UASB改进工艺处理橡胶助剂废水的中试研究邹小玲1, 顾爱兵2, 缪应祺1, 倪国1(1., 212013; 2., 212013) :UASB,。,COD5000~12000mg/L,pH8.0,,COD80%,6.0kgCOD/(m3·d),pH7.3,。:; ; UASB; :X703 :A :1003-6504(2004)06-0086-03 ,60t。50,15t,,,,。,,[1]。1 ,[2]。,,,,。,。,:M(2-)、NOBS(N-2-)、CBS(N--2-)、NS(N--2-),,NOBS,65%。,M。,1。1 ()COD(mg/L)pHNOBS6000~150000.85%10NaCl、、NaOH、(NH4)2SO4CBS12000~180002.10%8.0、NaCl、MNS10000~160003.21%10NaCl、Na2SO4、NaOH、M:(1978-),,,,。 ,,,,,COD5000~12000mg/L,pH8.0,0.5%~1.1%。:(1);(2)pH,;(3)COD,;(4);(5)(M)。,(UASB),,,[3]。UASBLetfinga2070,UASB,,,UASB,,,[4]。1.1 厌氧反应器的设计与制作,1.2m,4.0m,4.5m3,4.1m3。1,。3,,2.3m,,,0.4m,,、、,,,,,,,6~12。,,,,,,VFA。,,。12,。。·86· 27 6 200411 DOI:10.19672/j.cnki.1003-6504.2004.06.0351 UASB1.2 进水方式:,,(2000~10000mg/L),(0.5~2.0m3/d),。,,,(KH2PO4)。1.3 污泥的驯化:,。:,,,。3,。0.6kgCOD/(m3·d),30.5g/L,4.0g/L,2~12d。3:(1)。,,pH。,,,COD。COD3000~4000mg/L,COD15%~30%。(2)。,,COD50%~60%。1.0~1.5m3/d,COD4000~7000mg/L。,,,。(3)。COD7000~10000mg/L,80%。。,,2~3d。,,,,,。2 2.1 容积负荷2,,。,(0.6kgCOD/(m3·d))。,,,6.0kgCOD/(m3·d),COD1000~2000mg/L,80%。,,COD,,。2 COD2.2 温度的影响(3):COD。20℃,45%,25~36℃,,80%。。,,,。3 2.3 pH值,pH。4,pH,7.0~8.0,,pH,9.0~11.0,12.0,pH,,,,。pH,7.1~7.4。,。pH,·87·UASB ,pH,,,,。。4 pH5pH,pH,0.1~0.3,pHpH,,,,,pH。pH,,,。5 pH2.4 产气量的变化6,,,。,,。,,。,,。,1.24m3/(m3·d),,,。6 4 (1),、,UASB,。COD8000~10000mg/L,COD80%,6.0kgCOD/(m3·d),COD1500mg/L。(2)UASB,,,,。,,,,,,。[][1] .[J].,1994,41(2):109-114.[2] .[J].,200l,17(19):6-10.[3] .M[J].,1990,10(5):378-382.[4] .[M].:,2002,245-246.(:2003-10-28;:2003-12-08)(上接第22页)。。[][1] ,,.[J].,2003.26(5):52-54.[2] .[M].:,1998,130-134.[3] ,,,./[J].,2002,16(3):345-350.(:2003-08-11;:2003-11-24)·88· 27 6 200411 EnvironmentalHormoneinWaterSamplesofWastewaterTreatmentPlantLINXing-tao,CHENMing,WANGXiao-yi,ZHANGShu-fen,WUShao-hua,CHENSha,WANGGui-hua,RENRen(CollegeofEnvironmentalandEnergyEngineering,BeijingUniversityofTechnology,Beijing100022)Abstract:Methodforanalyzingtheresidualofphthalateestersofenvi-ronmentalhormoneinurbanwastewaterbyusingsolidphaseextraction(HLB-cartridge)andhighperformanceliquidchromatographywases-tablished.AndtheresiduallevelsofphthalateestersininfluentsandeffluentsofthefourwastewatertreatmentplantsinBeijingwereinvesti-gated.Therewerefivekindsofphthalateesters(DEP,BBP,DBP,DCHPandDEHP)werecheckedoutandtheresultsbetween0.72and59.17μg/Lwereobtained.Itwasindicatedthatthetreatmenttakenbywastewatertreatmentplantscouldremovemostofphthalateestersofen-vironmentalhormone.Keywords:solid-phaseextraction;highperformanceliquidchromatog-raphy;phthalateesters;environmentalhormone;urbanwastewaterAnExperimentalStudyofPlasmaPyrolysisofWasteTyresTANGLan,HUANGHai-tao,WUChuang-zhi(GuangzhouInstituteofEnergyConversion,ChineseAcademyofSciences,Guangzhou510070)Abstract:Thermalplasmapyrolysisofwastetyresforrecoveringenergyandusefulchemicalswasperformedinanitrogenplasmareactor.Un-dertheexperimentalconditions,totalcontentofgasproductcanreachupto40%;thecontentofsolidresidueis60%.ThemaingaseousproductsareH2,CO,CH4,C2H2andsoon.Thepyrolyticcarbonblack(CBp)haspropertiesofthoseofvariousgradescarbonblackaddedduringtiresmanufacture.Keywords:thermalplasma;wastetyres;pyrolysis;carbonblack;wasterecycling.StudyonSyntheticReactionandApplicationofNon-phosphoriteBuilderVSLIYan-wen,YANGRen-bin,GUOZheng-yuan(CollegeofEnvironmentandResources,HunanAgriculturalUniversity,Changsha410128)Abstract:Sodiumpersulfateandsodiumhydrosulfitewasbeingreduc-er,aqueoussolutionpolymerizationofmaleicanhydrideandacrylicacidwasappliedtosynthesizethecopolymerwhichcanbeusedtosub-stituteSTPPinlaundrypowder.Itwasappliedinsomedifferentkindsoflaundrypowderandsomevaluabledataobtained.Keywords:maleicanhydride-acrylicacidcopolymer;non-phosphorousbuilder;appliedexperiment;Pilot-scaleStudyonTreatmentofWastewaterofRubber-aidbyImprovedUASBReactorZOUXiao-ling1,GUAi-bing2,MIAOYing-qi1,NIGuo1(1.DepartmentofBiologicalandEnvironmentalEngineering,JiangsuUniversity,Zhenjiang212013;2.SuTaiEnvironmentalConservationCompany,Zhenjiang212013)Abstract:Thepilot-scalestudyonprocessingwastewaterofrubber-aidbyimprovedUASBreactorshowedthatthereactorcaneffectivelytreatwastewater.Intheprocessoftheexperiment,influentCODwas5000~12000mg/L,andinfluentpHover8.0.Aftersludgetamingandculturing,about80%CODremovalratewasachieved,withorganicloading6.0kgCOD/(m3·d),andeffluentpHabout7.3.Thereactorcanmeetthedemandofexpectationandensurethesequentaerobictreatment.Keywords:wastewater;anaerobic;UASB;rubber-aidPurificationTechnologyofFlueGasfromCoal-firedCeramicKilnLICai-ting1,WANGLi-ping1,ZENGGuang-ming1,WEIXian-xun1,TANYa1,ZHANGMing-yu2(1.DepartmentofEnvironmentalScienceandEngineering,HunanUniversity,Changsha410082;2.PowderMetallurgyInstitute,CentralSouthUniversity,Changsha410083)Abstract:Anewbuiltdust-removeranddesulfurizationequipmentofcoal-firedkilninaceramicfactoryisdiscussed.Wettingdesulfurizationanddust-removerandceramicmicroporeareusedtofiltratedustwhilelimestoneisaddedtorecyclingwaterfordesulfurization.Purifiedfluegasisdischargedbya30meter-highchimney.Fluegasanddustmeettheemissionstandardsbylocalenvironmentalpr