SBR短程硝化的实现维持及稳定性张强

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SBR、*张强,徐国勋,吴文雯,曾林慧(上海理工大学城市建设与环境工程学院,上海200093)   :,SBRpH7.5~8.5,,NO-2-N/NO-x-N90%,pHDO。,DO0.5~1.0mg/L,5.5h,,1,90%。,CODNH+4-N。,。  :SBR;;;  :X703.1   :A   :(K)08088(1002-1264)(2008)06-0025-04Achievement,MaintainmentandStabilityofShortcutBiologicalNitrificationinSequencingBatchReactorZHANGQiang,XUGuo-xun,WUWen-wen,ZENGLin-hui(UrbanConstructionandEnvironmentEngineering,UniversityofShanghaiforScienceandTechnology,Shanghai20093,China)Abstract:TheshortcutnitrificationanddenitrificationwereachievedefficientlybycontrollingpHvaluebetween7.5and8.5inthesequencingbatchreactor(SBR)treatingsimulatedmunicipalsewage.Thenitrosationrate(NO-2-N/NO-x-N)maintainedabove90%allthetime.TheresultalsoshowedgoodrepeatabilitiesofpHvalueandDOconcentrationduringshortnitrificationprocess.WithDOconcentrationat0.5~1.0mg/Landaerationtimeat5.5hours,theshortcutnitrificationanddenitrificationcanbekeptingoodstate,withoutanychangeafteroperationofonemonth.Onthisbasis,theimpactloadresistantcapabilityofthesystemwasalsostudied.Theresultshowedthatthesystempossessesstrongeimpactloadresistibility.Keywords:SBR;shortcutnitrification;fixed-timecontrol;lowDO  pH[1]、[2],,。SBRpH,,、、,DO。,。1 1.1 1。SBR,106cm,40cm,22L。,;,,;,,,;3,20cm,,。SBR、、、,。1 SBR25  216200812URBANENVIRONMENTURBANECOLOGYVol.21No.6Dec.2008*:(568001) :2008-08-311.2   、NH4Cl、KH2PO4,。COD160~400mg/L,NH+4-N50~100mg/L,NaHCO3,NaOHpH。26~28℃。1.3   :;:N-(1-);:;COD:;pH:pHs-2C。[3]。1.4   ,4.8g/L。NH+4-N、。3d,COD92%,NH+4-N85%,、。,SBR12h,:0.5h,5~8h,2~3h,1~3h,0.5h。2 2.1 pH  NaOHpH7.5~8.5,,NO-2-N,NaHCO3,23d,COD,90%,CODpH。NH+4-N2。2 NH+4-N  2,,pH,,NH+4-N39%。,NH+4-N,NH+4-N。pH,NH+4-N。  NO-3-N,NO-2-N,NO-2-N/NO-x-N50%,。NO-3-N、NO-2-NNO-2-N/NO-x-N3。3 NO-x-NNO-2-N  3,pH7.5~8.5,,NO-2-N,NO-3-N,NO-2-N/NO-x-N3%85%。NO-2-N,pH。,NO-2-N,pH。,pH7.5~8.5,SBR。  ,pH,,pH、DO、NH+4-N、NO-3-N、NO-2-N,4。,(MLSS)3.6g/L,COD150mg/L,NH+4-N50mg/L。  4,pH,60min,,,pH。pH,,,H+pH。,,NO-2-N,330min,pH,NH+4-N3mg/L。pH,NO-2-N,,26                   216 2008,,pH。,pH,pH,NO-2-N,330min,,,NO-2-NNO-3-N,NH+4-NNO-2-N,。pH,。4 pH、DONO-x-N  4,DO,NH+4-N,,,DO。330min,,、,DO。  ,pH。,[4],,pH,,DO;,pH,[5]。,DO。2.2 DO  4DO(0.3~0.5、0.5~1.0、1.0~2.02.0~5.0mg/L)(1、2、3、4),DONO-2-N、COD、NH+4-N、,。(MLSS)3.6g/L,COD150mg/L,NH+4-N50mg/L。51。5 DONO-x-NNO-2-N1 DO、DO(mg/L)(min)(mgNH+4-N/(gMLSSL))COD(%)NH+4-N(%)0.3~0.54800.021596810.5~13300.032895981~23300.031498962~52800.04079690  5,12,NO-2-N80%,NH+4-N81%,DO,。DO,DO,,,,NO-2-N。12,,2NO-2-N1NO-2-N。1。  DO,34,NO-2-N,NO-3-N。,DO1mg/L,,NO-2-N,NO-2-N。  1,1,,DO,DO。23,,COD、NH+4-N95%,3NO-2-N,DO。4,,COD、NH+4-N90%,NO-2-N50%,DO,27 , SBR、NO-2-N,,。  ,DO。DO,,,NO-2-N;DO,,。,DO0.5~1.0mg/L,5.5h,,NO-2-N90%,COD、NH+4-N95%、98%。2.3   ,,。,COD,COD,50mg/L,COD。  NH+4-N,NH4ClNH+4-N。6。6 NH+4-N  6,25,5NH+4-N,。NH+4-N5NH+4-N,,(100%)。,6,4NH+4-N,NH+4-N。,NH+4-N,,,。,,。  ,,,。3   1)pH7.5~8.5,26~28℃,。23,,NO-2-N,NO-3-N7mg/L,NO-2-N90%。  2),pH、DO、NH+4-N、NO-3-N、NO-2-N。。  3)DO。,DO0.5~1.0mg/L,5.5h,。  4),COD;NH+4-N,,NH+4-N。NH+4-N,。[1] Villaverdes,F.Fdz-polancoandP.A.Garcia.NitrifyingBio-filmAcclimationtoFreeAmmoniainSubmergedBiofilters.Start-UpInfluence[J].WatRes,1999,34(2):602-610.[2] Ruizg,Jeison,Chamyr.NitrificationwithHighNitriteAccumula-tionfortheTreatmentofWastewaterwithHighAmmoniaConcen-tration[J].WatRes,2003,37(6):1371-1377.[3] .(4)[M].:,2002:246-286.[4] ,,,.pHSBR[J].,2003,9(5):549-553.[5] Y.Z.Peng,J.F.Gao,S.Y.Wang,etal.UseofpHasFuzzyControlParameterforNitrificationunderDifferentAlkalinityinSBRProcess[J].Wat.Sci.Tech,2003,147(11):77-84.:(1983-),,,,。28                   216 2008

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