66BasicScienceFe2O3-MnO2/-Al2O3112221.2142152.100124-Al2O3Fe2O3-MnO2/-Al2O3BETXRDFe2O3-MnO2/-Al2O330g/L20mL/L3.0hCOD85%,-Al2O3X703A1674-6708201144-0116-02[1-4]H2O2OH-Fe2O3-MnO2/-Al2O3BETXRDH2O211.11.1.1-4mm1.1.2Fe2O3-MnO2/-Al2O35002-12Fe2O3-MnO2/-Al2O3FeNO33MnNO3240031.2MicromeriticsMicromeriticsASAP201V4.02ARigakuD/max2500V/PCXCuK40kV200mA5~801.320~80500mg/L30g/LH2O220mL/LCODCODGB11914-198922.12.2.11-9.63%10.06%5.79%m2g-1cm3g-1nm-Al2O3159.00.8322.36Fe2O3-MnO2/-Al2O3149.80.7520.111BET2.2.2XRD1Fe2O3-MnO2/-Al2O3(a)Fe2O3/-Al2O3(b)XRD132.838.348.462.067.8-Al2O3432.938.748.867.9-Al2O366655335201111.indd112011//114::6BasicScience21.32080500mg/L30g/LH2O220mL/L(COD)(COD)GB11914-198922.12.2.11-9.63%10.06%5.79%(m2g1)(cm3g1)(nm)-Al2O3159.00.8322.36Fe2O3-MnO2/-Al2O3149.80.7520.111BET2.2.2XRD1Fe2O3-MnO2/-Al2O3(a)Fe2O3/-Al2O3(b)XRD132.838.348.462.067.8-Al2O3432.938.748.867.9-Al2O31XRD-Fe2O335.836.644.563.5a=b=c=8.535nmFe2MnO4FeMn-Al2O3Mn1Fe2O3/-Al2O3Fe2O3-MnO2/-Al2O3Mn1XRD-Fe2O335.836.644.563.5a=b=c=8.535nmFe2MnO4FeMn-Al2O3Mn1Fe2O3/-Al2O3Fe2O3-MnO2/-Al2O3Mn2.32.3.1Fe2O3/-Al2O3MnO2/-Al2O3-Al2O3Fe2O3-MnO2/-Al2O34030g/L20mL/L500mg/LCOD22COD%-Al2O312.3Fe2O3/-Al2O355.1MnO2/-Al2O337.8Fe2O3-MnO2/-Al2O362.22COD2,Fe2O3-MnO2/-Al2O3Fe2O3/-Al2O3MnO2/-Al2O3-Al2O3FeMn-Al2O3COD2.3.2COD32.32.3.1Fe2O3/-Al2O3MnO2/-Al2O3-Al2O3Fe2O3-MnO2/-Al2O34030g/L20mL/L500mg/LCOD22COD(%)-Al2O312.3Fe2O3/-Al2O355.1MnO2/-Al2O337.8Fe2O3-MnO2/-Al2O362.22COD2,Fe2O3-MnO2/-Al2O3Fe2O3/-Al2O3MnO2/-Al2O3-Al2O3FeMn-Al2O3COD2.3.2COD2CODH2O220mL/L30g/L2Fe2O3-MnO2/-Al2O3CODCOD60COD[5],602COD2.3.3COD3COD2COD2CODH2O220mL/L30g/L2FO3MOO3ODCOD60COD[5],602.3.3COD3CODFe2O3-MnO2/-Al2O36030g/LH2O220mL/LCOD1.5COD[67]1.54Fe2O3-MnO2/-Al2O36030g/LH2O220mL/LCOD1.5COD[6,7]1.53COD31)-2)20COD60COD50%3)Fe2O3-MnO2/-Al2O36030g/LH2O220mL/L1.5COD85.2%[1]C.S.Zalazar,M.L.Satuf,O.M.Alfano,A.E.Cassano,Environ.Sci.Technol.42(2008)6198-6204.[2]B.Xu,N.Y.Gao,H.Cheng,S.J.Xia,M.Rui,D.D.Zhao,J.Hazard.Mater.162(2009)954-959.[3]S.Popiel,T.Nalepa,D.Dzierak,R.Stankiewicz,Z.Witkiewicz,J.Hazard.Mater.164(2009)1364-1371.[4]W.R.Chen,C.M.Sharpless,K.G.Linden,I.H.(Mel)Suffet,Environ.Sci.Technol.40(2006)2734-2739.[5]H.J.Fan,Huang,S.T.W.H.Chung,J.L.Jan,W.Y.Lin,C.C.Chen,J.Hazard.Mater.171(2009)1032-1044.[6]G.Q.Zhang,F.L.Yang,M.M.Gao,L.F.Liu,J.Phys.Chem.C112(2008)89578962.3COD31-220COD60COD50%3Fe2O3-MnO2/-Al2O36030g/LH2O220mL/L1.5COD85.2%[1]C.S.Zalazar,M.L.Satuf,O.M.Alfano,A.E.Cassano,Environ.Sci.Technol.42(2008)6198-6204.[2]B.Xu,N.Y.Gao,H.Cheng,S.J.Xia,M.Rui,D.D.Zhao,J.Hazard.Mater.162(2009)954-959.[3]S.Popiel,T.Nalepa,D.DzierZak,R.Stankiewicz,Z.Witkiewicz,J.Hazard.Mater.164(2009)1364-1371.[4]W.R.Chen,C.M.Sharpless,K.G.Linden,I.H.(Mel)Suffet,Environ.Sci.Technol.40(2006)2734-2739.[5]H.J.Fan,Huang,S.T.W.H.Chung,J.L.Jan,W.Y.Lin,C.C.Chen,J.Hazard.Mater.171(2009)1032-1044.[6]G.Q.Zhang,F.L.Yang,M.M.Gao,L.F.Liu,J.Phys.Chem.C112(2008)8957-8962.[7]G.QZhang,F.L.Yang,M.M.Gao,X.H.Fang,L.F.Liu.Electrochim.Acta53(2008)5155-5161.[8]T.Luo,Z.H.Ai,L.Z.Zhang.J.Phys.Chem.C112(2008)65666553362011117e2-n2/-Al2C87-881..indd1172011//114::