氨氮废水生物处理工艺及研究进展王洪

第36卷　第5期2008年9月　　　　　　　河南师范大学学报(自然科学版)JournalofHenanNormalUniversity(NaturalScience)　　　　　　　Vol.36　No.5Sept.2008　　:1000-2367(2008)05-0097-04王　洪1,2,李海波1(1.,110044;2.,110004)　:,,.、、.CO2、、.:;;;;:X703.1　　　　　　　　　　　　　　　:A、,.,,,,.,、.,,,.,;、,,..1　,;,,,,1.,,;,,,;-.2[1],、、3(1、2、3).,.,;,,,.,,BOD5.2　,,.A/O80,,,[2].,,,50%.,,,70%.,,,,.A/O(),.,,.Bardenpho、Phoredox、:2007-09-11:(20060570):　(1974-),,,,:.DOI:10.16366/j.cnki.1000-2367.2008.05.035A2/O.SBR,.SBR、、、、5.SBR,,.,[3],,,.SBR,ICEAS、DAT-IAT、CASS、IDEA、UNITANK[4].,,、,,Orbal、Carrousel、[5].,;10%～20%,,,,.,、AB、MBR,.,:,,;,;,..3　3.1　-,,、,.,,、SBR、、CAST[6].-(simultaneousnitrificationdenitrification,SND),;A/OSND.SND,,,.,SND,,、DO、、、pHSND[7-9].[10]OGO,.,TNNH+4-N9.87mg·L-16.53mg·L-1,TNNH+4-N74.04%81.14%.DO(0.1～2mg·L-1),,,,.[11](SOA).,,,DO1.0mg·L-1,25℃,,,65%,20mg·L-1,COD30mg·L-1,,.Gao[12]Orbal,,DO、MLSS、.DO,、DO0.1、0.40.7mg·L-1,,5.5g·L-1,150%,71.2%.,(DO0.1mg·L-1),,.3.2　,,NO-2-N,.,,NO-2-N,,;,,NO-2-N98河南师范大学学报(自然科学版)　　　　　　　　　　　　　　　　2008年NO-2-NNO-3-N,,NO-2-NN2NO-3-NN2.,25%,40%,300%[13],,(、).NO-2.,,pH,DO,、(FA)、[14,15].SHARONDelft[16],,(30～40℃),,,HRT,,,.,,.OLANDGent.,NO-2-N.,AOB(),,.NO-2-NAOBNOB().AOB0.2～0.4mg·L-1,NOB1.2～1.5mg·L-1.OLAND,NOB,NO-2-N[17].[18]2.0mg·L-1,(30±2)℃,,.[19]A/O,DOpH,pH,,NO-2-N,,.[20]SBR,,0.5mg·L-111.8～49.1mg·L-1,13d.Zhang[21]UASB+A/OCN、NH+4-N,0.28～0.60(kgNH+4-N)·(m3·d)-117～29℃,A/ONO-2-N90%～99%,.,NH+4-N90%～100%,UASB,67%～80%.40%.3.3　1995,Mulder,,,Anammox[22].,,,,.,NO-2-N,NH+4-N.SHARON-ANAMMOX、OLAND.SHARON-ANAMMOXSHARONANAMMOX,SHARONANAMMOX,C/N,SHARON-ANAMMOX2002Dokhaven[23],.(CANON)DO,(),NO-2-NNH+4-NN2[24].,pH,,SRT.3.4　,,,,[25]..、、,-、.[26,27],,,,DO,,.ANAMMOX[28,29].().4　,、,3,.,,,,、,.99第5期　　　　　　　　　　　　　王　洪等:氨氮废水生物处理工艺及研究进展,、,.,,,,、;,,,,CO2、、、,.　　　[1]　.[M].:,2006.[2]　.[M].:,2006.[3]　　,,,.[J].(),2002,35(1):76-79.[4]　,　.[M].:,2005.[5]　,,.[J].,2007,17(1):153-154.[6]　,　.[J].,2001,19(1):29-35.[7]　ZengRJ,LemaireR,YuanZ,etal.Simultaneousnitrification,denitrification,andphosphorusremovalinalab-scalesequencingbatchre-actor[J].BiotechnolBioeng,2003,84(2):170-178.[8]　AharonAbeliovich.Theprokaryotes-TheNitriteOxidizingBacteria[M].NY:Springer,2006.[9]　,,　,.[J].,2007,1(1):68-73.[10]　,,,.OGO-[J].,2007,33(4):18-21.[11]　,,,.[J].,2005,13(6):16-18.[12]　GaoSY,PengYZ.NovelstrategyofnitrogenremovalfromdomesticwastewaterusingpilotOrbaloxidationditch[J].WaterRes,2007,41(2):397-405.[13]　PolliceA,TandoiV,LestingiC.Influenceofaerationandsludgeretentiontimeonammoniumoxidationtonitriteandnitrate[J].WaterRes,2002,36(10):2541-2546.[14]　CiudadG,RubilarO,MunozP,etal.Partialnitrificationofhighammoniaconcentrationwastewaterasapartofashortcutbiologicalni-trogenremovalprocess[J].ProcessBiochem,2005,40(5):1715-1719.[15]　,,,.[J].,2006,22(19):39-43.[16]　HellingaC,SchellenAJ,MulderJW,etal.TheSHARONprocess:aninnovativemethodfornitrogenremovalfromanammonium-richwastewater[J].WaterSciTechnol,1998,37(9):135-142.[17]　,　,　,.-[J].,2006,16(4):19-21.[18]　　,　,,.C/N[J].,2007,25(2):15-19.[19]　　,　,,.A/O-()[J].,2006,26(5):716-721.[20]　,,,.[J].(),2006,(46)12:2077-2080.[21]　ZhangSJ,PengYZ.Organicmatterandconcentratednitrogenremovalbyshortcutnitrificationanddenitrificationfrommaturemunici-pallandfillleachat[J].JEnvironSci,2007,(19)6:647-651.[22]　MulderA,VandeGrafAA,RobertsonLA,etal.Anaerobicammoniumoxidationdiscoveredinadenitrifyingfluidizedbedreactor[J].FEMSMicrobiolLett,1995,16:177-184.[23]　,Markvanloosdrecht.DOKHAVEN[J].,2003,29(10):19-25.[24]　FuxC,BoehlerM,HuberP,etal.Biologicaltreatmentofammonium-richwastewaterbypartialnitritationandsubsequentanaerobicammoniumoxidation(anammox)inapilotplant[J].JBiotechnol,2002,99(3):295-306.[25]　　,,,.[J].,2002,3(10):58-60.[26]　CaoGM,ZhaoQX,SunXB,etal.CharacterizationofnitrifyinganddenitrifyingbacteriacoimmobilizedinPVAandkineticsmodelofbiologicalnitrogenremovalbycoimmobilizedcells[J].EnzymeMicrobTechnol,2002,30:49-55.[27]　,.[J].,2002,10(5):1-6.[28]　,　,.UASB[J].,2003,22(10):665-669.[29]　StrousM,HeijnetJJ,KuenenJG.Thesequencingbatchreactorasapowerfultoolforthestudyofslowlygrowinganaerobicammomi-um-oxidizingmicroorganisms[J].ApplMicrobiolBiotechnol,1998,50(5):589-596.(103)100河南师范大学学报(自然科学版)　　　　　　　　　　　　　　　　2008年,:(1);(2).4',4-,pH,Si(OEt)4,1,2-.　　　[1]　ChongK,SivaguruJ,ShichiT,etal.Useofchirallymodifiedzeolitesandcrystalsinphotochemicalasymmetricsynthesis[J].JAmChemSoc,2002,124:2858-2859.[2]　DaoFS,RongC,YanQS,etal.Anovelopen-frameworkgalliumphosphatecontainingtwodifferentbuildingunits[J].EurJInorgChem,2003,28:1303-1305.[3]　SergioFernandez-Armas,JoseMesaL,Jose′PizarroL,etal.Aneworganicallytemplatedgallium(III)-dopedchromium(III)fluorophos-phite,(C2H10N2)[Ga0.98Cr0.02(HPO3)F3]hydrothermalsynthesis,crystalstructureandspectroscopicproperties[J].SolidStateChem,2004,177:765-771.[4]　WANGL,SONGT,FANY,etal.Ga3(HPO3)4F4(H3DETA)(DETA:Diethylenetriamine):ANewOpen-FrameworkFluorinatedGalli-umPhosphitewithPentamericBuildingUnit[J].JSolidStateChem,2006,179:824-829.[5]　WANGL,SONGT,FANY,etal.SynthesisandCharacterizationofaNewOpen-FrameworkFluorinatedGalliumPhosphitewithThree-DimensionalIntersectingChannels[J].JSolidStat