FCC催化剂生产尾气洗涤废水的膜过滤试验唐彦强

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FCC112111.4300792.430072FCC、—200L/hPTFEFCC。1865h10NTU10000NTU。FCCX703C1000-4602201621-0104-04FieldStudyonTreatmentofFCCCatalystProductionWastewaterbyHollowFiberMembraneTANGYan-qiang1WANGHong-ping12MAXue-qing1XIAORui11.SchoolofResourcesandEnvironmentalScienceWuhanUniversityWuhan430079China2.HubeiProvincialCollaborativeInnovationCenterforWaterResourcesSecurityWuhan430072ChinaAbstractThewastewaterfromgaswashinginFCCcatalystproductionischaracterizedbystrongacidandhighconcentrationofsuspendedsolids.Afieldtestsystemwithwaterproductioncapacityof200L/hwasbuiltusingprecipitationandhollowfibermembranefiltration.PTFEhollowfibermembranewasusedtoremovesuspendedsolidsfromthewastewater.Thetreatmentefficiencyandthefluxchangewerestudied.Thesystemwasoperatedcontinuouslyfor1865hours.Theoperationresultsindicatedthattheturbidityofeffluentwaslessthan10NTUandthepermeatefluxwasstablewhenthewastewaterqualitywasnormal.Butthereweretwosignificantchangesinwastewaterqualityduringoperationandthepre-cipitationwasineffective.Theturbidityofincomingwaterformembranetankreached10000NTU.Thequalityofpermeatebecameworseandthepermeatefluxdecreaseddramaticallybecauseofmembranefouling.Thepermeatefluxcannotberecoveredfullybyaerationorbackwashingsoitisnecessarytocar-ryoutstudyonchemicalwashing.KeywordsFCCcatalystwastewaterfromgaswashinghollowfibermembraneFCC、1。2~4pH·401·3221201611CHINAWATER&WASTEWATERVol.32No.21Nov.2016。56FCC17。pH6~87pH。pH。、、、、89。FCC。/。11.1、、、1、A、B。1Fig.1SchematicdiagramofexperimentalsetupPTFE0.2~0.4μm0.8mm1.6mmpH1~14<0.05MPa25m2。1.21865hA、B———。5~50kPa200L/h。1.3、、、。、、HACH2100ANMicrotracS3500。22.12.1.1FCC35~55℃pH1~33000~10000NTU。200~300NTU2D10=2.72μmD50=8.53μmD90=43.29μm。2Fig.2Variationofeffluentturbidityfromsedimentationtankwithrunningtime150~270h1000~1150h。·501·.watergasheat.comFCC322110000NTU2。2.1.2A、B。10NTUA、B100200NTU3。3A、BFig.3Variationofeffluentturbidityfrommembranetankswithrunningtime2.25、1020kPa———4。4A、Fig.4VariationoftransmembranepressureandflowrateofmembranetankAwithrunningtimeS15kPa200L/h80L/h。200L/h10kPaS2、100L/hS1。200L/h20kPa200L/h。2.3。200L/h。DarcyJ=ΔPμR1J=QA2JΔPμRQA。R。RM、RCRPJ=ΔPμRM+RC+RP3k=QΔP=AμRM+RC+RP4RM、、910RC、1011、RP。A·601·3221.watergasheat.comμkRPRCk。5kS1kS2k。kk4。kS3k。5kFig.5Variationofkwithrunningtime3①—FCC——3000~10000NTU10NTU。②。。1.J.2015417136-139.2.J.2015439190-191.3.J.2010384308-310.4.J.2015341211-14.5./J.200723653-54.6.VJ.201336891-96.7.J.200334340-43.8Le-ClechPChenVFaneTAG.FoulinginmembranebioreactorsusedinwastewatertreatmentJ.JMembrSci20062841/217-53.9LeeEJKimKYLeeYSetal.Astudyonthehigh-fluxMBRsystemusingPTFEflatsheetmembraneswithchemicalbackwashingJ.Desalination2012306135-40.10BaiRLeowHF.Microfiltrationofactivatedsludgewastewater—theeffectofsystemoperationparametersJ.SepPurifTechnol2002292189-198.11PradhanMVigneswaranSAimRBetal.Modellingofparticledepositioninasubmergedmembranemicrofiltra-tionsystemJ.Desalination2014350414-20.1991-。E-mailtyq828@163.com2016-05-11·701·.watergasheat.comFCC3221

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