O3氧化工艺处理黄连素制药废水研究秦伟伟

512Vol．5No．12201112ChineseJournalofEnvironmentalEngineeringDec．2011O3121*211331．1000122．2665103．110026O3CODpH、O3O3O3。O3COD700mg/L、COD3500mg/L、pH0．88O314.05mg/L·min180min2529mg/LCOD77．46%41．28%BOD5/CODB/C0．060.344．7COD。O3。O3X703A1673-9108201112-2717-05TreatmentofberberinepharmaceuticalwastewaterwithO3oxidationprocessQinWeiwei12SongYonghui1ChengJianguang2XiaoShuhu1ZengPing1GuoXiaochun3WangXin31．DepartmentofUrbanWaterEnvironmentalResearchChineseResearchAcademyofEnvironmentalSciencesBeijing100012China2．CollegeofChemicalandEnvironmentalEngineeringShandongUniversityofScienceandTechnologyQingdao266510China3．NortheastPharmaceuticalGroupsShenyang110026ChinaAbstractO3oxidationprocesswasusedtotreatberberinepharmaceuticalwastewaterwithhighlyconcentratedberberineandCOD．TheeffectsofinitialwastewaterpHO3dosageandinitialberberineconcentrationontheO3oxi-dationprocessefficiencieswereinvestigatedtodeterminetheoptimaloperationparameters．Itshowedthattheberber-ineinwastewatercouldbeeffectivelydecomposedbyO3anditsCODconcentrationwasreduced．Forthewastewaterwithberberineof700mg/LCODof3500mg/LandpHof0．88whentheozoneconcentrationwas14．05mg/L·minandthetreatmenttimewas180mintheozonedosagewas2529mg/LtheberberineandCODremovaleffi-cienciesreached77．46%and41．28%respectivelytheBOD5/CODratioB/Cratioincreasedfrom0．06to0．34．AstheinitialconcentrationofberberinewastewaterincreasedtheberberineandCODremovalefficienciesdecreasedgradually．ItwasverifiedthatO3oxidationprocesswasaneffectivepretreatmenttechnologythatcouldgreatlyimprovethebiodegradabilityofberberinepharmaceuticalwastewaterwithaB/Cratioincreaseby4．7times．KeywordsberberineO3advancedoxidationpretreatmentpharmaceuticalwastewater2008ZX07208-0032010－08－222010－11－301986～。[e-mail]*[e-mail]20H18NO411410。2。COD34。5。。GB21903-2008《51Fig．1Molecularstructureofberberine》——、、。O32。·OH·OH。O3、、6-15。O3、、、、、1617。O3pH、O3、。11．1、32。2.0L3S-A1010.0g/h180W。O3。1．2pH0.9700mg/LCOD3500mg/LBOD5200mg/LBOD5/COD0.06。。2Fig.2SchematicdiagramofexperimentalsetuppH0.1mol/LNaOHH2SO4。O320。O3D=ρ·t/VDO3mg/LρO3mg/L·mintminVL。UV-6100340nm340nm18。CODCR3200CODWTWGermanBOD519。3。22.1O3UV-vis3pH0.88O314.05mg/L·min60minO3200～500nm。4228、262、340422nm。4O3CO2。2．2O32．2．1pHpH0.88、3.0、5.0、7.0、9.011.014.05mg/L·minO3180minpH817212O33O3UV-visFig.3UV-visspectravariationofberberinewithtimeinO3oxidationprocessCOD45。4pHFig．4EffectofinitialpHonberberineremovalefficiency4pH。。pH70%。O3pHpH。O3。5pHCOD。pHCOD90min。CODpH0.8841.28%20%。pH＞5.0pHCODpHCODO3COD。pH＜5.0O3pH＞5.0pHO3O3·OH2021。5pHCODFig.5EffectofinitialpHonCODremovalefficiencypH3.5。O3pH。2．2．2O3pH0.88O314.05、11.26、6.91、3.92mg/L·min180minO3COD67。67O3COD。O314.05mg/L·min180minO32529.00mg/LCOD41.28%77.46%。O3。O3。2．2．3pH0.8814.05mg/L·minO3180min100、500700mg/LCOD89。8。100mg/L90.11%700mg/L9172577.46%。。。8Fig．8Effectofinitialconcentrationonberberineremovalefficiency9COD。100mg/L180minCOD61.24%700mg/L180minCOD41.28%。O3。9CODFig．9EffectofinitialconcentrationonCODremovalefficiency2．3BOD5B/CpH0.88O3BOD5B/C10。O314.05mg/L·min180minBOD5221mg/L737mg/LB/C0.060.344.7。O3。10BOD5BOD5/CODFig.10RemovalefficiencyofBOD5andBOD5/COD31O3027212O3pH。2700mg/L、COD3500mg/L、pH0.88O3O314.05mg/L·min180minO32529.00mg/LCOD77.46%41.28%。3O3CODO3。4O3B/C。1CreaseyW．A．Biochemicaleffectsofberberine．Biochemi-calPharmacology19792871081-10842．．200328230-32ZhangLaixinYangQiongLiXiaowei．Extractberberinefromrhizomacoptidis．GuizhouChemicalIndustry200328230-32inChinese3．．199718383-85YangJunLuZhengyuHuJicuietal．Advancesinbio-logicaltreatmemtprocessesofantibioticproductionwastewater．EnvironmentalScience199718383-85inChinese4RenM．J．ZengP．SongY．H．etal．Performanceofpulseelectro-coagulationonberberinehydrochloridewastewater//IWA．The2ndIWAAsiaPacificRegionalYWPConference．BeijingIWAPublishing2009．181-1875．-．200629182-83LiXiangdongFengQiyan．Experimentalstudyontreat-mentofpharmaceuticalwastewaterbyhydrolysisaerobicprocess．EnvironmetalScience＆Technology200629182-83inChinese6YaoC．C．HaagW．R．Rateconstantsfordirectreactionofozonewithseveraldrinkingwatercontaminants．Wat．Res．1991254761-7737RivasJ．GimenoO．BeltránF．etal．Wastewaterrecy-clingApplicationofozonebasedtreatmentstosecondaryeffluents．Chemosphere2009746854-8598．O3/H2O2．200223567-71MaJunShiFenghua．StudyonremovalofnitrobenzeneinwaterbyO3/H2O2．EnvironmentalScience200223567-71inChinese9LauT．K．ChuW．GrahamN．ReactionpathwaysandkineticsofbutylatedhydroxyanisolewithUVozonationandUV/O3processes．Wat．Res．2007414765-77410GzmenB．BerkantK．MuratGizirA．etal．Oxida-tivedegradationsofreactiveblue4dyebydifferentad-vancedoxidationmethods．J．Hazard．Mater．20091681129-13611LucasM．S．PeresJ．A．LanB．Y．etal．Ozonationkineticsofwinerywastewaterinapilot-scalebubblecol-umnreactor．Wat．Res．20094361523-153212．-．2006WuXiange．Degradationofsomeorganicpollutantsusingacombinationtechniqueofozone-activatedcarbonandad-vancedoxidation．GuangzhouDoctoralDissertationofChineseAcademyofSciencesGuangzhouInstituteofGeo-chemistry2007inChinese13．Fenton．2009225516-520ZhangLiZhuXiaodongZhangYanfengetal．Experi-mentalstudyontreatmentofo