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3212201212ActaScientiaeCircumstantiaeVol．32No．12Dec．20121982—E-maillijiang0808@126．com*E-mailhq0980@126．comBiographyLIJiang1982—malePh．D．candidateE-maillijiang0808@126．com*CorrespondingauthorE-mailhq0980@126．comHenriSpanjers．2012．UASBJ．32122929-2934LiJHeQHenriSpanjers．2012．Sludgecharacteristicsalongtheheightoffull-scaleUASBreactortreatingpaper-milleffluentsJ．ActaScientiaeCircumstantiae32122929-2934UASB李江1，何强1，*，HenriSpanjers21．4000452．2012-02-242012-04-052012-04-17UASBUASB7．2m、．VS、TS、VSS、TSS2．20m．1．20m3．45mCOD900mg·L－1．1．20mVS/TSTS136g·L－1VS75g·L－10．16g·g－1·d－1gVSSCOD308μm．UASB．UASB0253-2468201212-2929-06X703ASludgecharacteristicsalongtheheightoffull-scaleUASBreactortreatingpaper-milleffluentsLIJiang1HEQiang1*HenriSpanjers21．KeyLaboratoryoftheThreeGorgesＲeservoirＲegion'sEco-EnvironmentMinistryofEducationChongqingUniversityChongqing4000452．SectionSanitaryEngineeringDelftUniversityofTechnologyDelftＲeceived24February2012receivedinrevisedform5April2012accepted17April2012AbstractTheobservationsofsludgestabilitygranulemorphologyandspecificmethanogenicactivitySMAwereusedtoinvestigatethesludgecharacteristicsalongtheheightoffull-scaleupflowanaerobicsludgebedUASBreactortreatingpaper-milleffluents．TheresultsshowedthatthesolidsconcentrationofsludgedecreasedandthenstabilizedwithincreasingheightsalongUASBreactor．HighersolubleCODconcentrationmorethan900mg·L－1ofsludgewasobtainedat1．20mand3．45moftheUASBreactor．IntermsoftheratioofVS/TSSMAandmorphologycharacteristicsofsludgethesludgefrom1．20mofUASBreactorwasmorestableVS/TSas50%andhadhigherSMA0．16g·g－1·d－1asamountofCODinpergramVSSandbiggergranuleaverageequivalentdiameteras308μmthanthatofotherplacesofthereactor．Thesludgealongtheheightoffull-ScaleUASBreactorhadsignificantdifferenceingranulemorphologybuthadclosespecificmethanogenicactivity．Keywordssludgecharacteristicsspecificmethanogenicactivityfull-scaleUASBreactorpaper-millwastewater1IntroductionUpflowAnaerobicSludgeBedUASB、vanLier2008．UASB3000、、Tchobanoglousetal．2003vanLier2008Habetsetal．198510%～15%vanLier2008．UASB24～27℃vanHaandeletal．1994．5～20℃UASB．32LettingaandHulshoffPol1991UASB．UASBUASBUASBUASB．Mahmoud2004CODCOD66%87%UASB20%UASB47%．UASB．．UASB．Mahmoud2004UASB40%VS/TS．An2009UASB．UemuraHarada2000UASBCODCOD．Mahadevaswamy2004UASBpH．UASBUASB．、UASB．UASB．2Materialsandmethods2．1．UASBEGSB1．UASB7．2m35～37℃6h40m3·h－1．UASB1．20、1．95、2．203．45m2．0～4℃．1Fig．1SchematicprocessoftheWWTP2UASBmFig．2SamplingportsinUASBreactorunitm2．2pH、TotalSolidsTS、volatileSolidsVS、TotalSuspendedSolidsTSSvolatileSuspendedSolidsVSSAPHA20053．CODCODMerck．COD3500r·min－1HeraeusLabofuge400ThermoScientific5min0．45μmMilliporeCOD．pHpH197-sWTW．XL30-ESEMPhilipsLeicaM205FA．SpecificMethanogenicActivity039212UASBSMAAMPTSⅠBioprocessControl3．640mL400mL．．CO2、H2S．3Fig．3AutomatedmethanepotentialtestsystempHAngelidaki2008Angelidakietal．2009Tatianaetal．2010Leitaoetal．2009．pHK2HPO4·3H2O0．2mol·L－1NaH2PO4·2H2O0．2mol·L－1NH4Cl170g·L－1、CaCl2·2H2O8g·L－1MgSO4·7H2O9g·L－1FeCl3·4H2O2g·L－1、CoCl2·6H2O2g·L－1、MnCl2·4H2O0．5g·L－1、CuCl2·2H2O30mg·L－1、ZnCl250mg·L－1、HBO350mg·L－1、NH46Mo7O2·4H2O90mg·L－1、Na2SeO3·5H2O100mg·L－1、NiCl2·6H2O50mg·L－1、EDTA1g·L－1．ExtracellularPolymericSubstancesEPSSolubleMicrobialProductsSMPBoundEPSeEPSSatyawalietal．2008．12000gSorvallＲC5BPluscentrifuge15min0．45μmSMPGaoetal．2010．0．9%NaCl100℃1heEPSChangetal．1998Satyawalietal．2008Zhangetal．2010．3Ｒesults3．1UASB4．TSVS1．20m136、75g·L－13．45m113、67g·L－12．20m．TSSVSSTSVS．VS/TSVSS/TSS1．20m60%1．20m50%1．20m1．20m．4Fig．4ProfilesofTSVSTSSandVSSalongtheheightofUASBreactorpH7．00．COD1．20m945mg·L－12．20m785mg·L－1UemuraHarada2000．3．45m955mg·L－1．3．20℃1atmNL3d1．1．20m0．16g·g－1·d－1gVSSCOD1UASBTable1CumulativemethaneproductionandSMAalongtheheightsofUASBreactor/m*/NLSMA/g·g－1·d－11．200．250．161．950．210．122．200．240．123．450．240．14*SMAgVSSCOD．1392320．13g·g－1·d－1．1.20m．3．3UASB1．20m2505．5．．5UASBabFig．5OutsideaandinsidebimagesofsludgefromthebottomofUASBreactor1．20m3．45m6．6UASB2mm220、308μm6．7、2．31．1.20m．1．20m3．45mEPS90mg·g－1gMLSSVS．6UASB1．20ma3．45mbFig．6Imagesofsludgesfroma1．20mofUASBreactorandb3．45mofUASBreactor4Discussion4．1Mahmoud2004An2009．Mahmoud2004UASB37g·L－1、27g·L－115g·L－1、11g·L－140%VS/TS73%．An2009UASB30.62g·L－1、22．01g·L－111.99g·L－1、8．27g·L－1VS/TS70%．UASBUASB．UASB3sludgebed、sludgeblanketBolle239212UASBetal．1986a．Bolle1986bLi+UASB．2．20m．4．2UASBUASB．1．20m3．45m2．20m1．20m2．20m．Mahmoud200440%40%．4．3UASBLettingaetal．1991．CO2CO2CO2－3Ca2+CaCO3CaCO3．Batstone2002UASB1805m30．5～1．5mm0．98mm400～700g·m－3．Abreu2007．．Batstone20020～200μm、．．Conrad200020mmol·L－1．Angelidakietal．2009pH．4．4UASBBatstoneKeller2001UASBUASB．3Batstoneetal．2002．Ca2+、、Ca2+7%、1．1%、0．2%0.7%Ca2+．5Conclusions、UASB7．2m．TSVSTSSVSS1．20mVS/TSVSS/TSS1．20m50%COD3．45m2．20m2．20m3．45m1．20m1．20m0．16g·g－1·d－1gVSSCOD0．13g·g－1·d－1UASB．感谢代尔夫特理工大学卫生工程系HaleOzgun和MustafaEvrenErsahin两位博士生对论文实验的帮助，感谢JulesB．vanLier教授对论文的指导．3392321965—．E-mailhq0980@126．com．ＲeferencesAbreuAACostaJCAraya-KroffPetal．2007．QuantitativeimageanalysisasadiagnostictoolforidentifyingstructuralchangesduringarevivalprocessofanaerobicgranularsludgeJ．WaterＲesea