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112Vol．11No．220172ChineseJournalofEnvironmentalEngineeringFeb．20172015－09－142016－02－231982—。E-mailduanxiumei1@sinochem．com*EGSB-BF-*110021EGSB-BF-。EGSBHＲT36hpH6.8～7.535±1℃BFHＲT48hDO2～4mg·L－1150%80～100mg·L－1COD、NH+4-N、TP、SS90%～99.4%、91%～100%、93%～98.5%、92%96%。、、。X505A1673-9108201702-0879-06DOI10.12030/j．cjee．201509075NaturallatexwastewatertreatmentwithEGSB-shakingbedbiofilm-coagula-tionprocessDUANXiumei*ANPengMAWenjingZHANGJunZHANGKaiyangSUNLanmeiTechnicalDevelopmentDepartmentShenyangＲesreachInstituteofChemicalIndustryShenyang110021ChinaAbstractToreusenaturalrubberlatexproductionprocessingwastewateranEGSB-BFbiofilm-coagulationprocesswasusedasanadvancedtreatmentstepandtheoperationstabilityandtreatmentabilityoftheprocesswereanalyzed．TheHＲToftheEGSBwas36hthepHwas6.8～7.5andthetemperaturewas35±1℃．FurthermoretheHＲToftheBFbiofilmwas48htheDOconcentrationwas2～4mg·L－1andthenitrifyingliquidrefluxratiowas150%．Coagulationsedimentationwasusedfortheadvancedprocessingofthebiochemicaltailwaterwith80～100mg·L－1ironsulfateusedasthecoagulant．FinallytheremovalratesofCODNH+4-NTPchromaticityandSSwere90%～99.4%91%～100%93%～98.5%92%and96%respective-lyandtheeffluentsatisfiedtheemissionandrecyclingrequirementsfornaturalrubberlatexproductionprocess-ing．Theprocesshasnumerousadvantagessuchasashortstarttimeimpactresistancestableoperationofthedeepprocessingofnaturalrubberlatexprocessingwastewaterandtheproductionwatersatisfiedthewaterqualitystandardforrubberproductionreuse．KeywordsnaturalrubberproductionwaterreuseexpandedgranularsludgeblanketreactorEGSBshakingbedbiofilmcoagulation、、、1。、、COD。、、2。COD11expandedgranularsludgeblanketreactorEGSB3-4。、、5。。EGSB-BF-COD、、。11.1EGSB10%。EGSB、、、EGSB。。、、。。BiofringeBFNETD100mm×H150mm160。1。1EGSB-BF-Fig．1NaturalrubberwastewatertreatmentbytechnologicalprocessofEGSB-BFbiofilm-coagulation．1.2NY687-200361。1Table1InfluentqualityanddischargestandardpHCOD/mg·L－1BOD5/mg·L－1NH3-N/mg·L－1SS/mg·L－15～67500～80003700～4000325～350458～500NY687-20036～91003020701.3EGSB40%3hydraulicreten-tiontimeHＲT36hpH6.8～7.235±1℃。BF2d。pH6.8～7.5DO2～4mg·L－1HＲT48h10d。0882EGSB-BF-1.4161000mL800mL50r·min－110%、、、60～120mg·L－115min40minTP、pH。1.5DOLDOpH-SG2TSSCOD-、《》7。。22.1EGSBEGSBDO0.3mg·L－1。20g-MLSS·L－1EGSB、2。＜1000mg·L－142d5.6kgCOD·m3·d－1、。。8EGSB-A/O4EGSB20kgCOD·m3·d－1。95EGSBCOD94.4%BOD5/COD0.460.56。EGSB。10EGSB-CASS-8～10kgCOD·m3·d－11UASB-A/O5.8kgCOD·m3·d－1COD62%。EGSBUASB。EGSBUASB。EGSB。2EGSB/Fig．2Organicmatter/organicloadremovalratesofEGSBreactor2.2BF30℃1881130℃35±1℃HＲT48hDO2～4mg·L－1150%5000mgMLSS·L－1EGSBBFBFCOD3。3CODFig．3CODremovalofswim-bedbiofilm320dCOD500～1000mg·L－1630mg·L－1COD47mg·L－1COD91.1%0.31kgCOD·m3·d－121～35COD1000～1500mg·L－11121mg·L－1COD27～220mg·L－1146mg·L－1COD88%0.59kgCOD·m3·d－136～41COD1500～2000mg·L－11600mg·L－1COD76～255mg·L－1228mg·L－1COD85%0.89kgCOD·m3·d－10.95kgCOD·m3·d－1。COD。NY687-2003-4。43mg·L－1112mg·L－1010.1mg·L－143gN·m3·d－1。4Fig．4Ammonianitrogenremovalofswim-bedbiofilm11BFCOD96%80%。5BF-COD、TNNH+4-N93.6%、72.7%98.9%。2882EGSB-BF-。BF、。BFMLSS17425mg·L－1123～41.5kg·m3·d－1。0.186112～3。2.32.2mg·L－198%40pH7.0。、23。95%pH。2Table2ComparationofTPremovalaftercoagulation/mg·L－1TP/mg·L－1TP/%TP/mg·L－1TP/%TP/mg·L－1TP/%TP/mg·L－1TP/%601.150.61.055.41.435.60.865.3800.768.10.386.41.150.10.197.31000.481.80.195.50.769.90.0100.01200.290.90.0597.70.387.40.0100.0。2～380～100mg·L－1。3Table3Decolorizingabilityofdifferentcoagulants/mg·L－1/%/%/%/%603317.5283032203220802927.52050283028301002147.51270224520501201270490166010752Al3+、Fe3+、、、ξ、、、13。14、3pH7pH5。。15。pHpH。388113EGSB-BF-COD、NH+4-N、TP、SS90%～99.4%、91%～100%、93%～98.5%、92%96%。、。1．UASB-A/OJ．200929849-512．MEM-J．2013331252-553．EGSB-MBＲJ．20153551416-14224．EGSBJ．201535545-475．-J．2009371218-12226．NY687-2003S．20047．．4M．20028．EGSBJ．2011377130-1321369．EPSB-EGSB-PNHJ．2015314105-10710．EGSB-CASS-J．20125336-3811．J．201032267-6912．A/O-J．20126103481-348413．J．2015994360-436414．PTAJ．201427527-3115．D．2011488