201511466Fuel&ChemicalProcessesHPF1211.7117122.401220HPF2。HPF。TQ522.61A1001-3709201506-0049-03ComparisonbetweenHPFdesulfurizationandvacuumpotassiumcarbonatedesulfurizationLuoWanjiang1SongYingfang2LiuXiaojing11.ShanjiaoChemicalCo.Ltd.ShaanxiCoalandChemicalIndustryGroupWeinan711712China2.CokingPlantofChongqingIron&SteelCo.Ltd.Chongqing401220ChinaAbstractThispaperintroducesHPFdesulfurizationandvacuumpotassiumcarbonatedesulfurizationandcomparestheadvantagesanddisadvantagesofthesetwoprocesses.AnalysisshowsthatHPFdesulfurizationhastheadvantagesoflowinvestmentsimpleoperationbutithasthedisadvantagesofhighoperationcostlowqualitysulfurproducedlargeamountofwastewatergeneratedandseriouspollutionproblemwhilevacuumpotassiumcarbonatedesulfurizationneedshigherinvestmentiscomplexinprocessbutitcostlessforoperationandtheproductsulfuricacidcanbedirectlyusedforammoniarecovery.KeywordsCokeovengasDesulfurizationprocessComparison2015-07-061984-HPF2。1HPF1.1HPFHPFPDSH2S1。1HPF2HPF140000m3/h170000m3/h94DOI:10.16044/j.cnki.rlyhg.2015.06.031Fuel&ChemicalProcessesNov.2015Vol.46No.6。H2S50mg/m3H2S。1.2H2SHCNH2SHCN12。2120000m3/hH2S200mg/m3H2S98%2。、。2HPFHPF2、、65000m3/h213。HPF4。。1HPFHPFPDS20t/a、920t/aV2O538m3、127t/a、KOH48%201t/a90%3250t/a98%8700t/a180m3/h、125m3/h、2m3/h、4.3t/h、7100m3/h、1256kWh410m3/h、285m3/h、9m3/h、1m3/h、2.5t/h、2m3/h、1217kWh5.8MPa4t/h95%~98%99%43001035037505022.4/a714/a78.02/1000m311.09/1000m332、HPF2。2012112014102。H2S200mg/m321.04/1000m3。H2S29.59/1000m339.45/1000m3。HPF。、05201511466Fuel&ChemicalProcesses。WSA。、。2、HPFHPFHPFWSA40000m3/h70000m3/h120000m3/hPDS2.7t/a、2.7t/aPDS5.4t/a、5.4t/a、2700t/aV2O54~5m3/a、32.5t/a、KOH48%605t/a90%1.6~2.5t/d90%3.6~4.2t/d98%35~40t/d145m3/h125m3/h、0.5m3/h、1.9t/h、2000m3/h、550kWh3m3/h、1.5t/h、4000m3/h、955kWh10.25m3/h、10t/h、100~150m3/h、905.85kWh5.8MPa4t/h。H2S33.02mg/m341.45mg/m3159.72mg/m320~30t/d150~170mg/L60~80t/d240~260mg/L7.2t/d80~100mg/L29.59/1000m339.45/1000m321.04/1000m341HPF、、。2HPFH2S。3、、、。1.J.200940357-58.2.WSAJ.201442146-49.3.HPFJ.200940456-57.4.HPFJ.201442254-56.櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘櫘48257/a。223/a22/t。50t/a140/a。1000t/a1000t/a340/a。412012。XS1.5%wt%BT。、98%。。2。、。15