THESCIENCEANDTECHNOLOGYOFINDUSTRIALWATERTREATMENTTHESCIENCEANDTECHNOLOGYOFINDUSTRIALWATERTREATMENTEditedbyZAHIDAMJADCRCPressisanimprintoftheTaylor&FrancisGroup,aninformabusinessBocaRatonLondonNewYorkCo-publishedbyIWAPublishing,AllianceHouse,12CaxtonStreet,LondonSW1H0QS,UKTel.+44(0)2076545500,Fax+44(0)2076545555publications@iwap.co.uk®isatrademarkofTheMathWorks,Inc.andisusedwithpermission.TheMathWorksdoesnotwarranttheaccuracyofthetextorexercisesinthisbook.Thisbook’suseordiscussionofMATLAB®softwareorrelatedproductsdoesnotconsti-tuteendorsementorsponsorshipbyTheMathWorksofaparticularpedagogicalapproachorparticularuseoftheMATLAB®software.CRCPressTaylor&FrancisGroup6000BrokenSoundParkwayNW,Suite300BocaRaton,FL33487-2742©2010byTaylorandFrancisGroup,LLCCRCPressisanimprintofTaylor&FrancisGroup,anInformabusinessNoclaimtooriginalU.S.GovernmentworksPrintedintheUnitedStatesofAmericaonacid-freepaper10987654321InternationalStandardBookNumber-13:978-1-4200-7145-0(Ebook-PDF)Thisbookcontainsinformationobtainedfromauthenticandhighlyregardedsources.Reasonableeffortshavebeenmadetopublishreliabledataandinformation,buttheauthorandpublishercannotassumeresponsibilityforthevalidityofallmaterialsortheconsequencesoftheiruse.Theauthorsandpublishershaveattemptedtotracethecopyrightholdersofallmaterialrepro-ducedinthispublicationandapologizetocopyrightholdersifpermissiontopublishinthisformhasnotbeenobtained.Ifanycopyrightmaterialhasnotbeenacknowledgedpleasewriteandletusknowsowemayrectifyinanyfuturereprint.ExceptaspermittedunderU.S.CopyrightLaw,nopartofthisbookmaybereprinted,reproduced,transmitted,orutilizedinanyformbyanyelectronic,mechanical,orothermeans,nowknownorhereafterinvented,includingphotocopying,microfilming,andrecording,orinanyinformationstorageorretrievalsystem,withoutwrittenpermissionfromthepublishers.Forpermissiontophotocopyorusematerialelectronicallyfromthiswork,pleaseaccess()orcontacttheCopyrightClearanceCenter,Inc.(CCC),222RosewoodDrive,Danvers,MA01923,978-750-8400.CCCisanot-for-profitorganizationthatprovideslicensesandregistrationforavarietyofusers.FororganizationsthathavebeengrantedaphotocopylicensebytheCCC,aseparatesystemofpaymenthasbeenarranged.TrademarkNotice:Productorcorporatenamesmaybetrademarksorregisteredtrademarks,andareusedonlyforidentifica-tionandexplanationwithoutintenttoinfringe.VisittheTaylor&FrancisWebsiteat:AnOverview................................................................1ZahidAmjadandPeterG.Koutsoukos2ChapterCrystalGrowthInhibitionofCalciumSulfateandCalciumOxalatesinAqueousSystems...................................................................................................21MuallaOner3ChapterCalciumCarbonateScaleControlinIndustrialWaterSystems................................39PeterG.Koutsoukos4ChapterCalciumCarbonate:PolymorphStabilizationinthePresenceofInhibitors.............61PeterG.KoutsoukosandTaoChen5ChapterScaleandDepositControlPolymersforIndustrialWaterTreatment........................81RobertW.ZuhlandZahidAmjad6ChapterNewModelsforCalciumPhosphateScaleFormationandDissolution..................105LijunWang,PatrickP.Emmerling,ZacharyJ.Henneman,andGeorgeH.Nancollas7ChapterDesignandApplicationsofCoolingWaterTreatmentPrograms............................113LibardoA.Perez,GaryE.Geiger,andCharlesR.Ascolese8ChapterLatestDevelopmentsinOilfieldScaleControl........................................................129MingdongYuan9ChapterControlofSilicaScalinginGeothermalSystemsUsingSilicaInhibitors,ChemicalTreatment,andProcessEngineering.......................................................155DarrellL.GallupandPaulN.Hirtz1Chapter0RecentDevelopmentsinControllingSilicaandMagnesiumSilicateFoulantsinIndustrialWaterSystems.....................................................................................179KonstantinosD.DemadisviContents1Chapter1PhosphateContainingScaleFormationinWastewater...........................................205PeterG.KoutsoukosandAikateriniN.Kofina1Chapter2NewDevelopmentsinMembrane-BasedProcessesforIndustrialApplications.....227PeterS.Cartwright1Chapter3ReverseOsmosisMembraneFoulingControl.........................................................247JaneKucera1Chapter4ScaleFormationandControlinThermalDesalinationSystems.............................271FaizurRahmanandZahidAmjad1Chapter5BoilerWaterTreatment.................