CANON体系中颗粒污泥粒径及CN比对反应器脱氮性能的影响李津青

356201811JournalofUniversityofChineseAcademyofSciencesVol．35NovemberNo．62018*2016ZX05066006-001[e-mail]2095-6134201806-0845-06CANONC/N*12221111014082100022201710302018110LiJQHanXYHuangJetal．EffectsofparticlesizesandC/NratiosonthenitrogenremovalperformanceinCANONsystemJ．JournalofUniversityofChineseAcademyofSciences2018356845-850．SBＲＲ10.2～0.5mm、Ｒ20.5～1mm、Ｒ3＞1mmC/N。Ｒ1、Ｒ2、Ｒ3AOBNOBＲ2Ｒ1Ｒ3Ｒ2Ｒ1Ｒ3。C/N0.59kg/m3·d0.34kg/m3·d94.75%95.07%87.55%。CANONC/N1.5。C/NX703Adoi10.7523/j．issn．2095-6134.2018.06.017EffectsofparticlesizesandC/NratiosonthenitrogenremovalperformanceinCANONsystemLIJinqing1HANXiaoyu2HUANGJing2ZHANGShujun2LIUHonghui1LIUXinchun11CollegeofＲesourcesandEnvironmentUniversityofChineseAcademyofSciencesBeijing101408China2ＲesearchandDevelopmentCenterofBeijingDrainageGroupCorporationBeijing100022ChinaAbstractHighammonianitrogenwastewaterwastreatedinanintegratedanaerobicammoniaoxidationSBＲreactor．EffectsofparticlesizesＲ10.2-0.5mmＲ20.5-1mmＲ3＞1mmandC/Nratiosonthenitrogenremovalfromgranularsludgewerestudied．TheresultsshowedthattheAOBactivitiesofＲ1Ｒ2andＲ3decreasedinturnＲ2hadthehighestNOBactivityfollowedbyＲ1andＲ3hadthelowestandＲ2hadthehighestactivityofANAMMOXfollowedbyＲ1andＲ3hadthelowest．WhentheC/Nratioincreasedthegranularsludgemorphologychangedobviouslyandmicroscopicexaminationshowedthatthemiddleredpartgraduallyreducedandperipheral35yellowencirclementoccurred．Thetotalnitrogenremovalloadreducedfrom0.59kg/m3·dto0.34kg/m3·dandthetotalnitrogenremovalrateincreasedfrom94.75%to95.07%andthendecreasedto87.55%．TheresultsshowedthattheC/Nratioshouldnotexceed1.5inCANONprocess．KeywordsanaerobicammoniaoxidationgranulesizesgranulesC/NratioanaerobicammoniumoxidationAnammox2080NO2－—NNH4+—N11.320.26。1、、2DokHavenANAMMOX3.5a3。StrassDEMON0.5a4。0.5～1a5。6。completelyautotrophicnitrogenremovalovernitriteCANON。SBＲ3Ｒ1∶0.2～0.5mm、Ｒ2∶0.5～1mm、Ｒ3＞1mmC/NCOD/TNCANON。11.1SBＲ1300mm1400mm100L90L。0.1mm10mm、、+、、5。1/330±1℃。1SBＲFig．1SchematicoftheSBＲreactor1.2NH4+—N=400～500mg/LNO2－—N=0～10mg/LNO3－—N=0～10mg/LCODpH7.43～8.26。＜0.2mm46%258μm。1.3－N－1－CODpH、OＲPWTWC400DOPAＲTECHSOUＲStrathkelvin6486CANONC/N3～430℃。CKSOUＲCKAOBSOUＲAOBNH4+—N100mg/LNOBSOUＲNOBNO2－—N30mg/L。SOUＲ3。1、0.5、0.2mmGB6003.1—2012Ｒ1∶0.2～0.5mmＲ2∶0.5～1mmＲ3＞1mm。mastersizer2000。OLYMPUS-BX51。22.1。0～15d20min16～25d10min26～43d5min44～230d7min。2。2Ｒ135.0%Ｒ214.7%Ｒ33.7%。Ⅰ0～42dＲ135%～60%。Ⅱ43～107dＲ2Ｒ3Ｒ230%～40%Ｒ35%13%7。Ⅲ108～230dＲ3Ｒ1Ｒ2。、。Philips8DO3.3mg/L30μmDO0mg/L。Ｒathnayake9DO2mg/L300μmDO0mg/L100.5～1mm0.2～0.5mm＞1mm。2Fig．2Variationinparticlesizeproportion1130%。3。Ⅰ0～42d46%9%3800mg/L1100mg/LⅡ43～107d1100mg/L1700mg/L15%Ⅲ108～230d1700mg/L5700mg/L12%26%8%。Ⅱ、Ⅲ30%0.48kg/m3·d。Hubaux12。13DODO1.2mg/L。DO0.55～2.37mg/LDO。2.2AOB、NOB、ANAMMOX0.5～1mm＞1mm748353Fig．3VariationsinsludgeconcentrationandparticleproportionＲ1、Ｒ2、Ｒ3AOB、NOBANAMMOXAOB、NOBStrathkelvin。ANAMMOX1L3DO0.1mg/L30±0.4℃pH8.0±0.150mg/LANAMMOX。1Ｒ1、Ｒ2、Ｒ3AOB17.36、14.71、9.63mgO2/gVSS·hNOB8.55、9.05、5.30mgO2/gVSS·hＲ1AOBＲ2Ｒ3ZhangL14AOBAOBAOBNOBＲ1Ｒ2Ｒ3NOBNO2－—N。vanderStar15NOBNO2－—N12～955mmol/LNO2－—N0.2～3mmol/LNO2－—N。16DONOBNO2－—NNOB。1718。AOBAOBNOBANAMMOXNOBDODOANAMMOXＲ23.30mgN/gMLSS·hＲ30.34mgN/gMLSS·hＲ10.99mgN/gMLSS·h6＞2.5mm、1.5～2.5mm、0.5～1.5mm。1mm19Ｒ1、Ｒ2Ｒ3。PCＲＲ1、Ｒ2、Ｒ3copies/gMLSS1.20E+082.91E+09、1.16E+072.27E+08、1.01E+072.79E+08Ｒ1、Ｒ2、Ｒ34.13%、5.12%3.63%Ｒ1、Ｒ2Ｒ3。1mgO2/gVSS·hANAMMOXmgN/gMLSS·hTable1ＲesultsofSOUＲmgO2/gVSS·htestandANAMMOXactivitymgN/gMLSS·h/mmSOUＲCKSOUＲAOBSOUＲNOBANAMMOXＲ1∶0.2～0.52.19±0.3117.36±1.768.55±0.780.99±0.12Ｒ2∶0.5～12.05±0.2814.71±1.529.05±0.803.30±0.42Ｒ3＞11.67±0.199.63±1.135.30±0.540.34±0.062.3C/NⅢC/NC/NCANON。4Ⅰ0～42d51.29mg/L8486CANONC/N1.12mg/L14.44mg/L30.12mg/L0.53kg/m3·d80.75%Ⅱ43～107d99.91mg/L4.62mg/L57.49mg/L26.81mg/L0.46kg/m3·d80.80%Ⅲ108～230d48.95mg/L2.66mg/L3.11mg/L。ⅢC/N=1、1.5、2、312.62、14.08、27.4147.38mg/LC/N=1、1.5、2、30.59kg/m3·d94.75%、0.53kg/m3·d95.07%、0.45kg/m3·d88.68%、0.34kg/m3·d87.55%Du20C/N=1C/N。Ni21C/N3。C/N=2C/N=11.5ⅠⅡ22。CANONC/N1.5。4Fig．4VariationsofinletandoutletTNNH4+—NNO3－—NandNO2－—NC/N5C/N=1C/N=1.5C/N=2C/N=3。C/N。。5C/N40XFig．5GranulogramsindifferentC/NconditionsMagnification40X31SBＲ107d。2AOBNOB0.5～1mm0.2～0.5mm＞1mm。3CANONC/N1.5C/N。1MulderAvandeGraafAAＲobertsonLAetal．AnaerobicammoniumoxidationdiscoveredinadenitrifyingfluidizedbedreactorJ．FEMSMicrobiologyEcology1995163177-184．2StrousMHeijnenJJKuenenJGetal．Thesequencingbatchreactorasapowerfultoolforthestudyofslowlygrowinganaerobicammonium-oxidizingmicroorganismsJ．AppliedMicrobiology＆Biotechnology1998505589-596．3WrVDSAbmaWＲBlommersDetal．Startupofreactorsforanoxicammoniumoxidationexperiencesfromthefirstfull-scaleanammoxreactorinＲotterdamJ．Water94835Ｒesearch200741184149-4163．4WettB．DevelopmentandimplementationofarobustdeammonificationprocessJ．WaterScience＆TechnologyAJournaloftheInternationalAssociationonWaterPollutionＲesearch200756781．5．D．2013．6．J．201434123078-3085．7．J．201431167-73．8PhilipsSLaanbroekHJVerstraeteW．OrigincausesandeffectsofincreasednitriteconcentrationsinaquaticenvironmentsJ．ＲeviewsinEnvironmentalScience＆Biotechnology200212115-141．9Ｒa