Fenton及类Fenton试剂的研究进展

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1FentonFenton(AOP)FentonFe2+H2O2•OH•OHFenton1894Fenton[1]Fe2+H2O2Fe2+H2O2FentonFentonFentonFentonH2O2•OHFentonFentonFenton[2,3]Fe2++H2O2Fe3++OH-+•OH(1)Fe2++•OHFe3++OH-(2)Fe3++H2O2Fe2++HO2•+H+(3)HO2•+H2O2O2+H2O+•OH(4)RH+•OHR•+H2O(5)R•+Fe3+R++Fe2+(6)R•+O2ROO+CO2+H2O(7)Fe2+H2O2•OHFe3+Fe3+H2O2Fe2+Fe2+H2O2•OHFe2+•OHRHR•R•CO2H2OCOD[4]FentonpHFe2+H2O2Fenton2Fenton2.1/Fenton(7)H2O2H2O2+hv2HO•(8)Fe2+Fe2+H2O2FentonpH=3Fe(OH)2+FentonFenton471023Fenton•OHFentonFentonFenton/Fenton/H2O2//Fenton/FentonFentonFenton:X703:A:1008-8814(2007)03-0001-04:2007-03-04:(1979-),,,,,.173Vol.17No.320076JournalofLuoyangTechnologyCollegeJune2007Fe(OH)2+Fe2++•OH(9)Fe2+H2O2Fe3+Fe(OH)2+Fe2+Fe(ROO)2+Fe2++CO2+•R(10)•RO2Fe2+Fenton[5][6]Fe2+H2O2Fe2+H2O2Fe2+H2O2(9)(10)[7]H2O2BFe2+/UVCu2+/UVFe2+Cu2+Mn2+/UVAg+/UVH2O2Fenton/Fenton2.2-/H2O2//FentonFe2+H2O2H2O2Fenton/FentonH2O2H2O2•OHH2O2H2O2+•OHHO2•+H2O(11)UV/Fenton[8][9]Fe3+C2O42-[Fe(C2O4)3]3-200nm500nm•OHFe(C2O4)33-Fe2++2C2O42-+C2O4-•(12)C2O4-•+Fe(C2O4)33-Fe2++3C2O42-+2CO2(13)C2O4-•CO2+CO2-(14)C2O4-•/CO2-•+O2O2-•+2CO2/CO2(15)2O2-•+2H+H2O2+O2(16)Fe2+H2O2FentonUV-vis/H2O2/[22][23][24]24-[13]C2O42-H2O2Fe3+Fe2+H2O2UV-vis/H2O2/Fenton•OHUV-vis/H2O2/[14]UV/H2O2FeSO4pH2.3/Fenton1mm~1m[15]Rudolph[16]25min71%98%LuigiC[17]40~120min80%~87%FentonJ.Sanz[18]FentonFenton[19][20]Fenton217FentonFenton2.4/Fenton20kHz[21][22]5000K5107Pa109K/s[23][24]H2O•OH+•H(17)•OH•OHH2O2(18)•H•HH2(19)H2O2•OH[25][26][27][28]pHFe()H2O2H2O2(PCBS)(PAH)(Fe()[29]UV[30]UV/H2O2/Fe()[31]UV/H2O2/O3[32])(17)(18)H2O2Fe()Fe()H2O2(1)•OHFentonNagata[33]2-3-4-Fe()BeckettHua205kHz14-Fe()4[34]Fe()[29]50kHzB(ARB)pHFe()ARBARBH2O2Fe()H2O2·OHARBFe()H2O2H2O2FentonFenton/FentonH2O2Fe()(17)•HH2O2•OHH2O(20)H2O2•OHH2O2•OHFenton[35]Fenton[36]FentonFeSO4H2O2pH15min3FentonFenton399.31%FentonFenton3FentonFentonFentonFentonFentonFentonFentonFenton(pH)FentonFentonFentonFentonFentonFenton:[1]FentonHJH.OxidationofTartaricAcidPresenceofIron[J].JChemSoc,1984,(65):899-905.[2]BossmannSH,OliverosE,GbSetal.NewevidenceagainsthydroxylradicalsasreactiveintermediateinthethermalandphotochemicallyenhancedFentonreaction[J].PhysChem.A,1998,102(28):5542-5550.[3]ChenR,PignatelloJJ.RoleofquinineintermediatesaselectronshuttleinFentonandPhotoassistedFentonoxidationsofaromaticcompounds[J].EnvironSciTechnol,1997,31(8):2399-2406.[4]GermanHRossetti,EnriqueDAlbizzati,OrlandoMAlfano.DecompositionofFormicAcidinaWaterSolutionEmployingthePhoto-FentonReaction[J].IndEngChemRes,2002,(41):1436-1444.[5],,.UV-Vis/H2O2/[J].,2003,21(1):72-78.[6],.-Fenton[J].,1994,13(4):302-306.[7],,.Fenton[J].,1999,20(3):72-74.[8]JamesAS,StepmenRB.Ferrioxalate-mediatedphoto-degradationoforganicpollutantsincontaminatedwater[J].WaterRCS,1997,31(4):787-798.[9]ZeppRG,FaustBC,HoigneJ.Hydroxylradicalformationinaqueousreaction(pH=3~8)ofiron()withhydrogenperoxide:ThePhoto-Fentonreaction[J].EnvironSciTechnol,1992,26(2):313-319.[10]LiTY,LiuQY.StudyonphotodegradationofchloroforminwaterbyUV/H2O2/ferrioxalatecomplexes[J].ChinaEnvironmentalScience,1999,19(6):526-529.[11]ZhangND,HuangJL,ZhengW.TheresearchonphotodegradationofanilinewastewaterbydynamicUV-vis/H2O2/ferrioxalatecomplexesprocess[J].JournalofChemicalIndustryandEngineering,2002,53(1):36-39.[12]ZhangND,HuangJL,ZhengW.Treatmentofphenols-containingwastewaterbyphoto-Fentonprocess[J].TechniquesandEquipmentforEnvironmentalPollutionControl,2002,3(2):20-22.[13]RaquelF,PupoN,GuimaraesJR.Photodegradationdichloroaceticacidand2,4-dichlorophenolbyferrioxalate/H2O2system[J].WaterRes,2000,34(3):859-901.[14],,.UV/[J].,2001,34(2):74-78.[15].[M].:,1999.[16]RudolphA,Abrarnovith,HuangBangZhou.DecompositionofPCBandotherpolychlorinaledaromaticsinsoilusingmicrowaveenergy[J].Chemosphere,1998,37(8):1427-1436.[17]LuigiCampenella,RaffoedlaCresti.Microwavesassistedphotodegradationofpollutants.In:SPIEconferenceonenvironmentalmonitoringandremediationtechnologies[J].BostonMssochasettsNovenbe,1998,(1):105-113.[18]SanzJ,LombranaJI,DeluisAM,etal.MicrowaveandFenton'sreagentoxidationofwastewater[J].EnvironChemLett,2003,(1):45-50.[19],.Fenton[J].,2003,19(1):85-90.[20],,.[J].,2003,23(8):36-38.[21].[M].:,1990.[22],,.[J].,2000,(7):1-3.[23],,.[J].,2003,4(4):66-69.417(58)[1].[D].:,2004.[2].[J].,2005,(3):6-10.[3].2005[J].,2005,(4):3-4.[4].:124[EB/OL].[5].2007[EB/OL].(LuoyangInstituteofScienceandTechnology,Luoyang471023,China)Abstract:Therearebothexternalandinternalfactorsforthefierceemploymentcompetitionfacedbycollegestudents,especiallythefemalestudents.Thisarticle,basedonaseriesofinvestigation,comestoaconclusionthatcollegefemalestudents'consciousnessofjob-takingplaysavitalroleintheirjob-searching.Keywords:CollegefemaleStudents;EmploymentConsciousness;Analysis4[24],.[J].,2003,20(2):86-89.[25]ChenYC,PanagiotisSmirniotis.Enhancementofphotocatalyticdegradationofphenolandchlorophenolsbyultrasound[J].IndEngChemRes,2002,(41):5958-5965.[26]DewulfJ,VanLangenhoveH,DeV

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