484．11．MBBＲA/OJ．2012352178－181．12McQuarrieJamesPBoltzJoshuaP．MovingbedbiofilmreactortechnologyprocessapplicationsdesignandperformanceJ．WaterEnvironmentＲesearch2011836560－575．13．MBBＲJ．201127390－93．14．J．20126124553－4558．15．、J．2008438－42．16．J．201026119－12．■·481·