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2009-03-27*E-mailhouhaige@hlju.edu.cn1972-。PVDF、、、[1]。PVDF,。PVDF、[2]。PVDFPVDF。PVDF。1PVDF。PVDFPVDF。。1.1PVDFDMF、TEP、NMP、DMSO。。Dar-JongLin[3]TEPPVDF。MeiZhang[4]DMSOPVDF。A.Bottino[5]DMF、NMPPVDFNMP、TEPDMFTEP。[6]。1.2PVDFPVDF*150080PVDF。PVDF。PVDF。TQ325.4A1001-0017(2009)06-0054-04ResearchprogressinPVDFUltrafiltrationMembranesPreparedbyphaseInversionMethodandTheirModificationsLIUChun-tao,JINZhengHOUHai-geSUNYong-rongandWENLei(CollegeofChemistryandMaterialsScience,HeilongjiangUniversity,Harbin150080)Abstract:Thenewlyresearchprogressofpoly(vinylidene)fluoride(PVDF)membraneinpreparationandmodificationisreviewed.Theresearchfocusesontheeffectsofsolventsandnon-solventsontheporeandstructureofPVDFmembranesbyphaseinversion.ThemodificationmethodsofPVDFultrafiltrationmembranesincludingsubstancemodificationandsurfacemodificationareintroduced.Thesubstancemodificationmethodinclud－edphysicalblendingandcopolymerization,thesurfacemodificationincludedradiationinducedgraftingandlow-temperatureplasma.ItwasevidentthatphysicalblendingwasthemaintrendofmodificationofPVDFultrafiltrationmembrane.ThePVDFultrafiltrationmembraneasanewtechniqueinwatertreatmentapplicationisintroducedbriefly.Keywords:PVDF;ultrafiltrationmembrane;preparation;modificationPVDFVol．31．No．62009·54·。[7]PVDF。[8],。XiaofengLi[9]20℃80℃。M.G.Buonomenna[10]C1-C8C1-C8PVDFβPVDFαβ。A.Bottino[11]PVDF。2PVDFPVDF。。2.1PVDF2.1.1PVDF。。PVDFPVDF。[12]Al2O3/PVDFAl2O3Al2O32%。[13]Al2O3TiO2PVDF。[14]SiO2PVDFSiO2。[15]。[16]SiO2PVDFSiO2γ-PVDFPVDF。PVDFZrO2[17]、Fenton[18]、CaCO3[19]、[20]LiClO4[21]。。[22]、、PVDF、、12-、、、、。M.Khayet[23]PEGPEOPVDFPEGPEO。Yong-HongZhaoHPG[24]、EPTBPACPSHPE-g-MPEG[25]PVDFACPSPEGACPS。[26]IPDI,PEG,HEMAEGMMAPVDF3。2.1.2PVDFPVDF。PVDF[27]HF“”,PVDFPVDF-g-PSSA。[28]。2.2PVDF2.2.1、、γ-。[29]Co-60γPVDFAAC25KGyAACAAC40%。、IPA、HClCuSO4[30]CuSO4Cu-2009316CHEMISTRYANDADHESION·55·SO4。[31]EBPVDF-g-PM-MAPMMAPVDF。2.2.2PVDFPVDF。[32]PVDFPVDF。[33]ArPVDF。3PVDFPVDF、。PVDF、。PVDFPVDF[35]。PVDF。[36]PVDF1.08g/L99%。PVDF、、。PVDF、。4PVDF。PVDFPVDF。1,,.J.,2003(3):61~65.2,,.PVDEJ..2007,33(8):50~53.3LINDAR-JONG,CHENGHSU-HSIEN,CHENTZNNG-CHIN,etal.FormationofporousPoly(vinylidene)fluoridemembranewithsymmetricorasymmetricmorphologybyimmersionprecipi－tationinthewater/TEP/PVDFsystemJ.EuropeanPolymerJour－nal,2006,42(2006):1581~1594.4ZHANGMEI,ZHANGAI-QING,ZHUBAO-KU,etal.Polymor－phisminporouspoly(vinylidene)fluoridemembraneformedviaimmersionprecipitationprocessJ.JornalMembraneScience,2008,319(2008):169~175.5BottinoA,CapannelliG,ComiteA.Novelporousmembranefromchemicallymodifiedpoly(vinylidene)fluorideJ.JournalMem－braneScience,2006,273(2006):20~24.6,,.J.,2006,3:21~23.7,,.PVDFJ.,2008,21(4):380~384.8,,.PVDFJ.,2002,15(2):171~176.9LIXIAOFENG,WANGYONGGANG,LUXIAOLONG,etal.MorphologychangesofpolyvinylidenefluoridemembranesunderdifferentphaseseparationmechanismsJ.JournalMembraneScience,2008,320:477~482.10BUONOMENNAMG,MACCHIP,DAVOLIM,etal.Poly(vinylidene)fluoridemembranebyphaseinversion:therolethecastingandcoagulationconditionplayintheirmorphology,crystallinestructureandpropertiesJ.EuropeanPolymerJour－nal,2007,43:1557~1572.11BOTTINOA,CAPANNOLLIG,COMITEA.Novelporouspoly(vinylidene)fluoridemembraneformembranedistillationJ.Desalination,2005,183:375~382.12,,,..J.2007,28(2):371~376.13,,,.PVDFJ.,2005,26(3):126~129.14,,.SiO2J.,2006,26(1):31~34.15,,.SiO2PVDFJ.,2007,27(3):21~24.16,,.SiO2J.,2007,27(6):47~50.17BOTTINOA,CAPANNELLIG,COMITEA,etal.PreparationandcharacterizationofnovelporousPVDF-ZrO2compositemembranesJ.Desalination,2002,146:35~40.18,,,.FentonJ.,2007,22(5):8~11.19,,,.J.,2008,27(3):56~59;20,,,.J.,2008,25(1):40~43.PVDFVol．31．No．62009·56·532POISSONNMAAZOUZASAUTEREAUHetal.Curingofdi－cyandiamideepoxyresinsacceleratedwithsubstitutedureasJ.J.Appl.Polym.Sci.199869:2487~2497.3WEARRLStPAUlW.Stableheat-curingepoxyresincompo－sitions:US2847395P.1958-08-12.4ALEKSANDRACN.Substitutedureasaslowtemperatureepoxycuringagents:US3386955P.1968-06-04.5ALEKSANDRACN.Lowtemperaturecurableepoxyresinadhe－sivecompositionswithlongstoragestability:US3386956P.1968-06-04.6MCKOWNAG.Particulateadhesivecontainingpolyepoxidescarboxylatedbutadiene-acrylonitrilecopolymerandaureaderivativeasacuringagent:US3655818P.1972-04-11.7MCKOWNAG.Adhesive:US3707583P.1972-12-26.8ITOMHATAHKAMAGATAK.ThermalprotertiesofepoxyresincuredwithimidazoleJ.J.Appl.Polym.Sci.198733:1843~1848.9.J.19941:34~37.10BROWNJHAMERTONIHOWLINBJ.Preparationcharac－terizationandthermalpropertiesofcontrollablemetal-imida－zolecomplexcuringagentsforepoxyresinsJ.J.Appl.Polym.Sci.200075:201~217.11KURNOSKINAV.Structureoftheepoxy-chelatemetal-con－tainingmatrices:throreeticalaspectsJ.J.Appl.Polym.Sci.199348:639~656.12TAKECHISMATSUDAH.Crosslinkingofbisepoxieswithdi－valentmetalsaltsofpaminobenzoicacidanddiamineJ.J.Appl.Polym.Sci.199348:1105~1114.13KAPLANMLWAYDAALLYONSAM.Lanthanide-imida－zolecomplexesaslatentcuringagentsforepoxyresinsJ.J.Polym.Sci.:PartA:Polym.Chem.199028:731~740.14NANDLALSDEDWARDSW.2-phenylimidazole-phosphoricacidsaltasanacceleratorforacidanhydridecurativesinone-componentepoxycompositions:US6462164P.2002-10-08.15S